{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2016:PAHGM5TYW2ZH6GQW7VJMCLUILW","short_pith_number":"pith:PAHGM5TY","canonical_record":{"source":{"id":"1611.03150","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2016-11-10T01:29:52Z","cross_cats_sorted":["cond-mat.mes-hall"],"title_canon_sha256":"0ed4b3bbdcb3a46501a8c2a3eccd3439ce154cb1e062903f16d701c23475f395","abstract_canon_sha256":"561c4b2b324c0f8d3664fb13349dc51f8788c9b08bae41e751847923d66a8bb3"},"schema_version":"1.0"},"canonical_sha256":"780e667678b6b27f1a16fd52c12e885da10966f257ec4aeeb82b8fc569975a1b","source":{"kind":"arxiv","id":"1611.03150","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1611.03150","created_at":"2026-05-18T00:54:27Z"},{"alias_kind":"arxiv_version","alias_value":"1611.03150v1","created_at":"2026-05-18T00:54:27Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1611.03150","created_at":"2026-05-18T00:54:27Z"},{"alias_kind":"pith_short_12","alias_value":"PAHGM5TYW2ZH","created_at":"2026-05-18T12:30:39Z"},{"alias_kind":"pith_short_16","alias_value":"PAHGM5TYW2ZH6GQW","created_at":"2026-05-18T12:30:39Z"},{"alias_kind":"pith_short_8","alias_value":"PAHGM5TY","created_at":"2026-05-18T12:30:39Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2016:PAHGM5TYW2ZH6GQW7VJMCLUILW","target":"record","payload":{"canonical_record":{"source":{"id":"1611.03150","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2016-11-10T01:29:52Z","cross_cats_sorted":["cond-mat.mes-hall"],"title_canon_sha256":"0ed4b3bbdcb3a46501a8c2a3eccd3439ce154cb1e062903f16d701c23475f395","abstract_canon_sha256":"561c4b2b324c0f8d3664fb13349dc51f8788c9b08bae41e751847923d66a8bb3"},"schema_version":"1.0"},"canonical_sha256":"780e667678b6b27f1a16fd52c12e885da10966f257ec4aeeb82b8fc569975a1b","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T00:54:27.669894Z","signature_b64":"g5APUIx+d5ujckLTBlBfUIJq7lL3Y2rA8KtkIrzIsXTWfWBrIjznc75tNaL5v206EP9ZDPMZQ4K8tghFHOThCA==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"780e667678b6b27f1a16fd52c12e885da10966f257ec4aeeb82b8fc569975a1b","last_reissued_at":"2026-05-18T00:54:27.669166Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T00:54:27.669166Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1611.03150","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:54:27Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"NdCN7y7y7/5M4jnhabdUH7hWhPmk0EmVe9OvXGsBjIHBoywpkZaihQqqVwGjQuhdNPRFmF/Z3XplAuzDnBPCAg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-21T11:59:37.550941Z"},"content_sha256":"20171487c9a18eabd1fe3fa6a9ca3668b787db54cc5767170108c2d1eafac46f","schema_version":"1.0","event_id":"sha256:20171487c9a18eabd1fe3fa6a9ca3668b787db54cc5767170108c2d1eafac46f"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2016:PAHGM5TYW2ZH6GQW7VJMCLUILW","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Superintermolecular orbitals in the C$_{60}$/pentacene complex","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["cond-mat.mes-hall"],"primary_cat":"cond-mat.mtrl-sci","authors_text":"A. Gardner, G. P. Zhang, K. Drake, T. Latta, Y. H. Bai","submitted_at":"2016-11-10T01:29:52Z","abstract_excerpt":"We report a group of unusually big molecular orbitals in the C60/pentacene complex. Our first-principles density functional calculation shows that these orbitals are very delocalized and cover both C60 and pentacene, which we call superintermolecular orbitals or SIMOs. Their spatial extension can reach 1 nm or larger. Optically, SIMOs are dark. Different from ordinary unoccupied molecular orbitals, SIMOs have a very weak Coulomb and exchange interaction. Their energy levels are very similar to the native superatomic molecular orbitals in C60, and can be approximately characterized by orbital a"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1611.03150","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:54:27Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"QjpElJTYW3LOpBH8V3P5i4osUIiWLCTZisyThNAFxS1WMZaepMD6tohTNrrKnpQet9zGhR8CRHBFjcf7r+41Aw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-21T11:59:37.551291Z"},"content_sha256":"4bdc2e324d2197ddc65e3688d3981a77b47f2286c7e5a767757f39a56c611c8d","schema_version":"1.0","event_id":"sha256:4bdc2e324d2197ddc65e3688d3981a77b47f2286c7e5a767757f39a56c611c8d"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/PAHGM5TYW2ZH6GQW7VJMCLUILW/bundle.json","state_url":"https://pith.science/pith/PAHGM5TYW2ZH6GQW7VJMCLUILW/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/PAHGM5TYW2ZH6GQW7VJMCLUILW/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-05-21T11:59:37Z","links":{"resolver":"https://pith.science/pith/PAHGM5TYW2ZH6GQW7VJMCLUILW","bundle":"https://pith.science/pith/PAHGM5TYW2ZH6GQW7VJMCLUILW/bundle.json","state":"https://pith.science/pith/PAHGM5TYW2ZH6GQW7VJMCLUILW/state.json","well_known_bundle":"https://pith.science/.well-known/pith/PAHGM5TYW2ZH6GQW7VJMCLUILW/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2016:PAHGM5TYW2ZH6GQW7VJMCLUILW","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"561c4b2b324c0f8d3664fb13349dc51f8788c9b08bae41e751847923d66a8bb3","cross_cats_sorted":["cond-mat.mes-hall"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2016-11-10T01:29:52Z","title_canon_sha256":"0ed4b3bbdcb3a46501a8c2a3eccd3439ce154cb1e062903f16d701c23475f395"},"schema_version":"1.0","source":{"id":"1611.03150","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1611.03150","created_at":"2026-05-18T00:54:27Z"},{"alias_kind":"arxiv_version","alias_value":"1611.03150v1","created_at":"2026-05-18T00:54:27Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1611.03150","created_at":"2026-05-18T00:54:27Z"},{"alias_kind":"pith_short_12","alias_value":"PAHGM5TYW2ZH","created_at":"2026-05-18T12:30:39Z"},{"alias_kind":"pith_short_16","alias_value":"PAHGM5TYW2ZH6GQW","created_at":"2026-05-18T12:30:39Z"},{"alias_kind":"pith_short_8","alias_value":"PAHGM5TY","created_at":"2026-05-18T12:30:39Z"}],"graph_snapshots":[{"event_id":"sha256:4bdc2e324d2197ddc65e3688d3981a77b47f2286c7e5a767757f39a56c611c8d","target":"graph","created_at":"2026-05-18T00:54:27Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"We report a group of unusually big molecular orbitals in the C60/pentacene complex. Our first-principles density functional calculation shows that these orbitals are very delocalized and cover both C60 and pentacene, which we call superintermolecular orbitals or SIMOs. Their spatial extension can reach 1 nm or larger. Optically, SIMOs are dark. Different from ordinary unoccupied molecular orbitals, SIMOs have a very weak Coulomb and exchange interaction. Their energy levels are very similar to the native superatomic molecular orbitals in C60, and can be approximately characterized by orbital a","authors_text":"A. Gardner, G. P. Zhang, K. Drake, T. Latta, Y. H. Bai","cross_cats":["cond-mat.mes-hall"],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2016-11-10T01:29:52Z","title":"Superintermolecular orbitals in the C$_{60}$/pentacene complex"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1611.03150","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:20171487c9a18eabd1fe3fa6a9ca3668b787db54cc5767170108c2d1eafac46f","target":"record","created_at":"2026-05-18T00:54:27Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"561c4b2b324c0f8d3664fb13349dc51f8788c9b08bae41e751847923d66a8bb3","cross_cats_sorted":["cond-mat.mes-hall"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2016-11-10T01:29:52Z","title_canon_sha256":"0ed4b3bbdcb3a46501a8c2a3eccd3439ce154cb1e062903f16d701c23475f395"},"schema_version":"1.0","source":{"id":"1611.03150","kind":"arxiv","version":1}},"canonical_sha256":"780e667678b6b27f1a16fd52c12e885da10966f257ec4aeeb82b8fc569975a1b","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"780e667678b6b27f1a16fd52c12e885da10966f257ec4aeeb82b8fc569975a1b","first_computed_at":"2026-05-18T00:54:27.669166Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T00:54:27.669166Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"g5APUIx+d5ujckLTBlBfUIJq7lL3Y2rA8KtkIrzIsXTWfWBrIjznc75tNaL5v206EP9ZDPMZQ4K8tghFHOThCA==","signature_status":"signed_v1","signed_at":"2026-05-18T00:54:27.669894Z","signed_message":"canonical_sha256_bytes"},"source_id":"1611.03150","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:20171487c9a18eabd1fe3fa6a9ca3668b787db54cc5767170108c2d1eafac46f","sha256:4bdc2e324d2197ddc65e3688d3981a77b47f2286c7e5a767757f39a56c611c8d"],"state_sha256":"930f961ff26d26ddac7495840b6e0c0bf587441f2c200ca36c61c09a86bb2b79"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"LyezMGnh2K0HHQonHXak4iTFmUHj20iOPBvxfel5gQTVxnLdT/DWV7di6CrV8+/dcR/Tyl7YorpitxQdLEVzAw==","signed_message":"bundle_sha256_bytes","signed_at":"2026-05-21T11:59:37.553529Z","bundle_sha256":"283dfa5f0296a04527e33c100c9f3a621c6ae9bccc06161ef300e9e01d5535b9"}}