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At the onset of the Ti deposition, a downward band-bending was observed on ZnO(000$\\bar{1}$)-O while no change occurred on ZnO(0001)-Zn. Combining this with the photoemission analysis of the Ti 2p core level and Zn L$_3$(L$_2$)M$_{45}$M$_{45}$ Auger transition, it is established that the Ti/ZnO reaction is of the form Ti + 2 ZnO $\\rightarrow$ TiO$_2$ + 2 Zn on ZnO(0001)-Zn and Ti + y ZnO $\\rightarrow$ TiZn$_x$O$_y$ + (y-x) Zn on ZnO(000$\\bar{"},"verification_status":{"content_addressed":true,"pith_receipt":true,"author_attested":false,"weak_author_claims":0,"strong_author_claims":0,"externally_anchored":false,"storage_verified":false,"citation_signatures":0,"replication_records":0,"graph_snapshot":true,"references_resolved":false,"formal_links_present":false},"canonical_record":{"source":{"id":"1805.10608","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2018-05-27T11:19:15Z","cross_cats_sorted":[],"title_canon_sha256":"c9a88740361cbb456a4855b85ebe27047404c9d26d3735ebf6495276389e22ad","abstract_canon_sha256":"d4b543bc89f611273ab1c156303065e74727ba7c24f6725c512cb5335c667d39"},"schema_version":"1.0"},"receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T00:14:51.933408Z","signature_b64":"/j7Gma9TEYOlHK/kX8N82KZu3r02KOuhTKPrRrZQZRsDnEO/cLV1WnM3npUfBqlD4SX2Cmn7uClOM+QAAKKLDQ==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"8b11c95a7f4226fbbe9ffd460f1bacc0d09eaafc186577873c5bd0ae6e340dbb","last_reissued_at":"2026-05-18T00:14:51.932881Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T00:14:51.932881Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"graph_snapshot":{"paper":{"title":"Orientation-dependent chemistry and band-bending of Ti on polar ZnO surfaces","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"G. 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