{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2023:TAMS5NFB66GX2YIBZPTHPPLFNN","short_pith_number":"pith:TAMS5NFB","canonical_record":{"source":{"id":"2301.10399","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2023-01-25T03:43:00Z","cross_cats_sorted":[],"title_canon_sha256":"a42ba8033048d7a11b745a6c1fc9a8177b53efd85c15f8470cff293aba6b27c7","abstract_canon_sha256":"5fd30dbdff48bbdb138ee76fea51accefc93bff3b950a8b718a688dac70ca074"},"schema_version":"1.0"},"canonical_sha256":"98192eb4a1f78d7d6101cbe677bd656b665aa35232b75e07140185c951bf37aa","source":{"kind":"arxiv","id":"2301.10399","version":2},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2301.10399","created_at":"2026-07-05T10:03:22Z"},{"alias_kind":"arxiv_version","alias_value":"2301.10399v2","created_at":"2026-07-05T10:03:22Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2301.10399","created_at":"2026-07-05T10:03:22Z"},{"alias_kind":"pith_short_12","alias_value":"TAMS5NFB66GX","created_at":"2026-07-05T10:03:22Z"},{"alias_kind":"pith_short_16","alias_value":"TAMS5NFB66GX2YIB","created_at":"2026-07-05T10:03:22Z"},{"alias_kind":"pith_short_8","alias_value":"TAMS5NFB","created_at":"2026-07-05T10:03:22Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2023:TAMS5NFB66GX2YIBZPTHPPLFNN","target":"record","payload":{"canonical_record":{"source":{"id":"2301.10399","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2023-01-25T03:43:00Z","cross_cats_sorted":[],"title_canon_sha256":"a42ba8033048d7a11b745a6c1fc9a8177b53efd85c15f8470cff293aba6b27c7","abstract_canon_sha256":"5fd30dbdff48bbdb138ee76fea51accefc93bff3b950a8b718a688dac70ca074"},"schema_version":"1.0"},"canonical_sha256":"98192eb4a1f78d7d6101cbe677bd656b665aa35232b75e07140185c951bf37aa","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T10:03:22.460307Z","signature_b64":"+j4m4FkWzYZ4aOe14+xnnSfwoNQre5q5aUZ5weTN8B/+M7c6busoodTlkew6YyRTV9PgZsAZc/yzkc5wagJGAg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"98192eb4a1f78d7d6101cbe677bd656b665aa35232b75e07140185c951bf37aa","last_reissued_at":"2026-07-05T10:03:22.459928Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T10:03:22.459928Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"2301.10399","source_version":2,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T10:03:22Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"Nt35hdV4Zw4yaL67AIvFJsjj4TY9t9ndgswWftw1Y0l7KxQ5IRAJ5yLUTNP28ZkCD6fk7P3i8utZlSUno8DZDg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-07-06T22:27:48.895565Z"},"content_sha256":"bff84cb2f142e628664e3a2f551fc2db51118d473a915eb8aacbca4ee2759275","schema_version":"1.0","event_id":"sha256:bff84cb2f142e628664e3a2f551fc2db51118d473a915eb8aacbca4ee2759275"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2023:TAMS5NFB66GX2YIBZPTHPPLFNN","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Electrochemically induced switching from antiferromagnetic spin-chain to frustrated spin-glass state in maple-leaf lattice Na2Mn3O7","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Anirudh Adavi, Bachu Sravan Kumar, Corson Chao, Hari Ramachandran, Iwnetim I. Abate, Kevin H. Stone, Lilia S. Xie, Mark Asta, Ming Lei, Shivani Srivastava, Varun Kamboj, Zhelong Jiang","submitted_at":"2023-01-25T03:43:00Z","abstract_excerpt":"We report the electrochemical tuning of magnetic properties in the Na2Mn3O7 maple-leaf lattice (MLL) through ion deintercalation, revealing a switch from the 1D antiferromagnetic (AFM) spin-chain behavior of the S=3/2 MLL structure to frustrated magnetism spin-glass behavior. By utilizing Na deintercalation, we stabilize ferromagnetic (FM) short-range interactions within the original short-range AFM system, creating magnetic frustration within the system beyond that induced from the MLL geometrically frustrated structure, leading to a spin-glass state. Magnetic and structural analyses, combine"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2301.10399","kind":"arxiv","version":2},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2301.10399/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T10:03:22Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"Hp2ctRYqzpoHwzYdXEQtcZ6csn7xN+QBWPxi/j3IpY2dYKAGQ6HNv7NkB5bc+PEnVL1jDezXDHb1ZEMBObMtCw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-07-06T22:27:48.895940Z"},"content_sha256":"58e883d42e24cc5371d9d2c49689489c3a55341dfe68929a67500242b6ef3057","schema_version":"1.0","event_id":"sha256:58e883d42e24cc5371d9d2c49689489c3a55341dfe68929a67500242b6ef3057"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/TAMS5NFB66GX2YIBZPTHPPLFNN/bundle.json","state_url":"https://pith.science/pith/TAMS5NFB66GX2YIBZPTHPPLFNN/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/TAMS5NFB66GX2YIBZPTHPPLFNN/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-07-06T22:27:48Z","links":{"resolver":"https://pith.science/pith/TAMS5NFB66GX2YIBZPTHPPLFNN","bundle":"https://pith.science/pith/TAMS5NFB66GX2YIBZPTHPPLFNN/bundle.json","state":"https://pith.science/pith/TAMS5NFB66GX2YIBZPTHPPLFNN/state.json","well_known_bundle":"https://pith.science/.well-known/pith/TAMS5NFB66GX2YIBZPTHPPLFNN/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2023:TAMS5NFB66GX2YIBZPTHPPLFNN","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"5fd30dbdff48bbdb138ee76fea51accefc93bff3b950a8b718a688dac70ca074","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2023-01-25T03:43:00Z","title_canon_sha256":"a42ba8033048d7a11b745a6c1fc9a8177b53efd85c15f8470cff293aba6b27c7"},"schema_version":"1.0","source":{"id":"2301.10399","kind":"arxiv","version":2}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2301.10399","created_at":"2026-07-05T10:03:22Z"},{"alias_kind":"arxiv_version","alias_value":"2301.10399v2","created_at":"2026-07-05T10:03:22Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2301.10399","created_at":"2026-07-05T10:03:22Z"},{"alias_kind":"pith_short_12","alias_value":"TAMS5NFB66GX","created_at":"2026-07-05T10:03:22Z"},{"alias_kind":"pith_short_16","alias_value":"TAMS5NFB66GX2YIB","created_at":"2026-07-05T10:03:22Z"},{"alias_kind":"pith_short_8","alias_value":"TAMS5NFB","created_at":"2026-07-05T10:03:22Z"}],"graph_snapshots":[{"event_id":"sha256:58e883d42e24cc5371d9d2c49689489c3a55341dfe68929a67500242b6ef3057","target":"graph","created_at":"2026-07-05T10:03:22Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2301.10399/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"We report the electrochemical tuning of magnetic properties in the Na2Mn3O7 maple-leaf lattice (MLL) through ion deintercalation, revealing a switch from the 1D antiferromagnetic (AFM) spin-chain behavior of the S=3/2 MLL structure to frustrated magnetism spin-glass behavior. By utilizing Na deintercalation, we stabilize ferromagnetic (FM) short-range interactions within the original short-range AFM system, creating magnetic frustration within the system beyond that induced from the MLL geometrically frustrated structure, leading to a spin-glass state. Magnetic and structural analyses, combine","authors_text":"Anirudh Adavi, Bachu Sravan Kumar, Corson Chao, Hari Ramachandran, Iwnetim I. Abate, Kevin H. Stone, Lilia S. Xie, Mark Asta, Ming Lei, Shivani Srivastava, Varun Kamboj, Zhelong Jiang","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2023-01-25T03:43:00Z","title":"Electrochemically induced switching from antiferromagnetic spin-chain to frustrated spin-glass state in maple-leaf lattice Na2Mn3O7"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2301.10399","kind":"arxiv","version":2},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:bff84cb2f142e628664e3a2f551fc2db51118d473a915eb8aacbca4ee2759275","target":"record","created_at":"2026-07-05T10:03:22Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"5fd30dbdff48bbdb138ee76fea51accefc93bff3b950a8b718a688dac70ca074","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2023-01-25T03:43:00Z","title_canon_sha256":"a42ba8033048d7a11b745a6c1fc9a8177b53efd85c15f8470cff293aba6b27c7"},"schema_version":"1.0","source":{"id":"2301.10399","kind":"arxiv","version":2}},"canonical_sha256":"98192eb4a1f78d7d6101cbe677bd656b665aa35232b75e07140185c951bf37aa","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"98192eb4a1f78d7d6101cbe677bd656b665aa35232b75e07140185c951bf37aa","first_computed_at":"2026-07-05T10:03:22.459928Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-05T10:03:22.459928Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"+j4m4FkWzYZ4aOe14+xnnSfwoNQre5q5aUZ5weTN8B/+M7c6busoodTlkew6YyRTV9PgZsAZc/yzkc5wagJGAg==","signature_status":"signed_v1","signed_at":"2026-07-05T10:03:22.460307Z","signed_message":"canonical_sha256_bytes"},"source_id":"2301.10399","source_kind":"arxiv","source_version":2}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:bff84cb2f142e628664e3a2f551fc2db51118d473a915eb8aacbca4ee2759275","sha256:58e883d42e24cc5371d9d2c49689489c3a55341dfe68929a67500242b6ef3057"],"state_sha256":"acdbd1348ab5e26206c8844547cc0b6373d3c7e7742e2f39bdcb195aff6f01f9"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"30UGQ97QFg84ie6WSuNK1JtZwppIQeAdAM1xpizhkRIeQ8C0nXRUG/ODA2yQmDq7nK/OicWzlrXpTQz58rQWDA==","signed_message":"bundle_sha256_bytes","signed_at":"2026-07-06T22:27:48.898109Z","bundle_sha256":"a3c11e783f8181ca81994b5ffa4e76cfd681c5645fae0a2659f11d5faf37983d"}}