{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2017:SPRR5NOYLVJOTZMXONOIJF232C","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"ca1b3bdedbd1707ce8f981eca56eadbcaae679648cc9a9591b2edc9634331c4a","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2017-10-13T23:04:52Z","title_canon_sha256":"ef8e764b3908147b91c9e7fb2acbb7634f6d24f19e75e17240cde152417c14e8"},"schema_version":"1.0","source":{"id":"1710.05097","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1710.05097","created_at":"2026-05-18T00:29:59Z"},{"alias_kind":"arxiv_version","alias_value":"1710.05097v1","created_at":"2026-05-18T00:29:59Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1710.05097","created_at":"2026-05-18T00:29:59Z"},{"alias_kind":"pith_short_12","alias_value":"SPRR5NOYLVJO","created_at":"2026-05-18T12:31:43Z"},{"alias_kind":"pith_short_16","alias_value":"SPRR5NOYLVJOTZMX","created_at":"2026-05-18T12:31:43Z"},{"alias_kind":"pith_short_8","alias_value":"SPRR5NOY","created_at":"2026-05-18T12:31:43Z"}],"graph_snapshots":[{"event_id":"sha256:1f3746f6b07955653de9fdd3c8a98a4e50b2796ff32a2671980c9a78a41fcd8b","target":"graph","created_at":"2026-05-18T00:29:59Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"Cation disorder is an important design criterion for technologically relevant transition-metal (TM) oxides, such as radiation-tolerant ceramics and Li-ion battery electrodes. In this letter, we use a combination of first-principles calculations, normal mode analysis, and band-structure arguments to pinpoint a specific electronic-structure effect that influences the stability of disordered phases. We find that the electronic configuration of a TM ion determines to which extent the structural energy is affected by site distortions. This mechanism explains the stability of disordered phases with ","authors_text":"Alexander Urban, Aziz Abdellahi, Gerbrand Ceder, Nongnuch Artrith, Stephen Dacek","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2017-10-13T23:04:52Z","title":"The electronic-structure origin of cation disorder in transition-metal oxides"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1710.05097","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:2da13cec943d8f8b5df58d183e16601d3985ea52a1babf5eeb1805d0a2799dbf","target":"record","created_at":"2026-05-18T00:29:59Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"ca1b3bdedbd1707ce8f981eca56eadbcaae679648cc9a9591b2edc9634331c4a","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2017-10-13T23:04:52Z","title_canon_sha256":"ef8e764b3908147b91c9e7fb2acbb7634f6d24f19e75e17240cde152417c14e8"},"schema_version":"1.0","source":{"id":"1710.05097","kind":"arxiv","version":1}},"canonical_sha256":"93e31eb5d85d52e9e597735c84975bd0ac9707569a9fed2c9e2af298783ef210","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"93e31eb5d85d52e9e597735c84975bd0ac9707569a9fed2c9e2af298783ef210","first_computed_at":"2026-05-18T00:29:59.401230Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T00:29:59.401230Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"NOq6jYvcMU/TZqbroCPKtLEbndf7KRPFiVWI3hWMf/gJ7bXNOb3mmxeBFrkzVjJsuVpV6Pe1hlvi6JcQU0GpBw==","signature_status":"signed_v1","signed_at":"2026-05-18T00:29:59.401767Z","signed_message":"canonical_sha256_bytes"},"source_id":"1710.05097","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:2da13cec943d8f8b5df58d183e16601d3985ea52a1babf5eeb1805d0a2799dbf","sha256:1f3746f6b07955653de9fdd3c8a98a4e50b2796ff32a2671980c9a78a41fcd8b"],"state_sha256":"7ac0254fc5fd0aeae6103d3f1ab646888466eef8de68fb41f8212f3b1b1e4e4b"}