{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2017:ST3NONPHCO3PWUQTDMDZOCG5UW","short_pith_number":"pith:ST3NONPH","canonical_record":{"source":{"id":"1707.09019","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.soft","submitted_at":"2017-07-23T20:34:04Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"30b114f24ac0d22bc75cbf29edfa675738d4011ae030eff417b5fbbf692f4b77","abstract_canon_sha256":"d36057db1836b84bdff657b9d550cc51beb63923a5779d53a9e53a69f7a77db3"},"schema_version":"1.0"},"canonical_sha256":"94f6d735e713b6fb52131b079708dda5aff608432edd712569b3796a668d12b6","source":{"kind":"arxiv","id":"1707.09019","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1707.09019","created_at":"2026-05-18T00:32:08Z"},{"alias_kind":"arxiv_version","alias_value":"1707.09019v1","created_at":"2026-05-18T00:32:08Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1707.09019","created_at":"2026-05-18T00:32:08Z"},{"alias_kind":"pith_short_12","alias_value":"ST3NONPHCO3P","created_at":"2026-05-18T12:31:43Z"},{"alias_kind":"pith_short_16","alias_value":"ST3NONPHCO3PWUQT","created_at":"2026-05-18T12:31:43Z"},{"alias_kind":"pith_short_8","alias_value":"ST3NONPH","created_at":"2026-05-18T12:31:43Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2017:ST3NONPHCO3PWUQTDMDZOCG5UW","target":"record","payload":{"canonical_record":{"source":{"id":"1707.09019","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.soft","submitted_at":"2017-07-23T20:34:04Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"30b114f24ac0d22bc75cbf29edfa675738d4011ae030eff417b5fbbf692f4b77","abstract_canon_sha256":"d36057db1836b84bdff657b9d550cc51beb63923a5779d53a9e53a69f7a77db3"},"schema_version":"1.0"},"canonical_sha256":"94f6d735e713b6fb52131b079708dda5aff608432edd712569b3796a668d12b6","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T00:32:08.228827Z","signature_b64":"ouh0P0rIKVy04TRkYq7jjsAfDQZMZHFVW0A1pERakQN7HtAbYCaxNdvga6qyBg8plBDyCTPkbLkjDa7XzkGVCg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"94f6d735e713b6fb52131b079708dda5aff608432edd712569b3796a668d12b6","last_reissued_at":"2026-05-18T00:32:08.228046Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T00:32:08.228046Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1707.09019","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:32:08Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"GVR8CvLKyg+T+BFGpN2loE7Ie8ZWmINkFo/A6XXD5ctR6UYCkz/++Q6flQ7emhrNpcx9fZogNNBUzx0PE3EmCQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-27T08:54:44.149825Z"},"content_sha256":"10ac0fbbd3078923fa14ba3beb1a6e0a21429a1308c5cda6e6fd33c62ca2a826","schema_version":"1.0","event_id":"sha256:10ac0fbbd3078923fa14ba3beb1a6e0a21429a1308c5cda6e6fd33c62ca2a826"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2017:ST3NONPHCO3PWUQTDMDZOCG5UW","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Quasichemical theory and the description of associating fluids relative to a reference: Multiple bonding of a single site solute","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"cond-mat.soft","authors_text":"Artee Bansal, D. Asthagiri, Walter G. Chapman","submitted_at":"2017-07-23T20:34:04Z","abstract_excerpt":"We derive an expression for the chemical potential of an associating solute in a solvent relative to the value in a reference fluid using the quasichemical organization of the potential distribution theorem. The fraction of times the solute is not associated with the solvent, the monomer fraction, is expressed in terms of (a) the statistics of occupancy of the solvent around the solute in the reference fluid and (b) the Widom factors that arise because of turning on solute-solvent association. Assuming pair-additivity, we expand the Widom factor into a product of Mayer f-functions and the resu"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1707.09019","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:32:08Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"87EgxtR7vKRVwy5MSHxR+vpN6h2VCOO6SkpodK5Cch/vfW1mfhGWA6uZXf1MDKUpbx7X0Mg2zkJN0i+/qFFcAA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-27T08:54:44.150683Z"},"content_sha256":"0c7e8921142e284e8ddc5496a8a36f42952d9b3f46c27516375c41d92fc6fa0d","schema_version":"1.0","event_id":"sha256:0c7e8921142e284e8ddc5496a8a36f42952d9b3f46c27516375c41d92fc6fa0d"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/ST3NONPHCO3PWUQTDMDZOCG5UW/bundle.json","state_url":"https://pith.science/pith/ST3NONPHCO3PWUQTDMDZOCG5UW/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/ST3NONPHCO3PWUQTDMDZOCG5UW/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-05-27T08:54:44Z","links":{"resolver":"https://pith.science/pith/ST3NONPHCO3PWUQTDMDZOCG5UW","bundle":"https://pith.science/pith/ST3NONPHCO3PWUQTDMDZOCG5UW/bundle.json","state":"https://pith.science/pith/ST3NONPHCO3PWUQTDMDZOCG5UW/state.json","well_known_bundle":"https://pith.science/.well-known/pith/ST3NONPHCO3PWUQTDMDZOCG5UW/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2017:ST3NONPHCO3PWUQTDMDZOCG5UW","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"d36057db1836b84bdff657b9d550cc51beb63923a5779d53a9e53a69f7a77db3","cross_cats_sorted":["physics.chem-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.soft","submitted_at":"2017-07-23T20:34:04Z","title_canon_sha256":"30b114f24ac0d22bc75cbf29edfa675738d4011ae030eff417b5fbbf692f4b77"},"schema_version":"1.0","source":{"id":"1707.09019","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1707.09019","created_at":"2026-05-18T00:32:08Z"},{"alias_kind":"arxiv_version","alias_value":"1707.09019v1","created_at":"2026-05-18T00:32:08Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1707.09019","created_at":"2026-05-18T00:32:08Z"},{"alias_kind":"pith_short_12","alias_value":"ST3NONPHCO3P","created_at":"2026-05-18T12:31:43Z"},{"alias_kind":"pith_short_16","alias_value":"ST3NONPHCO3PWUQT","created_at":"2026-05-18T12:31:43Z"},{"alias_kind":"pith_short_8","alias_value":"ST3NONPH","created_at":"2026-05-18T12:31:43Z"}],"graph_snapshots":[{"event_id":"sha256:0c7e8921142e284e8ddc5496a8a36f42952d9b3f46c27516375c41d92fc6fa0d","target":"graph","created_at":"2026-05-18T00:32:08Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"We derive an expression for the chemical potential of an associating solute in a solvent relative to the value in a reference fluid using the quasichemical organization of the potential distribution theorem. The fraction of times the solute is not associated with the solvent, the monomer fraction, is expressed in terms of (a) the statistics of occupancy of the solvent around the solute in the reference fluid and (b) the Widom factors that arise because of turning on solute-solvent association. Assuming pair-additivity, we expand the Widom factor into a product of Mayer f-functions and the resu","authors_text":"Artee Bansal, D. Asthagiri, Walter G. Chapman","cross_cats":["physics.chem-ph"],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.soft","submitted_at":"2017-07-23T20:34:04Z","title":"Quasichemical theory and the description of associating fluids relative to a reference: Multiple bonding of a single site solute"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1707.09019","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:10ac0fbbd3078923fa14ba3beb1a6e0a21429a1308c5cda6e6fd33c62ca2a826","target":"record","created_at":"2026-05-18T00:32:08Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"d36057db1836b84bdff657b9d550cc51beb63923a5779d53a9e53a69f7a77db3","cross_cats_sorted":["physics.chem-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.soft","submitted_at":"2017-07-23T20:34:04Z","title_canon_sha256":"30b114f24ac0d22bc75cbf29edfa675738d4011ae030eff417b5fbbf692f4b77"},"schema_version":"1.0","source":{"id":"1707.09019","kind":"arxiv","version":1}},"canonical_sha256":"94f6d735e713b6fb52131b079708dda5aff608432edd712569b3796a668d12b6","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"94f6d735e713b6fb52131b079708dda5aff608432edd712569b3796a668d12b6","first_computed_at":"2026-05-18T00:32:08.228046Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T00:32:08.228046Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"ouh0P0rIKVy04TRkYq7jjsAfDQZMZHFVW0A1pERakQN7HtAbYCaxNdvga6qyBg8plBDyCTPkbLkjDa7XzkGVCg==","signature_status":"signed_v1","signed_at":"2026-05-18T00:32:08.228827Z","signed_message":"canonical_sha256_bytes"},"source_id":"1707.09019","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:10ac0fbbd3078923fa14ba3beb1a6e0a21429a1308c5cda6e6fd33c62ca2a826","sha256:0c7e8921142e284e8ddc5496a8a36f42952d9b3f46c27516375c41d92fc6fa0d"],"state_sha256":"dfcfa2a7e6f57aa1fc78dc50d6f33312c51b2560c8048e70f9b635fd10156cba"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"NWIDuZBueSAwKMqbDigGBgJkNrDT0vqGwkVBWx7/haOJ17KCWO6BtN9bqy6N5xaIx6Q4MhBppv4Ai9qD+L7fAw==","signed_message":"bundle_sha256_bytes","signed_at":"2026-05-27T08:54:44.154965Z","bundle_sha256":"9e743204b79a28288c24b5d1193476cbaaa07a963a103c1eff0d0d77823dcceb"}}