{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2016:TODL4XVS5EYLDEYXP4AJR27SDC","short_pith_number":"pith:TODL4XVS","canonical_record":{"source":{"id":"1612.01949","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-12-06T18:57:46Z","cross_cats_sorted":[],"title_canon_sha256":"12a17c88ff1990b8bafed28230eb069bb1a6b7c17c35badf4a8b134b139bdd34","abstract_canon_sha256":"f4d89cd1f0a7a374f59e8b237f66171b31ac97eaf309106b0651d47e9c677fa7"},"schema_version":"1.0"},"canonical_sha256":"9b86be5eb2e930b193177f0098ebf2189fe9459e9488dea8980778786b009dab","source":{"kind":"arxiv","id":"1612.01949","version":2},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1612.01949","created_at":"2026-05-18T00:50:42Z"},{"alias_kind":"arxiv_version","alias_value":"1612.01949v2","created_at":"2026-05-18T00:50:42Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1612.01949","created_at":"2026-05-18T00:50:42Z"},{"alias_kind":"pith_short_12","alias_value":"TODL4XVS5EYL","created_at":"2026-05-18T12:30:46Z"},{"alias_kind":"pith_short_16","alias_value":"TODL4XVS5EYLDEYX","created_at":"2026-05-18T12:30:46Z"},{"alias_kind":"pith_short_8","alias_value":"TODL4XVS","created_at":"2026-05-18T12:30:46Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2016:TODL4XVS5EYLDEYXP4AJR27SDC","target":"record","payload":{"canonical_record":{"source":{"id":"1612.01949","kind":"arxiv","version":2},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-12-06T18:57:46Z","cross_cats_sorted":[],"title_canon_sha256":"12a17c88ff1990b8bafed28230eb069bb1a6b7c17c35badf4a8b134b139bdd34","abstract_canon_sha256":"f4d89cd1f0a7a374f59e8b237f66171b31ac97eaf309106b0651d47e9c677fa7"},"schema_version":"1.0"},"canonical_sha256":"9b86be5eb2e930b193177f0098ebf2189fe9459e9488dea8980778786b009dab","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T00:50:42.226987Z","signature_b64":"U/A36Hp34loS19n4d69e5GuFknVgjWm6evPv0KJRau4T0FO7zuIuj4An8VWaGC9M0q3/gZJb0urmAxFEra8fCg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"9b86be5eb2e930b193177f0098ebf2189fe9459e9488dea8980778786b009dab","last_reissued_at":"2026-05-18T00:50:42.226271Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T00:50:42.226271Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1612.01949","source_version":2,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:50:42Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"I1bD38YfDiup9h4untAXM+/J8ij0QMSOpsTefY8vRIfFHRZfDAJ6a+Oy2+ctUr/ox0q8DvwvTFJIGegZZhLlBQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-26T09:23:04.962675Z"},"content_sha256":"7b37b579d306066be793ea6e6a115bc30641de7b52532b58310c1b3ef951f7ab","schema_version":"1.0","event_id":"sha256:7b37b579d306066be793ea6e6a115bc30641de7b52532b58310c1b3ef951f7ab"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2016:TODL4XVS5EYLDEYXP4AJR27SDC","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Equation of Motion for the Solvent Polarization Apparent Charges in the Polarizable Continuum Model: Application to Time-Dependent CI","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"Roberto Cammi, Silvio Pipolo, Stefano Corni","submitted_at":"2016-12-06T18:57:46Z","abstract_excerpt":"The dynamics of the electrons for a molecule in solution is coupled to the dynamics of its polarizable environment, i.e., the solvent. To theoretically investigate such electronic dynamics, we have recently developed equations of motion (EOM) for the apparent solvent polarization charges that generate the reaction field in the Polarizable Continuum Model (PCM) for solvation and we have coupled them to a real-time time-dependent density functional theory (RT TDDFT) description of the solute [Corni et al. J. Phys. Chem. A 119, 5405 (2014)]. Here we present an extension of the EOM-PCM approach to"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1612.01949","kind":"arxiv","version":2},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:50:42Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"qh+3Kd1dKXSZo2gsm7dxYBU0zPbdXhKwU5DQRD+R3BHqLEWgpZgD1jVyT6xbO/7kt+pGvdQ32YE3zxbzE85qCQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-26T09:23:04.963278Z"},"content_sha256":"f9bac8f2530a9feccb85ac48d7f0df66af1d526ef947a6bf075e0eb06f59d650","schema_version":"1.0","event_id":"sha256:f9bac8f2530a9feccb85ac48d7f0df66af1d526ef947a6bf075e0eb06f59d650"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/TODL4XVS5EYLDEYXP4AJR27SDC/bundle.json","state_url":"https://pith.science/pith/TODL4XVS5EYLDEYXP4AJR27SDC/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/TODL4XVS5EYLDEYXP4AJR27SDC/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-05-26T09:23:04Z","links":{"resolver":"https://pith.science/pith/TODL4XVS5EYLDEYXP4AJR27SDC","bundle":"https://pith.science/pith/TODL4XVS5EYLDEYXP4AJR27SDC/bundle.json","state":"https://pith.science/pith/TODL4XVS5EYLDEYXP4AJR27SDC/state.json","well_known_bundle":"https://pith.science/.well-known/pith/TODL4XVS5EYLDEYXP4AJR27SDC/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2016:TODL4XVS5EYLDEYXP4AJR27SDC","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"f4d89cd1f0a7a374f59e8b237f66171b31ac97eaf309106b0651d47e9c677fa7","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-12-06T18:57:46Z","title_canon_sha256":"12a17c88ff1990b8bafed28230eb069bb1a6b7c17c35badf4a8b134b139bdd34"},"schema_version":"1.0","source":{"id":"1612.01949","kind":"arxiv","version":2}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1612.01949","created_at":"2026-05-18T00:50:42Z"},{"alias_kind":"arxiv_version","alias_value":"1612.01949v2","created_at":"2026-05-18T00:50:42Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1612.01949","created_at":"2026-05-18T00:50:42Z"},{"alias_kind":"pith_short_12","alias_value":"TODL4XVS5EYL","created_at":"2026-05-18T12:30:46Z"},{"alias_kind":"pith_short_16","alias_value":"TODL4XVS5EYLDEYX","created_at":"2026-05-18T12:30:46Z"},{"alias_kind":"pith_short_8","alias_value":"TODL4XVS","created_at":"2026-05-18T12:30:46Z"}],"graph_snapshots":[{"event_id":"sha256:f9bac8f2530a9feccb85ac48d7f0df66af1d526ef947a6bf075e0eb06f59d650","target":"graph","created_at":"2026-05-18T00:50:42Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"The dynamics of the electrons for a molecule in solution is coupled to the dynamics of its polarizable environment, i.e., the solvent. To theoretically investigate such electronic dynamics, we have recently developed equations of motion (EOM) for the apparent solvent polarization charges that generate the reaction field in the Polarizable Continuum Model (PCM) for solvation and we have coupled them to a real-time time-dependent density functional theory (RT TDDFT) description of the solute [Corni et al. J. Phys. Chem. A 119, 5405 (2014)]. Here we present an extension of the EOM-PCM approach to","authors_text":"Roberto Cammi, Silvio Pipolo, Stefano Corni","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-12-06T18:57:46Z","title":"Equation of Motion for the Solvent Polarization Apparent Charges in the Polarizable Continuum Model: Application to Time-Dependent CI"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1612.01949","kind":"arxiv","version":2},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:7b37b579d306066be793ea6e6a115bc30641de7b52532b58310c1b3ef951f7ab","target":"record","created_at":"2026-05-18T00:50:42Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"f4d89cd1f0a7a374f59e8b237f66171b31ac97eaf309106b0651d47e9c677fa7","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2016-12-06T18:57:46Z","title_canon_sha256":"12a17c88ff1990b8bafed28230eb069bb1a6b7c17c35badf4a8b134b139bdd34"},"schema_version":"1.0","source":{"id":"1612.01949","kind":"arxiv","version":2}},"canonical_sha256":"9b86be5eb2e930b193177f0098ebf2189fe9459e9488dea8980778786b009dab","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"9b86be5eb2e930b193177f0098ebf2189fe9459e9488dea8980778786b009dab","first_computed_at":"2026-05-18T00:50:42.226271Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T00:50:42.226271Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"U/A36Hp34loS19n4d69e5GuFknVgjWm6evPv0KJRau4T0FO7zuIuj4An8VWaGC9M0q3/gZJb0urmAxFEra8fCg==","signature_status":"signed_v1","signed_at":"2026-05-18T00:50:42.226987Z","signed_message":"canonical_sha256_bytes"},"source_id":"1612.01949","source_kind":"arxiv","source_version":2}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:7b37b579d306066be793ea6e6a115bc30641de7b52532b58310c1b3ef951f7ab","sha256:f9bac8f2530a9feccb85ac48d7f0df66af1d526ef947a6bf075e0eb06f59d650"],"state_sha256":"54c80d797c9f10276fcf9b65bd4da540548592e4a6f115587e65858ec8343f94"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"dZvA08XXjDx7meK3QIpYkVvP0h2zOPU2tEV4tlVWnRzhMluiN3hAE4tbWrwWiRzJYNQmVT0v6tK46AZA2BV+BA==","signed_message":"bundle_sha256_bytes","signed_at":"2026-05-26T09:23:04.966058Z","bundle_sha256":"9396a1c2e8e9505f6c6743dd17647146ffe19e4c31c3df570d92c17823801de8"}}