{"record_type":"pith_number_record","schema_url":"https://pith.science/schemas/pith-number/v1.json","pith_number":"pith:2016:PYSSBIHMTGWXEUL2E62DWJVMJR","short_pith_number":"pith:PYSSBIHM","schema_version":"1.0","canonical_sha256":"7e2520a0ec99ad72517a27b43b26ac4c7882cbd03a41e83feca4fa114c22a401","source":{"kind":"arxiv","id":"1610.06838","version":1},"attestation_state":"computed","paper":{"title":"Enhancing Cation Diffusion and Suppressing Anion Diffusion via Lewis-Acidic Polymer Electrolytes","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["cond-mat.mes-hall","cond-mat.mtrl-sci","cond-mat.soft"],"primary_cat":"physics.chem-ph","authors_text":"Brett M. Savoie, Michael A. Webb, Thomas F. Miller III","submitted_at":"2016-10-20T17:06:50Z","abstract_excerpt":"Solid polymer electrolytes (SPE) have the potential to increase both the energy density and stability of lithium-based batteries, but low Li-ion conductivity remains a barrier to technological viability. SPEs are designed to maximize Li-ion diffusivity relative to the anion, while maintaining sufficient salt solubility. It is thus remarkable that polyethylene oxide (PEO), the most widely used SPE, exhibits Li-ion diffusivity that is an order of magnitude smaller than that of typical counter-ions, such as TFSI, at moderate salt concentrations. Here, we show that Lewis-basic polymers like PEO in"},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"1610.06838","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-10-20T17:06:50Z","cross_cats_sorted":["cond-mat.mes-hall","cond-mat.mtrl-sci","cond-mat.soft"],"title_canon_sha256":"06fa94bba11e6bb837f94e4a202b859325f548d42ffaf988742195ee3313f0a7","abstract_canon_sha256":"a180bc96927c49ba71b575fe3a7f647793832f16ec98881594ef044ce01da612"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T00:52:22.581788Z","signature_b64":"f4THVQG4mJ2pIF62QFHkGND4JM129BK1Phhz7MnRhZoy6AhVSf9EDhc63h1opDFd3WRctmPXldPE7x+lm+3CCg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"7e2520a0ec99ad72517a27b43b26ac4c7882cbd03a41e83feca4fa114c22a401","last_reissued_at":"2026-05-18T00:52:22.581014Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T00:52:22.581014Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"Enhancing Cation Diffusion and Suppressing Anion Diffusion via Lewis-Acidic Polymer Electrolytes","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["cond-mat.mes-hall","cond-mat.mtrl-sci","cond-mat.soft"],"primary_cat":"physics.chem-ph","authors_text":"Brett M. Savoie, Michael A. Webb, Thomas F. Miller III","submitted_at":"2016-10-20T17:06:50Z","abstract_excerpt":"Solid polymer electrolytes (SPE) have the potential to increase both the energy density and stability of lithium-based batteries, but low Li-ion conductivity remains a barrier to technological viability. SPEs are designed to maximize Li-ion diffusivity relative to the anion, while maintaining sufficient salt solubility. It is thus remarkable that polyethylene oxide (PEO), the most widely used SPE, exhibits Li-ion diffusivity that is an order of magnitude smaller than that of typical counter-ions, such as TFSI, at moderate salt concentrations. Here, we show that Lewis-basic polymers like PEO in"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1610.06838","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"aliases":[{"alias_kind":"arxiv","alias_value":"1610.06838","created_at":"2026-05-18T00:52:22.581154+00:00"},{"alias_kind":"arxiv_version","alias_value":"1610.06838v1","created_at":"2026-05-18T00:52:22.581154+00:00"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1610.06838","created_at":"2026-05-18T00:52:22.581154+00:00"},{"alias_kind":"pith_short_12","alias_value":"PYSSBIHMTGWX","created_at":"2026-05-18T12:30:39.010887+00:00"},{"alias_kind":"pith_short_16","alias_value":"PYSSBIHMTGWXEUL2","created_at":"2026-05-18T12:30:39.010887+00:00"},{"alias_kind":"pith_short_8","alias_value":"PYSSBIHM","created_at":"2026-05-18T12:30:39.010887+00:00"}],"events":[],"event_summary":{},"paper_claims":[],"inbound_citations":{"count":0,"internal_anchor_count":0,"sample":[]},"formal_canon":{"evidence_count":0,"sample":[],"anchors":[]},"links":{"html":"https://pith.science/pith/PYSSBIHMTGWXEUL2E62DWJVMJR","json":"https://pith.science/pith/PYSSBIHMTGWXEUL2E62DWJVMJR.json","graph_json":"https://pith.science/api/pith-number/PYSSBIHMTGWXEUL2E62DWJVMJR/graph.json","events_json":"https://pith.science/api/pith-number/PYSSBIHMTGWXEUL2E62DWJVMJR/events.json","paper":"https://pith.science/paper/PYSSBIHM"},"agent_actions":{"view_html":"https://pith.science/pith/PYSSBIHMTGWXEUL2E62DWJVMJR","download_json":"https://pith.science/pith/PYSSBIHMTGWXEUL2E62DWJVMJR.json","view_paper":"https://pith.science/paper/PYSSBIHM","resolve_alias":"https://pith.science/api/pith-number/resolve?arxiv=1610.06838&json=true","fetch_graph":"https://pith.science/api/pith-number/PYSSBIHMTGWXEUL2E62DWJVMJR/graph.json","fetch_events":"https://pith.science/api/pith-number/PYSSBIHMTGWXEUL2E62DWJVMJR/events.json","actions":{"anchor_timestamp":"https://pith.science/pith/PYSSBIHMTGWXEUL2E62DWJVMJR/action/timestamp_anchor","attest_storage":"https://pith.science/pith/PYSSBIHMTGWXEUL2E62DWJVMJR/action/storage_attestation","attest_author":"https://pith.science/pith/PYSSBIHMTGWXEUL2E62DWJVMJR/action/author_attestation","sign_citation":"https://pith.science/pith/PYSSBIHMTGWXEUL2E62DWJVMJR/action/citation_signature","submit_replication":"https://pith.science/pith/PYSSBIHMTGWXEUL2E62DWJVMJR/action/replication_record"}},"created_at":"2026-05-18T00:52:22.581154+00:00","updated_at":"2026-05-18T00:52:22.581154+00:00"}