{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2021:OAVWZTOHEPT7LAGN6TGENZHL6B","short_pith_number":"pith:OAVWZTOH","canonical_record":{"source":{"id":"2106.08071","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"physics.chem-ph","submitted_at":"2021-06-15T11:55:14Z","cross_cats_sorted":["physics.atm-clus"],"title_canon_sha256":"b288645cb467cd58dc65c07fa378224cd549d0113abb13142b303591ec86a88a","abstract_canon_sha256":"de9dd015ff42bb78536d5720773950acd53c8b547082a961f841da85ca3da480"},"schema_version":"1.0"},"canonical_sha256":"702b6ccdc723e7f580cdf4cc46e4ebf05f482ab1bd1112e647c321df51f1baa3","source":{"kind":"arxiv","id":"2106.08071","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2106.08071","created_at":"2026-07-05T03:10:10Z"},{"alias_kind":"arxiv_version","alias_value":"2106.08071v1","created_at":"2026-07-05T03:10:10Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2106.08071","created_at":"2026-07-05T03:10:10Z"},{"alias_kind":"pith_short_12","alias_value":"OAVWZTOHEPT7","created_at":"2026-07-05T03:10:10Z"},{"alias_kind":"pith_short_16","alias_value":"OAVWZTOHEPT7LAGN","created_at":"2026-07-05T03:10:10Z"},{"alias_kind":"pith_short_8","alias_value":"OAVWZTOH","created_at":"2026-07-05T03:10:10Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2021:OAVWZTOHEPT7LAGN6TGENZHL6B","target":"record","payload":{"canonical_record":{"source":{"id":"2106.08071","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"physics.chem-ph","submitted_at":"2021-06-15T11:55:14Z","cross_cats_sorted":["physics.atm-clus"],"title_canon_sha256":"b288645cb467cd58dc65c07fa378224cd549d0113abb13142b303591ec86a88a","abstract_canon_sha256":"de9dd015ff42bb78536d5720773950acd53c8b547082a961f841da85ca3da480"},"schema_version":"1.0"},"canonical_sha256":"702b6ccdc723e7f580cdf4cc46e4ebf05f482ab1bd1112e647c321df51f1baa3","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T03:10:10.713490Z","signature_b64":"s/4h1UqEv/xUiolCXxSwRuzp5Uo9XNaOwC8xW30Z2p1BFM4hFVKxLJYkqAh4Ya2stlFwGkuw0pZ5Ea3d0zcGBg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"702b6ccdc723e7f580cdf4cc46e4ebf05f482ab1bd1112e647c321df51f1baa3","last_reissued_at":"2026-07-05T03:10:10.712993Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T03:10:10.712993Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"2106.08071","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T03:10:10Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"yyiNIhjZyN86YtDsGRDd6L9h/E0kmX92cpQ65lX/fbVpwQb5F57LVpq2hoZdugBRuYeu1XYv12QbrZrtLlh1BA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-04T14:52:26.787537Z"},"content_sha256":"dd7681564627722d292a52e5e702069919ce327b545c01b26cde159935a45eb1","schema_version":"1.0","event_id":"sha256:dd7681564627722d292a52e5e702069919ce327b545c01b26cde159935a45eb1"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2021:OAVWZTOHEPT7LAGN6TGENZHL6B","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Photoelectron circular dichroism of O 1$s$-photoelectrons of uniaxially oriented trifluoromethyloxirane: Energy dependence and sensitivity to molecular configuration","license":"http://creativecommons.org/licenses/by/4.0/","headline":"","cross_cats":["physics.atm-clus"],"primary_cat":"physics.chem-ph","authors_text":"A. Khan, A. Knie, C. K\\\"ustner-Wetekam, D. Kargin, D. Trabert, F. Trinter, G. Nalin, H. Fukuzawa, I. Vela-Perez, J. Viehmann, J. Williams, K. Fehre, K. Ueda, L. Marder, M. Hofmann, M. Ilchen, M. Kircher, M. Maurer, M. S. Sch\\\"offler, M. Waitz, N. Anders, N. M. Novikovskiy, Ph. V. Demekhin, R. D\\\"orner, R. Pietschnig, R. Tomar, S. Grundmann, T. Jahnke","submitted_at":"2021-06-15T11:55:14Z","abstract_excerpt":"The photoelectron circular dichroism (PECD) of the O 1s-photoelectrons of trifluoromethyloxirane(TFMOx) is studied experimentally and theoretically for different photoelectron kinetic energies. The experiments were performed employing circularly polarized synchrotron radiation and coincidentelectron and fragment ion detection using Cold Target Recoil Ion Momentum Spectroscopy. The corresponding calculations were performed by means of the Single Center method within the relaxed-core Hartree-Fock approximation. We concentrate on the energy dependence of the differential PECD of uniaxially orient"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2106.08071","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2106.08071/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T03:10:10Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"XOijP9LCs5E+vmb8Q2bClo/XanTNaS8va5GwdKs0r/l+Dcyn1VeGfDEPuawhog/FN1mO7ZIppOu1Sn8FeiICDg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-04T14:52:26.788049Z"},"content_sha256":"a0eb70e28dd1bbc07d7ad54de4bf5d81d5358a4e1e4a5327b8e42f5d51b8d865","schema_version":"1.0","event_id":"sha256:a0eb70e28dd1bbc07d7ad54de4bf5d81d5358a4e1e4a5327b8e42f5d51b8d865"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/OAVWZTOHEPT7LAGN6TGENZHL6B/bundle.json","state_url":"https://pith.science/pith/OAVWZTOHEPT7LAGN6TGENZHL6B/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/OAVWZTOHEPT7LAGN6TGENZHL6B/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-08-04T14:52:26Z","links":{"resolver":"https://pith.science/pith/OAVWZTOHEPT7LAGN6TGENZHL6B","bundle":"https://pith.science/pith/OAVWZTOHEPT7LAGN6TGENZHL6B/bundle.json","state":"https://pith.science/pith/OAVWZTOHEPT7LAGN6TGENZHL6B/state.json","well_known_bundle":"https://pith.science/.well-known/pith/OAVWZTOHEPT7LAGN6TGENZHL6B/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2021:OAVWZTOHEPT7LAGN6TGENZHL6B","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"de9dd015ff42bb78536d5720773950acd53c8b547082a961f841da85ca3da480","cross_cats_sorted":["physics.atm-clus"],"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"physics.chem-ph","submitted_at":"2021-06-15T11:55:14Z","title_canon_sha256":"b288645cb467cd58dc65c07fa378224cd549d0113abb13142b303591ec86a88a"},"schema_version":"1.0","source":{"id":"2106.08071","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2106.08071","created_at":"2026-07-05T03:10:10Z"},{"alias_kind":"arxiv_version","alias_value":"2106.08071v1","created_at":"2026-07-05T03:10:10Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2106.08071","created_at":"2026-07-05T03:10:10Z"},{"alias_kind":"pith_short_12","alias_value":"OAVWZTOHEPT7","created_at":"2026-07-05T03:10:10Z"},{"alias_kind":"pith_short_16","alias_value":"OAVWZTOHEPT7LAGN","created_at":"2026-07-05T03:10:10Z"},{"alias_kind":"pith_short_8","alias_value":"OAVWZTOH","created_at":"2026-07-05T03:10:10Z"}],"graph_snapshots":[{"event_id":"sha256:a0eb70e28dd1bbc07d7ad54de4bf5d81d5358a4e1e4a5327b8e42f5d51b8d865","target":"graph","created_at":"2026-07-05T03:10:10Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2106.08071/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"The photoelectron circular dichroism (PECD) of the O 1s-photoelectrons of trifluoromethyloxirane(TFMOx) is studied experimentally and theoretically for different photoelectron kinetic energies. The experiments were performed employing circularly polarized synchrotron radiation and coincidentelectron and fragment ion detection using Cold Target Recoil Ion Momentum Spectroscopy. The corresponding calculations were performed by means of the Single Center method within the relaxed-core Hartree-Fock approximation. We concentrate on the energy dependence of the differential PECD of uniaxially orient","authors_text":"A. Khan, A. Knie, C. K\\\"ustner-Wetekam, D. Kargin, D. Trabert, F. Trinter, G. Nalin, H. Fukuzawa, I. Vela-Perez, J. Viehmann, J. Williams, K. Fehre, K. Ueda, L. Marder, M. Hofmann, M. Ilchen, M. Kircher, M. Maurer, M. S. Sch\\\"offler, M. Waitz, N. Anders, N. M. Novikovskiy, Ph. V. Demekhin, R. D\\\"orner, R. Pietschnig, R. Tomar, S. Grundmann, T. Jahnke","cross_cats":["physics.atm-clus"],"headline":"","license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"physics.chem-ph","submitted_at":"2021-06-15T11:55:14Z","title":"Photoelectron circular dichroism of O 1$s$-photoelectrons of uniaxially oriented trifluoromethyloxirane: Energy dependence and sensitivity to molecular configuration"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2106.08071","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:dd7681564627722d292a52e5e702069919ce327b545c01b26cde159935a45eb1","target":"record","created_at":"2026-07-05T03:10:10Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"de9dd015ff42bb78536d5720773950acd53c8b547082a961f841da85ca3da480","cross_cats_sorted":["physics.atm-clus"],"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"physics.chem-ph","submitted_at":"2021-06-15T11:55:14Z","title_canon_sha256":"b288645cb467cd58dc65c07fa378224cd549d0113abb13142b303591ec86a88a"},"schema_version":"1.0","source":{"id":"2106.08071","kind":"arxiv","version":1}},"canonical_sha256":"702b6ccdc723e7f580cdf4cc46e4ebf05f482ab1bd1112e647c321df51f1baa3","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"702b6ccdc723e7f580cdf4cc46e4ebf05f482ab1bd1112e647c321df51f1baa3","first_computed_at":"2026-07-05T03:10:10.712993Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-05T03:10:10.712993Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"s/4h1UqEv/xUiolCXxSwRuzp5Uo9XNaOwC8xW30Z2p1BFM4hFVKxLJYkqAh4Ya2stlFwGkuw0pZ5Ea3d0zcGBg==","signature_status":"signed_v1","signed_at":"2026-07-05T03:10:10.713490Z","signed_message":"canonical_sha256_bytes"},"source_id":"2106.08071","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:dd7681564627722d292a52e5e702069919ce327b545c01b26cde159935a45eb1","sha256:a0eb70e28dd1bbc07d7ad54de4bf5d81d5358a4e1e4a5327b8e42f5d51b8d865"],"state_sha256":"7de9e51da838875d8e1b011d364e3c0135dc95bb4b8b8fb6630099c19c0c982c"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"j9XXHX7u8ytTQGb61RsUmiduwIdSAjOEn3NJ/JWr8sEEApDu9gbYW98zzgNTNMlY219K6wPPEFmO87vWMheTBw==","signed_message":"bundle_sha256_bytes","signed_at":"2026-08-04T14:52:26.793350Z","bundle_sha256":"a01bb45d92a6a777d723ff17c48f95bc35442c5f8f4af232f65e61e080780bcc"}}