{"record_type":"pith_number_record","schema_url":"https://pith.science/schemas/pith-number/v1.json","pith_number":"pith:2023:Q5I6AIMYSWHACKBLCOJBGTVJVV","short_pith_number":"pith:Q5I6AIMY","schema_version":"1.0","canonical_sha256":"8751e02198958e01282b1392134ea9ad69916ae0e91e6c64dc928cda69fb0c34","source":{"kind":"arxiv","id":"2304.12170","version":2},"attestation_state":"computed","paper":{"title":"On Using Non-Kekule' Triangular Graphene Quantum Dots for Scavenging Hazardous Sulfur Hexafluoride Components","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["cond-mat.mtrl-sci"],"primary_cat":"physics.chem-ph","authors_text":"Alok Shukla, Basant Roondhe, Rajeev Ahuja, Sumit Saxena, Vaishali Roondhe","submitted_at":"2023-04-24T15:28:25Z","abstract_excerpt":"The goal of the present study is to explore how the size and functionalization of graphene quantum dots (GQDs) affect their sensing capabilities. Specifically, we investigated the adsorption of SO$_2$, SOF$_2$, SO$_2$F$_2$, and SF$_6$ on GQDs that were functionalized with -CH$_3$, - COCH$_3$, and -NH$_2$. We used density functional theory to analyze the electronic properties of these functionalized GQDs and found that the functionalization significantly altered their electronic properties. For example, the B3LYP H-L gap of pristine triangulene was 3.9eV, while the H-L gap of functionalized tri"},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"2304.12170","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2023-04-24T15:28:25Z","cross_cats_sorted":["cond-mat.mtrl-sci"],"title_canon_sha256":"ffb1285b8e124ff51c01a285cfe09a908b0291d259017d2747071a6f9078e2be","abstract_canon_sha256":"2f827db0e8a6c6bd7dc27257502e56dcccd35346e6c158750ce3979182c4f09a"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T06:04:15.152185Z","signature_b64":"vYHJm8DkdpklYr1MNwfsPD9OwbDQZnTvD+oX/rexxLG/ZKJR5qlzw02qw4FaDUkwTt6Cm1s3PH5mX8yMEtnnCA==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"8751e02198958e01282b1392134ea9ad69916ae0e91e6c64dc928cda69fb0c34","last_reissued_at":"2026-07-05T06:04:15.151727Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T06:04:15.151727Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"On Using Non-Kekule' Triangular Graphene Quantum Dots for Scavenging Hazardous Sulfur Hexafluoride Components","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["cond-mat.mtrl-sci"],"primary_cat":"physics.chem-ph","authors_text":"Alok Shukla, Basant Roondhe, Rajeev Ahuja, Sumit Saxena, Vaishali Roondhe","submitted_at":"2023-04-24T15:28:25Z","abstract_excerpt":"The goal of the present study is to explore how the size and functionalization of graphene quantum dots (GQDs) affect their sensing capabilities. Specifically, we investigated the adsorption of SO$_2$, SOF$_2$, SO$_2$F$_2$, and SF$_6$ on GQDs that were functionalized with -CH$_3$, - COCH$_3$, and -NH$_2$. We used density functional theory to analyze the electronic properties of these functionalized GQDs and found that the functionalization significantly altered their electronic properties. For example, the B3LYP H-L gap of pristine triangulene was 3.9eV, while the H-L gap of functionalized tri"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2304.12170","kind":"arxiv","version":2},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2304.12170/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"aliases":[{"alias_kind":"arxiv","alias_value":"2304.12170","created_at":"2026-07-05T06:04:15.151785+00:00"},{"alias_kind":"arxiv_version","alias_value":"2304.12170v2","created_at":"2026-07-05T06:04:15.151785+00:00"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2304.12170","created_at":"2026-07-05T06:04:15.151785+00:00"},{"alias_kind":"pith_short_12","alias_value":"Q5I6AIMYSWHA","created_at":"2026-07-05T06:04:15.151785+00:00"},{"alias_kind":"pith_short_16","alias_value":"Q5I6AIMYSWHACKBL","created_at":"2026-07-05T06:04:15.151785+00:00"},{"alias_kind":"pith_short_8","alias_value":"Q5I6AIMY","created_at":"2026-07-05T06:04:15.151785+00:00"}],"events":[],"event_summary":{},"paper_claims":[],"inbound_citations":{"count":0,"internal_anchor_count":0,"sample":[]},"formal_canon":{"evidence_count":0,"sample":[],"anchors":[]},"links":{"html":"https://pith.science/pith/Q5I6AIMYSWHACKBLCOJBGTVJVV","json":"https://pith.science/pith/Q5I6AIMYSWHACKBLCOJBGTVJVV.json","graph_json":"https://pith.science/api/pith-number/Q5I6AIMYSWHACKBLCOJBGTVJVV/graph.json","events_json":"https://pith.science/api/pith-number/Q5I6AIMYSWHACKBLCOJBGTVJVV/events.json","paper":"https://pith.science/paper/Q5I6AIMY"},"agent_actions":{"view_html":"https://pith.science/pith/Q5I6AIMYSWHACKBLCOJBGTVJVV","download_json":"https://pith.science/pith/Q5I6AIMYSWHACKBLCOJBGTVJVV.json","view_paper":"https://pith.science/paper/Q5I6AIMY","resolve_alias":"https://pith.science/api/pith-number/resolve?arxiv=2304.12170&json=true","fetch_graph":"https://pith.science/api/pith-number/Q5I6AIMYSWHACKBLCOJBGTVJVV/graph.json","fetch_events":"https://pith.science/api/pith-number/Q5I6AIMYSWHACKBLCOJBGTVJVV/events.json","actions":{"anchor_timestamp":"https://pith.science/pith/Q5I6AIMYSWHACKBLCOJBGTVJVV/action/timestamp_anchor","attest_storage":"https://pith.science/pith/Q5I6AIMYSWHACKBLCOJBGTVJVV/action/storage_attestation","attest_author":"https://pith.science/pith/Q5I6AIMYSWHACKBLCOJBGTVJVV/action/author_attestation","sign_citation":"https://pith.science/pith/Q5I6AIMYSWHACKBLCOJBGTVJVV/action/citation_signature","submit_replication":"https://pith.science/pith/Q5I6AIMYSWHACKBLCOJBGTVJVV/action/replication_record"}},"created_at":"2026-07-05T06:04:15.151785+00:00","updated_at":"2026-07-05T06:04:15.151785+00:00"}