{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2015:PE6BGS4QDJWHUDOKECALXLTOLE","short_pith_number":"pith:PE6BGS4Q","canonical_record":{"source":{"id":"1506.03331","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2015-06-10T14:46:59Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"847bb58e12e37022a97bd7ef94c86076eb6bbf9c82a4d26c42b347f5e003b207","abstract_canon_sha256":"5942834f3468a7368894da539688e7c6827cd06219471fff8bb174cc604cbd29"},"schema_version":"1.0"},"canonical_sha256":"793c134b901a6c7a0dca2080bbae6e590a36b685d76595080bbbdc3910b4ec5c","source":{"kind":"arxiv","id":"1506.03331","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1506.03331","created_at":"2026-05-18T01:27:23Z"},{"alias_kind":"arxiv_version","alias_value":"1506.03331v1","created_at":"2026-05-18T01:27:23Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1506.03331","created_at":"2026-05-18T01:27:23Z"},{"alias_kind":"pith_short_12","alias_value":"PE6BGS4QDJWH","created_at":"2026-05-18T12:29:37Z"},{"alias_kind":"pith_short_16","alias_value":"PE6BGS4QDJWHUDOK","created_at":"2026-05-18T12:29:37Z"},{"alias_kind":"pith_short_8","alias_value":"PE6BGS4Q","created_at":"2026-05-18T12:29:37Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2015:PE6BGS4QDJWHUDOKECALXLTOLE","target":"record","payload":{"canonical_record":{"source":{"id":"1506.03331","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2015-06-10T14:46:59Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"847bb58e12e37022a97bd7ef94c86076eb6bbf9c82a4d26c42b347f5e003b207","abstract_canon_sha256":"5942834f3468a7368894da539688e7c6827cd06219471fff8bb174cc604cbd29"},"schema_version":"1.0"},"canonical_sha256":"793c134b901a6c7a0dca2080bbae6e590a36b685d76595080bbbdc3910b4ec5c","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T01:27:23.480858Z","signature_b64":"DQPXVRbJ6/fn7oSpLfX2B0ck8FrCLBG5UBKxXzL6W7X3LLHK8qa6QiXxNzaLQRCuSL+pkzx3Hw+elIzHMCEsAg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"793c134b901a6c7a0dca2080bbae6e590a36b685d76595080bbbdc3910b4ec5c","last_reissued_at":"2026-05-18T01:27:23.480374Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T01:27:23.480374Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1506.03331","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T01:27:23Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"tz7mRBbN7UlcokLy5ImrTGkS+O3rc/HAnHO08Y144jMCA444f00Lne41fUT03sPuS/uA4PtNQ69poPZgjMIXDA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-09T02:03:02.759918Z"},"content_sha256":"e68bbf901fb6d2a1abd026d01359377f68be1068511ea600bdac42d1d322d36d","schema_version":"1.0","event_id":"sha256:e68bbf901fb6d2a1abd026d01359377f68be1068511ea600bdac42d1d322d36d"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2015:PE6BGS4QDJWHUDOKECALXLTOLE","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Cavity-induced modifications of molecular structure in the strong coupling regime","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"quant-ph","authors_text":"Francisco J. Garcia-Vidal, Javier Galego, Johannes Feist","submitted_at":"2015-06-10T14:46:59Z","abstract_excerpt":"In most theoretical descriptions of collective strong coupling of organic molecules to a cavity mode, the molecules are modeled as simple two-level systems. This picture fails to describe the rich structure provided by their internal rovibrational (nuclear) degrees of freedom. We investigate a first-principles model that fully takes into account both electronic and nuclear degrees of freedom, allowing an exploration of the phenomenon of strong coupling from an entirely new perspective. First, we demonstrate the limitations of applicability of the Born-Oppenheimer approximation in strongly coup"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1506.03331","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T01:27:23Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"BZbnas9ebl10Kta5g1hvnaOxM67m/BY2WCCb+FFzMhOntyGP19B6g/xqKfIXyvANQ2698e+OLfkd6hiGUDYZDA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-09T02:03:02.760641Z"},"content_sha256":"664d218c3456fa79cc5c1078f4903027d0ad92f4465eb6f9682bafc44be507c9","schema_version":"1.0","event_id":"sha256:664d218c3456fa79cc5c1078f4903027d0ad92f4465eb6f9682bafc44be507c9"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/PE6BGS4QDJWHUDOKECALXLTOLE/bundle.json","state_url":"https://pith.science/pith/PE6BGS4QDJWHUDOKECALXLTOLE/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/PE6BGS4QDJWHUDOKECALXLTOLE/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-09T02:03:02Z","links":{"resolver":"https://pith.science/pith/PE6BGS4QDJWHUDOKECALXLTOLE","bundle":"https://pith.science/pith/PE6BGS4QDJWHUDOKECALXLTOLE/bundle.json","state":"https://pith.science/pith/PE6BGS4QDJWHUDOKECALXLTOLE/state.json","well_known_bundle":"https://pith.science/.well-known/pith/PE6BGS4QDJWHUDOKECALXLTOLE/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2015:PE6BGS4QDJWHUDOKECALXLTOLE","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"5942834f3468a7368894da539688e7c6827cd06219471fff8bb174cc604cbd29","cross_cats_sorted":["physics.chem-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2015-06-10T14:46:59Z","title_canon_sha256":"847bb58e12e37022a97bd7ef94c86076eb6bbf9c82a4d26c42b347f5e003b207"},"schema_version":"1.0","source":{"id":"1506.03331","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1506.03331","created_at":"2026-05-18T01:27:23Z"},{"alias_kind":"arxiv_version","alias_value":"1506.03331v1","created_at":"2026-05-18T01:27:23Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1506.03331","created_at":"2026-05-18T01:27:23Z"},{"alias_kind":"pith_short_12","alias_value":"PE6BGS4QDJWH","created_at":"2026-05-18T12:29:37Z"},{"alias_kind":"pith_short_16","alias_value":"PE6BGS4QDJWHUDOK","created_at":"2026-05-18T12:29:37Z"},{"alias_kind":"pith_short_8","alias_value":"PE6BGS4Q","created_at":"2026-05-18T12:29:37Z"}],"graph_snapshots":[{"event_id":"sha256:664d218c3456fa79cc5c1078f4903027d0ad92f4465eb6f9682bafc44be507c9","target":"graph","created_at":"2026-05-18T01:27:23Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"In most theoretical descriptions of collective strong coupling of organic molecules to a cavity mode, the molecules are modeled as simple two-level systems. This picture fails to describe the rich structure provided by their internal rovibrational (nuclear) degrees of freedom. We investigate a first-principles model that fully takes into account both electronic and nuclear degrees of freedom, allowing an exploration of the phenomenon of strong coupling from an entirely new perspective. First, we demonstrate the limitations of applicability of the Born-Oppenheimer approximation in strongly coup","authors_text":"Francisco J. Garcia-Vidal, Javier Galego, Johannes Feist","cross_cats":["physics.chem-ph"],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2015-06-10T14:46:59Z","title":"Cavity-induced modifications of molecular structure in the strong coupling regime"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1506.03331","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:e68bbf901fb6d2a1abd026d01359377f68be1068511ea600bdac42d1d322d36d","target":"record","created_at":"2026-05-18T01:27:23Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"5942834f3468a7368894da539688e7c6827cd06219471fff8bb174cc604cbd29","cross_cats_sorted":["physics.chem-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2015-06-10T14:46:59Z","title_canon_sha256":"847bb58e12e37022a97bd7ef94c86076eb6bbf9c82a4d26c42b347f5e003b207"},"schema_version":"1.0","source":{"id":"1506.03331","kind":"arxiv","version":1}},"canonical_sha256":"793c134b901a6c7a0dca2080bbae6e590a36b685d76595080bbbdc3910b4ec5c","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"793c134b901a6c7a0dca2080bbae6e590a36b685d76595080bbbdc3910b4ec5c","first_computed_at":"2026-05-18T01:27:23.480374Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T01:27:23.480374Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"DQPXVRbJ6/fn7oSpLfX2B0ck8FrCLBG5UBKxXzL6W7X3LLHK8qa6QiXxNzaLQRCuSL+pkzx3Hw+elIzHMCEsAg==","signature_status":"signed_v1","signed_at":"2026-05-18T01:27:23.480858Z","signed_message":"canonical_sha256_bytes"},"source_id":"1506.03331","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:e68bbf901fb6d2a1abd026d01359377f68be1068511ea600bdac42d1d322d36d","sha256:664d218c3456fa79cc5c1078f4903027d0ad92f4465eb6f9682bafc44be507c9"],"state_sha256":"d90dccb76c395bc776cc00118d25864494125367136c73a2b67dec5f853191ac"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"BHfSuQyPqi5twEGolOx7gantHj4E+QYU2kUENHCxKSzMQ8fLIU3jsdscS9wHfMyhQ9MYufXOzFEHIApgugcZDw==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-09T02:03:02.764708Z","bundle_sha256":"e104e05fbb9042ff964ff9f08f5442695a2ac924d3a436ebf70f5eecc957f555"}}