{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2004:SFAC3EMTIXFXLX5YGAQU6QA2OC","short_pith_number":"pith:SFAC3EMT","canonical_record":{"source":{"id":"physics/0408042","kind":"arxiv","version":4},"metadata":{"license":"","primary_cat":"physics.chem-ph","submitted_at":"2004-08-09T18:08:01Z","cross_cats_sorted":[],"title_canon_sha256":"44d584dd89949579d4b2994da8a458140c704dbfd06af3c115d05fb6fb3b786f","abstract_canon_sha256":"f9177f65362fe63e1fc2aa1616b07e205859ffaebd04d86a6ae7f6025ef8c78c"},"schema_version":"1.0"},"canonical_sha256":"91402d919345cb75dfb830214f401a70b2c52974214689950361f92f9f8f44de","source":{"kind":"arxiv","id":"physics/0408042","version":4},"source_aliases":[{"alias_kind":"arxiv","alias_value":"physics/0408042","created_at":"2026-07-04T16:49:55Z"},{"alias_kind":"arxiv_version","alias_value":"physics/0408042v4","created_at":"2026-07-04T16:49:55Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.physics/0408042","created_at":"2026-07-04T16:49:55Z"},{"alias_kind":"pith_short_12","alias_value":"SFAC3EMTIXFX","created_at":"2026-07-04T16:49:55Z"},{"alias_kind":"pith_short_16","alias_value":"SFAC3EMTIXFXLX5Y","created_at":"2026-07-04T16:49:55Z"},{"alias_kind":"pith_short_8","alias_value":"SFAC3EMT","created_at":"2026-07-04T16:49:55Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2004:SFAC3EMTIXFXLX5YGAQU6QA2OC","target":"record","payload":{"canonical_record":{"source":{"id":"physics/0408042","kind":"arxiv","version":4},"metadata":{"license":"","primary_cat":"physics.chem-ph","submitted_at":"2004-08-09T18:08:01Z","cross_cats_sorted":[],"title_canon_sha256":"44d584dd89949579d4b2994da8a458140c704dbfd06af3c115d05fb6fb3b786f","abstract_canon_sha256":"f9177f65362fe63e1fc2aa1616b07e205859ffaebd04d86a6ae7f6025ef8c78c"},"schema_version":"1.0"},"canonical_sha256":"91402d919345cb75dfb830214f401a70b2c52974214689950361f92f9f8f44de","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-04T16:49:55.166189Z","signature_b64":"wgY1a4yXuHQgZZNBx3+883yrtvzlc2YiliKTh6fY5ZkZ29xU7aPHI4SRa+XVYZ7jqyrsLkfHSnZmt3skL/6qAA==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"91402d919345cb75dfb830214f401a70b2c52974214689950361f92f9f8f44de","last_reissued_at":"2026-07-04T16:49:55.165755Z","signature_status":"signed_v1","first_computed_at":"2026-07-04T16:49:55.165755Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"physics/0408042","source_version":4,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-04T16:49:55Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"tIVI9pXE4fNpTojqpNeVu9mKsKJVf7qCevsMNUWYxNRyHhOmsv1V3Rb911p5wKbB1GKSjd1j7oCvZELGxySvCg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-07-07T12:12:02.636423Z"},"content_sha256":"e11f3bdb8c7545db392f5e1cbbf7ef3a35ce16a8e18acb21f9a45863522fadd1","schema_version":"1.0","event_id":"sha256:e11f3bdb8c7545db392f5e1cbbf7ef3a35ce16a8e18acb21f9a45863522fadd1"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2004:SFAC3EMTIXFXLX5YGAQU6QA2OC","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Core excitation in Ozone localized to one of two symmetry-equivalent chemical bonds - molecular alignment through vibronic coupling","license":"","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"A. Naves de Brito, K. Wiesner, N. Kosugi, O. Bjorneholm, S. L. Sorensen","submitted_at":"2004-08-09T18:08:01Z","abstract_excerpt":"Core excitation from terminal oxygen O$_T$ in O$_3$ is shown to be an excitation from a localized core orbital to a localized valence orbital. The valence orbital is localized to one of the two equivalent chemical bonds. We experimentally demonstrate this with the Auger Doppler effect which is observable when O$_3$ is core-excited to the highly dissociative O$_{T}$1s$^{-1}$7a$_1^1$ state. Auger electrons emitted from the atomic oxygen fragment carry information about the molecular orientation relative to the electromagnetic field vector at the moment of excitation. The data together with analy"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"physics/0408042","kind":"arxiv","version":4},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/physics/0408042/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-04T16:49:55Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"Er1ewylRJiSTvoKuXGQPz0FO8y7oHTz3dKTPNqTyiszrqCxu+YN7/KFKycU+wXIDqVZIcKcCpVXXPxc150o1AA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-07-07T12:12:02.636795Z"},"content_sha256":"1d72a717183d9f0443f02859e35e01650a2e534daf8b604d1baacd29c042a482","schema_version":"1.0","event_id":"sha256:1d72a717183d9f0443f02859e35e01650a2e534daf8b604d1baacd29c042a482"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/SFAC3EMTIXFXLX5YGAQU6QA2OC/bundle.json","state_url":"https://pith.science/pith/SFAC3EMTIXFXLX5YGAQU6QA2OC/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/SFAC3EMTIXFXLX5YGAQU6QA2OC/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-07-07T12:12:02Z","links":{"resolver":"https://pith.science/pith/SFAC3EMTIXFXLX5YGAQU6QA2OC","bundle":"https://pith.science/pith/SFAC3EMTIXFXLX5YGAQU6QA2OC/bundle.json","state":"https://pith.science/pith/SFAC3EMTIXFXLX5YGAQU6QA2OC/state.json","well_known_bundle":"https://pith.science/.well-known/pith/SFAC3EMTIXFXLX5YGAQU6QA2OC/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2004:SFAC3EMTIXFXLX5YGAQU6QA2OC","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"f9177f65362fe63e1fc2aa1616b07e205859ffaebd04d86a6ae7f6025ef8c78c","cross_cats_sorted":[],"license":"","primary_cat":"physics.chem-ph","submitted_at":"2004-08-09T18:08:01Z","title_canon_sha256":"44d584dd89949579d4b2994da8a458140c704dbfd06af3c115d05fb6fb3b786f"},"schema_version":"1.0","source":{"id":"physics/0408042","kind":"arxiv","version":4}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"physics/0408042","created_at":"2026-07-04T16:49:55Z"},{"alias_kind":"arxiv_version","alias_value":"physics/0408042v4","created_at":"2026-07-04T16:49:55Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.physics/0408042","created_at":"2026-07-04T16:49:55Z"},{"alias_kind":"pith_short_12","alias_value":"SFAC3EMTIXFX","created_at":"2026-07-04T16:49:55Z"},{"alias_kind":"pith_short_16","alias_value":"SFAC3EMTIXFXLX5Y","created_at":"2026-07-04T16:49:55Z"},{"alias_kind":"pith_short_8","alias_value":"SFAC3EMT","created_at":"2026-07-04T16:49:55Z"}],"graph_snapshots":[{"event_id":"sha256:1d72a717183d9f0443f02859e35e01650a2e534daf8b604d1baacd29c042a482","target":"graph","created_at":"2026-07-04T16:49:55Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/physics/0408042/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"Core excitation from terminal oxygen O$_T$ in O$_3$ is shown to be an excitation from a localized core orbital to a localized valence orbital. The valence orbital is localized to one of the two equivalent chemical bonds. We experimentally demonstrate this with the Auger Doppler effect which is observable when O$_3$ is core-excited to the highly dissociative O$_{T}$1s$^{-1}$7a$_1^1$ state. Auger electrons emitted from the atomic oxygen fragment carry information about the molecular orientation relative to the electromagnetic field vector at the moment of excitation. The data together with analy","authors_text":"A. Naves de Brito, K. Wiesner, N. Kosugi, O. Bjorneholm, S. L. Sorensen","cross_cats":[],"headline":"","license":"","primary_cat":"physics.chem-ph","submitted_at":"2004-08-09T18:08:01Z","title":"Core excitation in Ozone localized to one of two symmetry-equivalent chemical bonds - molecular alignment through vibronic coupling"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"physics/0408042","kind":"arxiv","version":4},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:e11f3bdb8c7545db392f5e1cbbf7ef3a35ce16a8e18acb21f9a45863522fadd1","target":"record","created_at":"2026-07-04T16:49:55Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"f9177f65362fe63e1fc2aa1616b07e205859ffaebd04d86a6ae7f6025ef8c78c","cross_cats_sorted":[],"license":"","primary_cat":"physics.chem-ph","submitted_at":"2004-08-09T18:08:01Z","title_canon_sha256":"44d584dd89949579d4b2994da8a458140c704dbfd06af3c115d05fb6fb3b786f"},"schema_version":"1.0","source":{"id":"physics/0408042","kind":"arxiv","version":4}},"canonical_sha256":"91402d919345cb75dfb830214f401a70b2c52974214689950361f92f9f8f44de","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"91402d919345cb75dfb830214f401a70b2c52974214689950361f92f9f8f44de","first_computed_at":"2026-07-04T16:49:55.165755Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-04T16:49:55.165755Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"wgY1a4yXuHQgZZNBx3+883yrtvzlc2YiliKTh6fY5ZkZ29xU7aPHI4SRa+XVYZ7jqyrsLkfHSnZmt3skL/6qAA==","signature_status":"signed_v1","signed_at":"2026-07-04T16:49:55.166189Z","signed_message":"canonical_sha256_bytes"},"source_id":"physics/0408042","source_kind":"arxiv","source_version":4}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:e11f3bdb8c7545db392f5e1cbbf7ef3a35ce16a8e18acb21f9a45863522fadd1","sha256:1d72a717183d9f0443f02859e35e01650a2e534daf8b604d1baacd29c042a482"],"state_sha256":"b07e3543f86ad222d585e356c2854712ed3850c370918e2d16c20f89f161ab3d"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"jS+DhdxyUWmCzdYpXOWFKVNZwCmHnPS0NmKMFO3wk8J2CeebZDC6pJPiIeuSQJsuuQUdrdP9f18RQDpNFWNzAg==","signed_message":"bundle_sha256_bytes","signed_at":"2026-07-07T12:12:02.638897Z","bundle_sha256":"023da7450464984441bfb75a3e5974aa45f3e624f1577fe6c890d50b898f09ad"}}