{"record_type":"pith_number_record","schema_url":"https://pith.science/schemas/pith-number/v1.json","pith_number":"pith:2014:OAPH2I525FXCYAVKNSCAM6MS77","short_pith_number":"pith:OAPH2I52","schema_version":"1.0","canonical_sha256":"701e7d23bae96e2c02aa6c84067992ffc8c0d213bbb2f97d358a40db8ac4d3ef","source":{"kind":"arxiv","id":"1403.5408","version":1},"attestation_state":"computed","paper":{"title":"Modelling the effect of nuclear motion on the attosecond time-resolved photoelectron spectra of ethylene","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"physics.atm-clus","authors_text":"Alison Crawford-Uranga, Angel Rubio, Duncan John Mowbray, Stefan Kurth, Umberto De Giovannini","submitted_at":"2014-03-21T10:05:56Z","abstract_excerpt":"Using time dependent density functional theory (TDDFT) we examine the energy, angular and time-resolved photoelectron spectra (TRPES) of ethylene in a pump-probe setup. To simulate TRPES we expose ethylene to an ultraviolet (UV) femtosecond pump pulse, followed by a time delayed extreme ultraviolet (XUV) probe pulse. Studying the photoemission spectra as a function of this delay provides us direct access to the dynamic evolution of the molecule's electronic levels. Further, by including the nuclei's motion, we provide direct chemical insight into the chemical reactivity of ethylene. These resu"},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"1403.5408","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.atm-clus","submitted_at":"2014-03-21T10:05:56Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"648bc8b4a1e839f454680d610e5e19ec46881074e0a76fbcac8b4165ab8c055f","abstract_canon_sha256":"6eefcd0eec014a21b389096dba9919205e5654655d05ceb7418f12a4fefcedde"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T02:44:08.269405Z","signature_b64":"wKyD5zSPHbk4uk73/v2O5Q8+RBmo49ogE/HgK0Y4r50d/BJbRb48tk1x6951iZ0OmZdW1stsj96tkJ99riY1Cw==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"701e7d23bae96e2c02aa6c84067992ffc8c0d213bbb2f97d358a40db8ac4d3ef","last_reissued_at":"2026-05-18T02:44:08.268959Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T02:44:08.268959Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"Modelling the effect of nuclear motion on the attosecond time-resolved photoelectron spectra of ethylene","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"physics.atm-clus","authors_text":"Alison Crawford-Uranga, Angel Rubio, Duncan John Mowbray, Stefan Kurth, Umberto De Giovannini","submitted_at":"2014-03-21T10:05:56Z","abstract_excerpt":"Using time dependent density functional theory (TDDFT) we examine the energy, angular and time-resolved photoelectron spectra (TRPES) of ethylene in a pump-probe setup. To simulate TRPES we expose ethylene to an ultraviolet (UV) femtosecond pump pulse, followed by a time delayed extreme ultraviolet (XUV) probe pulse. Studying the photoemission spectra as a function of this delay provides us direct access to the dynamic evolution of the molecule's electronic levels. Further, by including the nuclei's motion, we provide direct chemical insight into the chemical reactivity of ethylene. These resu"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1403.5408","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"aliases":[{"alias_kind":"arxiv","alias_value":"1403.5408","created_at":"2026-05-18T02:44:08.269019+00:00"},{"alias_kind":"arxiv_version","alias_value":"1403.5408v1","created_at":"2026-05-18T02:44:08.269019+00:00"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1403.5408","created_at":"2026-05-18T02:44:08.269019+00:00"},{"alias_kind":"pith_short_12","alias_value":"OAPH2I525FXC","created_at":"2026-05-18T12:28:41.024544+00:00"},{"alias_kind":"pith_short_16","alias_value":"OAPH2I525FXCYAVK","created_at":"2026-05-18T12:28:41.024544+00:00"},{"alias_kind":"pith_short_8","alias_value":"OAPH2I52","created_at":"2026-05-18T12:28:41.024544+00:00"}],"events":[],"event_summary":{},"paper_claims":[],"inbound_citations":{"count":0,"internal_anchor_count":0,"sample":[]},"formal_canon":{"evidence_count":0,"sample":[],"anchors":[]},"links":{"html":"https://pith.science/pith/OAPH2I525FXCYAVKNSCAM6MS77","json":"https://pith.science/pith/OAPH2I525FXCYAVKNSCAM6MS77.json","graph_json":"https://pith.science/api/pith-number/OAPH2I525FXCYAVKNSCAM6MS77/graph.json","events_json":"https://pith.science/api/pith-number/OAPH2I525FXCYAVKNSCAM6MS77/events.json","paper":"https://pith.science/paper/OAPH2I52"},"agent_actions":{"view_html":"https://pith.science/pith/OAPH2I525FXCYAVKNSCAM6MS77","download_json":"https://pith.science/pith/OAPH2I525FXCYAVKNSCAM6MS77.json","view_paper":"https://pith.science/paper/OAPH2I52","resolve_alias":"https://pith.science/api/pith-number/resolve?arxiv=1403.5408&json=true","fetch_graph":"https://pith.science/api/pith-number/OAPH2I525FXCYAVKNSCAM6MS77/graph.json","fetch_events":"https://pith.science/api/pith-number/OAPH2I525FXCYAVKNSCAM6MS77/events.json","actions":{"anchor_timestamp":"https://pith.science/pith/OAPH2I525FXCYAVKNSCAM6MS77/action/timestamp_anchor","attest_storage":"https://pith.science/pith/OAPH2I525FXCYAVKNSCAM6MS77/action/storage_attestation","attest_author":"https://pith.science/pith/OAPH2I525FXCYAVKNSCAM6MS77/action/author_attestation","sign_citation":"https://pith.science/pith/OAPH2I525FXCYAVKNSCAM6MS77/action/citation_signature","submit_replication":"https://pith.science/pith/OAPH2I525FXCYAVKNSCAM6MS77/action/replication_record"}},"created_at":"2026-05-18T02:44:08.269019+00:00","updated_at":"2026-05-18T02:44:08.269019+00:00"}