{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2016:S6BH4BK4YL5ZJQ7WYFIMIJO2KW","short_pith_number":"pith:S6BH4BK4","canonical_record":{"source":{"id":"1604.05852","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2016-04-20T08:27:20Z","cross_cats_sorted":[],"title_canon_sha256":"26a7492da15434c04057c8e21fd56a62134b28f16e089ad2c902a49cd9befebe","abstract_canon_sha256":"95ca8b44f062cb53b3d3bbf47ba29cd145154ae932c336805b379171b0714a3f"},"schema_version":"1.0"},"canonical_sha256":"97827e055cc2fb94c3f6c150c425da5593e1625ec821099162ddd2b1a3c29eb4","source":{"kind":"arxiv","id":"1604.05852","version":2},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1604.05852","created_at":"2026-05-18T01:16:32Z"},{"alias_kind":"arxiv_version","alias_value":"1604.05852v2","created_at":"2026-05-18T01:16:32Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1604.05852","created_at":"2026-05-18T01:16:32Z"},{"alias_kind":"pith_short_12","alias_value":"S6BH4BK4YL5Z","created_at":"2026-05-18T12:30:44Z"},{"alias_kind":"pith_short_16","alias_value":"S6BH4BK4YL5ZJQ7W","created_at":"2026-05-18T12:30:44Z"},{"alias_kind":"pith_short_8","alias_value":"S6BH4BK4","created_at":"2026-05-18T12:30:44Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2016:S6BH4BK4YL5ZJQ7WYFIMIJO2KW","target":"record","payload":{"canonical_record":{"source":{"id":"1604.05852","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2016-04-20T08:27:20Z","cross_cats_sorted":[],"title_canon_sha256":"26a7492da15434c04057c8e21fd56a62134b28f16e089ad2c902a49cd9befebe","abstract_canon_sha256":"95ca8b44f062cb53b3d3bbf47ba29cd145154ae932c336805b379171b0714a3f"},"schema_version":"1.0"},"canonical_sha256":"97827e055cc2fb94c3f6c150c425da5593e1625ec821099162ddd2b1a3c29eb4","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T01:16:32.650763Z","signature_b64":"NSUAZbrDoKWKctRHM/XJAhrVx1hgMfiTh9HBIEfETeyIQklWVvsCSdDYqb3Ldxn1UJLepwdocqqw+4EkgjnEAQ==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"97827e055cc2fb94c3f6c150c425da5593e1625ec821099162ddd2b1a3c29eb4","last_reissued_at":"2026-05-18T01:16:32.650139Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T01:16:32.650139Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1604.05852","source_version":2,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T01:16:32Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"20V0GpEw50T7xHE4TleeI7caGpFnkgIXRLhyuo5U8YuloLVWyCde3bFhw+jLf5Mt5CO3S6eOYB+DzqS1fsEyCA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-08T21:48:55.973886Z"},"content_sha256":"61e91851e4fd135e9dfcf0be386aa204bd2d06f21ade7717fcb15033155a8ec8","schema_version":"1.0","event_id":"sha256:61e91851e4fd135e9dfcf0be386aa204bd2d06f21ade7717fcb15033155a8ec8"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2016:S6BH4BK4YL5ZJQ7WYFIMIJO2KW","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"The conducting spin-crossover compound combining Fe(II) cation complex with TCNQ in a fractional reduction state","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Aleksander V. Korolyov, Alexander I. Kotov, Denis V. Starichenko, Eduard B. Yagubskii, Konstantin A. Lyssenko, Lev I. Buravov, Ludmila G. Lavrenova, Olga G. Shakirova, Vladimir N Zverev, Yuri N. Shvachko","submitted_at":"2016-04-20T08:27:20Z","abstract_excerpt":"The radical anion salt [Fe{HC(pz)3}2](TCNQ)3 demonstrating conductivity and spin-crossover transition (SCO) associated with Fe(II) complex cation subsystem has been synthesized and structurally characterized. A pronounced change of the dc resistivity and a robust broadening of the EPR signal triggered by the SCO transition are found. Enhanced EPR line broadening is interpreted in terms of cross relaxation between the TCNQ and Fe(II) spin subsystems"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1604.05852","kind":"arxiv","version":2},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T01:16:32Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"yeIpoUJNlc/T58lRB3ceMRhcXH2HEuXyTMTWlCEKubjQAQxprfFKu80NQAvekKkstFH3lfdxchL5QgqHZNDaCQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-08T21:48:55.974239Z"},"content_sha256":"6e4a295704920faf9f07f0c482d46e37fe56805da2e124e376c80546c3d70523","schema_version":"1.0","event_id":"sha256:6e4a295704920faf9f07f0c482d46e37fe56805da2e124e376c80546c3d70523"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/S6BH4BK4YL5ZJQ7WYFIMIJO2KW/bundle.json","state_url":"https://pith.science/pith/S6BH4BK4YL5ZJQ7WYFIMIJO2KW/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/S6BH4BK4YL5ZJQ7WYFIMIJO2KW/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-08T21:48:55Z","links":{"resolver":"https://pith.science/pith/S6BH4BK4YL5ZJQ7WYFIMIJO2KW","bundle":"https://pith.science/pith/S6BH4BK4YL5ZJQ7WYFIMIJO2KW/bundle.json","state":"https://pith.science/pith/S6BH4BK4YL5ZJQ7WYFIMIJO2KW/state.json","well_known_bundle":"https://pith.science/.well-known/pith/S6BH4BK4YL5ZJQ7WYFIMIJO2KW/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2016:S6BH4BK4YL5ZJQ7WYFIMIJO2KW","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"95ca8b44f062cb53b3d3bbf47ba29cd145154ae932c336805b379171b0714a3f","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2016-04-20T08:27:20Z","title_canon_sha256":"26a7492da15434c04057c8e21fd56a62134b28f16e089ad2c902a49cd9befebe"},"schema_version":"1.0","source":{"id":"1604.05852","kind":"arxiv","version":2}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1604.05852","created_at":"2026-05-18T01:16:32Z"},{"alias_kind":"arxiv_version","alias_value":"1604.05852v2","created_at":"2026-05-18T01:16:32Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1604.05852","created_at":"2026-05-18T01:16:32Z"},{"alias_kind":"pith_short_12","alias_value":"S6BH4BK4YL5Z","created_at":"2026-05-18T12:30:44Z"},{"alias_kind":"pith_short_16","alias_value":"S6BH4BK4YL5ZJQ7W","created_at":"2026-05-18T12:30:44Z"},{"alias_kind":"pith_short_8","alias_value":"S6BH4BK4","created_at":"2026-05-18T12:30:44Z"}],"graph_snapshots":[{"event_id":"sha256:6e4a295704920faf9f07f0c482d46e37fe56805da2e124e376c80546c3d70523","target":"graph","created_at":"2026-05-18T01:16:32Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"The radical anion salt [Fe{HC(pz)3}2](TCNQ)3 demonstrating conductivity and spin-crossover transition (SCO) associated with Fe(II) complex cation subsystem has been synthesized and structurally characterized. A pronounced change of the dc resistivity and a robust broadening of the EPR signal triggered by the SCO transition are found. Enhanced EPR line broadening is interpreted in terms of cross relaxation between the TCNQ and Fe(II) spin subsystems","authors_text":"Aleksander V. Korolyov, Alexander I. Kotov, Denis V. Starichenko, Eduard B. Yagubskii, Konstantin A. Lyssenko, Lev I. Buravov, Ludmila G. Lavrenova, Olga G. Shakirova, Vladimir N Zverev, Yuri N. Shvachko","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2016-04-20T08:27:20Z","title":"The conducting spin-crossover compound combining Fe(II) cation complex with TCNQ in a fractional reduction state"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1604.05852","kind":"arxiv","version":2},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:61e91851e4fd135e9dfcf0be386aa204bd2d06f21ade7717fcb15033155a8ec8","target":"record","created_at":"2026-05-18T01:16:32Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"95ca8b44f062cb53b3d3bbf47ba29cd145154ae932c336805b379171b0714a3f","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2016-04-20T08:27:20Z","title_canon_sha256":"26a7492da15434c04057c8e21fd56a62134b28f16e089ad2c902a49cd9befebe"},"schema_version":"1.0","source":{"id":"1604.05852","kind":"arxiv","version":2}},"canonical_sha256":"97827e055cc2fb94c3f6c150c425da5593e1625ec821099162ddd2b1a3c29eb4","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"97827e055cc2fb94c3f6c150c425da5593e1625ec821099162ddd2b1a3c29eb4","first_computed_at":"2026-05-18T01:16:32.650139Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T01:16:32.650139Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"NSUAZbrDoKWKctRHM/XJAhrVx1hgMfiTh9HBIEfETeyIQklWVvsCSdDYqb3Ldxn1UJLepwdocqqw+4EkgjnEAQ==","signature_status":"signed_v1","signed_at":"2026-05-18T01:16:32.650763Z","signed_message":"canonical_sha256_bytes"},"source_id":"1604.05852","source_kind":"arxiv","source_version":2}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:61e91851e4fd135e9dfcf0be386aa204bd2d06f21ade7717fcb15033155a8ec8","sha256:6e4a295704920faf9f07f0c482d46e37fe56805da2e124e376c80546c3d70523"],"state_sha256":"676da0018d870bc4bbc096ebcad308d47608a1963c402a63da4aa55d3548a5b3"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"tf0J+zk334gJdts0aiUY/theSgRDzPyOirvfc10BKS8JsnAJ6rCB31iX7/HFlyR08Ml9po16R+uTr4Ay69tUDw==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-08T21:48:55.976069Z","bundle_sha256":"99631ee4e7cea96a011237e14d5a04c128520f76df558b3feeea265cc9d25279"}}