{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2006:MFQ73R23GY2C6DKVQKBWE3GXGY","short_pith_number":"pith:MFQ73R23","canonical_record":{"source":{"id":"cond-mat/0611684","kind":"arxiv","version":2},"metadata":{"license":"","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2006-11-27T20:41:02Z","cross_cats_sorted":["cond-mat.other"],"title_canon_sha256":"87fac4f669cda2addd0c25aa74e12f43121b73e222ef6abe9ef0e678208f4f8d","abstract_canon_sha256":"7a79777e5e50db98229be825e28741831bdf5789528125b0297742de7ace7494"},"schema_version":"1.0"},"canonical_sha256":"6161fdc75b36342f0d558283626cd7362a6c9f1296cf4bfde4f071024f76b4b6","source":{"kind":"arxiv","id":"cond-mat/0611684","version":2},"source_aliases":[{"alias_kind":"arxiv","alias_value":"cond-mat/0611684","created_at":"2026-07-04T15:14:15Z"},{"alias_kind":"arxiv_version","alias_value":"cond-mat/0611684v2","created_at":"2026-07-04T15:14:15Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.cond-mat/0611684","created_at":"2026-07-04T15:14:15Z"},{"alias_kind":"pith_short_12","alias_value":"MFQ73R23GY2C","created_at":"2026-07-04T15:14:15Z"},{"alias_kind":"pith_short_16","alias_value":"MFQ73R23GY2C6DKV","created_at":"2026-07-04T15:14:15Z"},{"alias_kind":"pith_short_8","alias_value":"MFQ73R23","created_at":"2026-07-04T15:14:15Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2006:MFQ73R23GY2C6DKVQKBWE3GXGY","target":"record","payload":{"canonical_record":{"source":{"id":"cond-mat/0611684","kind":"arxiv","version":2},"metadata":{"license":"","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2006-11-27T20:41:02Z","cross_cats_sorted":["cond-mat.other"],"title_canon_sha256":"87fac4f669cda2addd0c25aa74e12f43121b73e222ef6abe9ef0e678208f4f8d","abstract_canon_sha256":"7a79777e5e50db98229be825e28741831bdf5789528125b0297742de7ace7494"},"schema_version":"1.0"},"canonical_sha256":"6161fdc75b36342f0d558283626cd7362a6c9f1296cf4bfde4f071024f76b4b6","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-04T15:14:15.251337Z","signature_b64":"/wYQMh+N2qc9vdQzGGwicE95JsxcP7BMadzSOLxSDSc8walWjwa+LYP9mJszsC9Qan0mluNxn22MbPeTVCxOAw==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"6161fdc75b36342f0d558283626cd7362a6c9f1296cf4bfde4f071024f76b4b6","last_reissued_at":"2026-07-04T15:14:15.250954Z","signature_status":"signed_v1","first_computed_at":"2026-07-04T15:14:15.250954Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"cond-mat/0611684","source_version":2,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-04T15:14:15Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"YPaJN1Tl6+J6HKazjowJpAoU8KFeZ+tx2DUwh9ZjPEmMTH/4o9uuJqKdHGT0EQ0WG+eqZkdyPAwQWpl0z/KeCg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-07-07T09:56:48.029945Z"},"content_sha256":"b78bdb3089b8f4bad8506b2531ea4b8ff2ada39c632083312c4cb91a7e4a6dde","schema_version":"1.0","event_id":"sha256:b78bdb3089b8f4bad8506b2531ea4b8ff2ada39c632083312c4cb91a7e4a6dde"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2006:MFQ73R23GY2C6DKVQKBWE3GXGY","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Subtle competition between ferromagnetic and antiferromagnetic order in a Mn(II) - free radical ferrimagnetic chain","license":"","headline":"","cross_cats":["cond-mat.other"],"primary_cat":"cond-mat.mtrl-sci","authors_text":"B. Canals, C. Paulsen, C. Sporer, D. B. Amabilino, D. Luneau, E. Lhotel, E. Ressouche, J. Veciana, V. Simonet","submitted_at":"2006-11-27T20:41:02Z","abstract_excerpt":"The macroscopic magnetic characterization of the Mn(II) - nitronyl nitroxide free radical chain (Mn(hfac)2(R)-3MLNN) evidenced its transition from a 1-dimensional behavior of ferrimagnetic chains to a 3-dimensional ferromagnetic long range order below 3 K. Neutron diffraction experiments, performed on a single crystal around the transition temperature, led to a different conclusion : the magnetic Bragg reflections detected below 3 K correspond to a canted antiferromagnet where the magnetic moments are mainly oriented along the chain axis. Surprisingly in the context of other compounds in this "},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"cond-mat/0611684","kind":"arxiv","version":2},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/cond-mat/0611684/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-04T15:14:15Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"I0z9aNw5hzKnMFiGQ8sUFAdQw5nuhBlFBkdsjdP5OQfdSqUUfi33uM3/BKhzY8P2MBLV2yJQe+bnVr0R1EbtDg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-07-07T09:56:48.030334Z"},"content_sha256":"f1eaf9708351ee1a645671b35da0816a4a2b5cc885300a8ef5d291c05e1ef64c","schema_version":"1.0","event_id":"sha256:f1eaf9708351ee1a645671b35da0816a4a2b5cc885300a8ef5d291c05e1ef64c"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/MFQ73R23GY2C6DKVQKBWE3GXGY/bundle.json","state_url":"https://pith.science/pith/MFQ73R23GY2C6DKVQKBWE3GXGY/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/MFQ73R23GY2C6DKVQKBWE3GXGY/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-07-07T09:56:48Z","links":{"resolver":"https://pith.science/pith/MFQ73R23GY2C6DKVQKBWE3GXGY","bundle":"https://pith.science/pith/MFQ73R23GY2C6DKVQKBWE3GXGY/bundle.json","state":"https://pith.science/pith/MFQ73R23GY2C6DKVQKBWE3GXGY/state.json","well_known_bundle":"https://pith.science/.well-known/pith/MFQ73R23GY2C6DKVQKBWE3GXGY/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2006:MFQ73R23GY2C6DKVQKBWE3GXGY","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"7a79777e5e50db98229be825e28741831bdf5789528125b0297742de7ace7494","cross_cats_sorted":["cond-mat.other"],"license":"","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2006-11-27T20:41:02Z","title_canon_sha256":"87fac4f669cda2addd0c25aa74e12f43121b73e222ef6abe9ef0e678208f4f8d"},"schema_version":"1.0","source":{"id":"cond-mat/0611684","kind":"arxiv","version":2}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"cond-mat/0611684","created_at":"2026-07-04T15:14:15Z"},{"alias_kind":"arxiv_version","alias_value":"cond-mat/0611684v2","created_at":"2026-07-04T15:14:15Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.cond-mat/0611684","created_at":"2026-07-04T15:14:15Z"},{"alias_kind":"pith_short_12","alias_value":"MFQ73R23GY2C","created_at":"2026-07-04T15:14:15Z"},{"alias_kind":"pith_short_16","alias_value":"MFQ73R23GY2C6DKV","created_at":"2026-07-04T15:14:15Z"},{"alias_kind":"pith_short_8","alias_value":"MFQ73R23","created_at":"2026-07-04T15:14:15Z"}],"graph_snapshots":[{"event_id":"sha256:f1eaf9708351ee1a645671b35da0816a4a2b5cc885300a8ef5d291c05e1ef64c","target":"graph","created_at":"2026-07-04T15:14:15Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/cond-mat/0611684/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"The macroscopic magnetic characterization of the Mn(II) - nitronyl nitroxide free radical chain (Mn(hfac)2(R)-3MLNN) evidenced its transition from a 1-dimensional behavior of ferrimagnetic chains to a 3-dimensional ferromagnetic long range order below 3 K. Neutron diffraction experiments, performed on a single crystal around the transition temperature, led to a different conclusion : the magnetic Bragg reflections detected below 3 K correspond to a canted antiferromagnet where the magnetic moments are mainly oriented along the chain axis. Surprisingly in the context of other compounds in this ","authors_text":"B. Canals, C. Paulsen, C. Sporer, D. B. Amabilino, D. Luneau, E. Lhotel, E. Ressouche, J. Veciana, V. Simonet","cross_cats":["cond-mat.other"],"headline":"","license":"","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2006-11-27T20:41:02Z","title":"Subtle competition between ferromagnetic and antiferromagnetic order in a Mn(II) - free radical ferrimagnetic chain"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"cond-mat/0611684","kind":"arxiv","version":2},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:b78bdb3089b8f4bad8506b2531ea4b8ff2ada39c632083312c4cb91a7e4a6dde","target":"record","created_at":"2026-07-04T15:14:15Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"7a79777e5e50db98229be825e28741831bdf5789528125b0297742de7ace7494","cross_cats_sorted":["cond-mat.other"],"license":"","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2006-11-27T20:41:02Z","title_canon_sha256":"87fac4f669cda2addd0c25aa74e12f43121b73e222ef6abe9ef0e678208f4f8d"},"schema_version":"1.0","source":{"id":"cond-mat/0611684","kind":"arxiv","version":2}},"canonical_sha256":"6161fdc75b36342f0d558283626cd7362a6c9f1296cf4bfde4f071024f76b4b6","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"6161fdc75b36342f0d558283626cd7362a6c9f1296cf4bfde4f071024f76b4b6","first_computed_at":"2026-07-04T15:14:15.250954Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-04T15:14:15.250954Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"/wYQMh+N2qc9vdQzGGwicE95JsxcP7BMadzSOLxSDSc8walWjwa+LYP9mJszsC9Qan0mluNxn22MbPeTVCxOAw==","signature_status":"signed_v1","signed_at":"2026-07-04T15:14:15.251337Z","signed_message":"canonical_sha256_bytes"},"source_id":"cond-mat/0611684","source_kind":"arxiv","source_version":2}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:b78bdb3089b8f4bad8506b2531ea4b8ff2ada39c632083312c4cb91a7e4a6dde","sha256:f1eaf9708351ee1a645671b35da0816a4a2b5cc885300a8ef5d291c05e1ef64c"],"state_sha256":"7c0f6039e28caf2cea3dbc133ac4529cf5325e2283ef0bce79f33dbd8e5daca8"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"7U7eM/8hpgD5bn4xwOHk8//mlDTHTPoXyG5kqMm6qixMq3y8TVgQcsZtwd20VqYBv2HJnfxbMy1sNtFukn+eBA==","signed_message":"bundle_sha256_bytes","signed_at":"2026-07-07T09:56:48.032268Z","bundle_sha256":"688a09690f25f2dc195dbef0b27b0be69000a673a1ad79995edb9fe156ce53ed"}}