{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2025:O2T3NV2ZNT2MDDLSXDKDKOZQLP","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"6d3ffd4a60913837b1becb738db025ac21de471cd9ed8f23528d20e06b78e6a5","cross_cats_sorted":["cond-mat.mtrl-sci"],"license":"http://creativecommons.org/licenses/by-sa/4.0/","primary_cat":"cond-mat.stat-mech","submitted_at":"2025-03-05T15:55:07Z","title_canon_sha256":"9955091de630c34f1eac6f53f8f5f8c1a41d2acccdde823a97109b0b3b14bebb"},"schema_version":"1.0","source":{"id":"2503.03616","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2503.03616","created_at":"2026-05-20T02:05:32Z"},{"alias_kind":"arxiv_version","alias_value":"2503.03616v1","created_at":"2026-05-20T02:05:32Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2503.03616","created_at":"2026-05-20T02:05:32Z"},{"alias_kind":"pith_short_12","alias_value":"O2T3NV2ZNT2M","created_at":"2026-05-20T02:05:32Z"},{"alias_kind":"pith_short_16","alias_value":"O2T3NV2ZNT2MDDLS","created_at":"2026-05-20T02:05:32Z"},{"alias_kind":"pith_short_8","alias_value":"O2T3NV2Z","created_at":"2026-05-20T02:05:32Z"}],"graph_snapshots":[{"event_id":"sha256:eeef49aa006181400220a40258e0feb11228a4c19f7566c080eeafee5c9d047b","target":"graph","created_at":"2026-05-20T02:05:32Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2503.03616/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"The solvation environments of Li$^+$ in conventional non-aqueous battery electrolytes, such as LiPF$_6$ in mixtures of ethylene carbaronate (EC) and ethyl methyl carbonate (EMC), are often used to rationalize the transport properties of electrolytes and solid electrolyte interphase (SEI) formation. In the SEI, the solvation environments in the compact electrical double layer (EDL) next to the electrode, also known as the Helmholtz layer, determine (partially) what species can react to form the SEI, with bulk solvation environments often being used as a proxy. Here we develop and test a theory ","authors_text":"Daniel M. Markiewitz, Martin Z. Bazant, Qisheng Wu, Yue Qi, Zachary A. H. Goodwin","cross_cats":["cond-mat.mtrl-sci"],"headline":"","license":"http://creativecommons.org/licenses/by-sa/4.0/","primary_cat":"cond-mat.stat-mech","submitted_at":"2025-03-05T15:55:07Z","title":"Theory of Cation Solvation in the Helmholtz Layer of Li-ion Battery Electrolytes"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2503.03616","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:98a9ed2680e2e3b796e3bfe48cf622bf2e6bd6aa417af2e0cb2b55eaf85b7f62","target":"record","created_at":"2026-05-20T02:05:32Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"6d3ffd4a60913837b1becb738db025ac21de471cd9ed8f23528d20e06b78e6a5","cross_cats_sorted":["cond-mat.mtrl-sci"],"license":"http://creativecommons.org/licenses/by-sa/4.0/","primary_cat":"cond-mat.stat-mech","submitted_at":"2025-03-05T15:55:07Z","title_canon_sha256":"9955091de630c34f1eac6f53f8f5f8c1a41d2acccdde823a97109b0b3b14bebb"},"schema_version":"1.0","source":{"id":"2503.03616","kind":"arxiv","version":1}},"canonical_sha256":"76a7b6d7596cf4c18d72b8d4353b305bfa459c035bce8fe79e50adcfd990ccbb","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"76a7b6d7596cf4c18d72b8d4353b305bfa459c035bce8fe79e50adcfd990ccbb","first_computed_at":"2026-05-20T02:05:32.839418Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-20T02:05:32.839418Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"BbUNReZvDqhMau3xxWQUUu6qiCw6fKyRmjTYaGcJ7VeN2aM2+QfiMk/h7g8IOZGSWBF8F3Tgc8Wh4iRfFAxsCw==","signature_status":"signed_v1","signed_at":"2026-05-20T02:05:32.840063Z","signed_message":"canonical_sha256_bytes"},"source_id":"2503.03616","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:98a9ed2680e2e3b796e3bfe48cf622bf2e6bd6aa417af2e0cb2b55eaf85b7f62","sha256:eeef49aa006181400220a40258e0feb11228a4c19f7566c080eeafee5c9d047b"],"state_sha256":"178976cf19f71feaf032ff3fc8d0e0215aea3c7c9293b1c348ad14d46e18531a"}