{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2014:P5I6GRWWJH2HBRTRLVI6JEMFWW","short_pith_number":"pith:P5I6GRWW","canonical_record":{"source":{"id":"1404.5166","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2014-04-21T10:33:21Z","cross_cats_sorted":[],"title_canon_sha256":"321755f93e7386724d24056ea3ac23544f83817b4c8807d75c5d542f8e89d2d9","abstract_canon_sha256":"415c9b08b9473a59f943116e9228c282861c0c38222faa55b583ffcee7dcacb1"},"schema_version":"1.0"},"canonical_sha256":"7f51e346d649f470c6715d51e49185b59ec9aecc25a0c05589b8c814455a4118","source":{"kind":"arxiv","id":"1404.5166","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1404.5166","created_at":"2026-05-18T02:44:08Z"},{"alias_kind":"arxiv_version","alias_value":"1404.5166v1","created_at":"2026-05-18T02:44:08Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1404.5166","created_at":"2026-05-18T02:44:08Z"},{"alias_kind":"pith_short_12","alias_value":"P5I6GRWWJH2H","created_at":"2026-05-18T12:28:43Z"},{"alias_kind":"pith_short_16","alias_value":"P5I6GRWWJH2HBRTR","created_at":"2026-05-18T12:28:43Z"},{"alias_kind":"pith_short_8","alias_value":"P5I6GRWW","created_at":"2026-05-18T12:28:43Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2014:P5I6GRWWJH2HBRTRLVI6JEMFWW","target":"record","payload":{"canonical_record":{"source":{"id":"1404.5166","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2014-04-21T10:33:21Z","cross_cats_sorted":[],"title_canon_sha256":"321755f93e7386724d24056ea3ac23544f83817b4c8807d75c5d542f8e89d2d9","abstract_canon_sha256":"415c9b08b9473a59f943116e9228c282861c0c38222faa55b583ffcee7dcacb1"},"schema_version":"1.0"},"canonical_sha256":"7f51e346d649f470c6715d51e49185b59ec9aecc25a0c05589b8c814455a4118","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T02:44:08.219352Z","signature_b64":"hy8IOItb4wf5yOddDf31UFUsHvyKuLAr73wHupuihPAGn7fapbT9NtW+B5TB9oKmCxO43PYrB3dIJyhQbDkKAA==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"7f51e346d649f470c6715d51e49185b59ec9aecc25a0c05589b8c814455a4118","last_reissued_at":"2026-05-18T02:44:08.218917Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T02:44:08.218917Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1404.5166","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T02:44:08Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"KDLRG9NDQ0QqLYO9NUB+CDYRj3Cfh9wAAPcyWhl7wifzg+nbQx+o9phqewePy40/fup7gfi2bFKIQx3XegSuAA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-03T11:03:28.594123Z"},"content_sha256":"b06ed10311ed2ec0776f758f37fc2f6e94d4cddcad806c70c0d77c44c5a7b27a","schema_version":"1.0","event_id":"sha256:b06ed10311ed2ec0776f758f37fc2f6e94d4cddcad806c70c0d77c44c5a7b27a"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2014:P5I6GRWWJH2HBRTRLVI6JEMFWW","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Quasiparticle level alignment for photocatalytic interfaces","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Angel Rubio, Annapaoala Migani, Duncan J. Mowbray, Hrvoje Petek, Jin Zhao","submitted_at":"2014-04-21T10:33:21Z","abstract_excerpt":"Electronic level alignment at the interface between an adsorbed molecular layer and a semiconducting substrate determines the activity and efficiency of many photocatalytic materials. Standard density functional theory (DFT) based methods have proven unable to provide a quantitative description of this level alignment. This requires a proper treatment of the anisotropic screening, necessitating the use of quasiparticle (QP) techniques. However, the computational complexity of QP algorithms has meant a quantitative description of interfacial levels has remained elusive. We provide a systematic "},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1404.5166","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T02:44:08Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"NCGXeaU0N4+sqOJzIK3lquaxCHnad2hvEJggWWUjYG58F4UQMkbo1jDNKXU+pctF0+pxsVK/vujx7Bg2cs9qCg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-03T11:03:28.594486Z"},"content_sha256":"acc0a961decf4d21eeab798218481565161947e140b7c6a0d737c9a2e4e8b2d1","schema_version":"1.0","event_id":"sha256:acc0a961decf4d21eeab798218481565161947e140b7c6a0d737c9a2e4e8b2d1"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/P5I6GRWWJH2HBRTRLVI6JEMFWW/bundle.json","state_url":"https://pith.science/pith/P5I6GRWWJH2HBRTRLVI6JEMFWW/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/P5I6GRWWJH2HBRTRLVI6JEMFWW/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-03T11:03:28Z","links":{"resolver":"https://pith.science/pith/P5I6GRWWJH2HBRTRLVI6JEMFWW","bundle":"https://pith.science/pith/P5I6GRWWJH2HBRTRLVI6JEMFWW/bundle.json","state":"https://pith.science/pith/P5I6GRWWJH2HBRTRLVI6JEMFWW/state.json","well_known_bundle":"https://pith.science/.well-known/pith/P5I6GRWWJH2HBRTRLVI6JEMFWW/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2014:P5I6GRWWJH2HBRTRLVI6JEMFWW","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"415c9b08b9473a59f943116e9228c282861c0c38222faa55b583ffcee7dcacb1","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2014-04-21T10:33:21Z","title_canon_sha256":"321755f93e7386724d24056ea3ac23544f83817b4c8807d75c5d542f8e89d2d9"},"schema_version":"1.0","source":{"id":"1404.5166","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1404.5166","created_at":"2026-05-18T02:44:08Z"},{"alias_kind":"arxiv_version","alias_value":"1404.5166v1","created_at":"2026-05-18T02:44:08Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1404.5166","created_at":"2026-05-18T02:44:08Z"},{"alias_kind":"pith_short_12","alias_value":"P5I6GRWWJH2H","created_at":"2026-05-18T12:28:43Z"},{"alias_kind":"pith_short_16","alias_value":"P5I6GRWWJH2HBRTR","created_at":"2026-05-18T12:28:43Z"},{"alias_kind":"pith_short_8","alias_value":"P5I6GRWW","created_at":"2026-05-18T12:28:43Z"}],"graph_snapshots":[{"event_id":"sha256:acc0a961decf4d21eeab798218481565161947e140b7c6a0d737c9a2e4e8b2d1","target":"graph","created_at":"2026-05-18T02:44:08Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"Electronic level alignment at the interface between an adsorbed molecular layer and a semiconducting substrate determines the activity and efficiency of many photocatalytic materials. Standard density functional theory (DFT) based methods have proven unable to provide a quantitative description of this level alignment. This requires a proper treatment of the anisotropic screening, necessitating the use of quasiparticle (QP) techniques. However, the computational complexity of QP algorithms has meant a quantitative description of interfacial levels has remained elusive. We provide a systematic ","authors_text":"Angel Rubio, Annapaoala Migani, Duncan J. Mowbray, Hrvoje Petek, Jin Zhao","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2014-04-21T10:33:21Z","title":"Quasiparticle level alignment for photocatalytic interfaces"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1404.5166","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:b06ed10311ed2ec0776f758f37fc2f6e94d4cddcad806c70c0d77c44c5a7b27a","target":"record","created_at":"2026-05-18T02:44:08Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"415c9b08b9473a59f943116e9228c282861c0c38222faa55b583ffcee7dcacb1","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2014-04-21T10:33:21Z","title_canon_sha256":"321755f93e7386724d24056ea3ac23544f83817b4c8807d75c5d542f8e89d2d9"},"schema_version":"1.0","source":{"id":"1404.5166","kind":"arxiv","version":1}},"canonical_sha256":"7f51e346d649f470c6715d51e49185b59ec9aecc25a0c05589b8c814455a4118","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"7f51e346d649f470c6715d51e49185b59ec9aecc25a0c05589b8c814455a4118","first_computed_at":"2026-05-18T02:44:08.218917Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T02:44:08.218917Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"hy8IOItb4wf5yOddDf31UFUsHvyKuLAr73wHupuihPAGn7fapbT9NtW+B5TB9oKmCxO43PYrB3dIJyhQbDkKAA==","signature_status":"signed_v1","signed_at":"2026-05-18T02:44:08.219352Z","signed_message":"canonical_sha256_bytes"},"source_id":"1404.5166","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:b06ed10311ed2ec0776f758f37fc2f6e94d4cddcad806c70c0d77c44c5a7b27a","sha256:acc0a961decf4d21eeab798218481565161947e140b7c6a0d737c9a2e4e8b2d1"],"state_sha256":"1ab2333150b5ab919164ceee18cb3d819b47307185f5986baf7b0f87cc40a07c"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"W8YM4zvYJQAH91wXBwLTpfhN3m6idWpD76TqmXImBVuZUbrBQXCo/5dJ+91Y2+wK9mT+baioJJTJAhkWPrhnCw==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-03T11:03:28.596739Z","bundle_sha256":"16e6e7efc85258506f6929dbcdd733cbffbec1a95e1bd6b3a558aa398962c99b"}}