{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2014:VYD3QSV4WTADJJOTNMMIWRCO5B","short_pith_number":"pith:VYD3QSV4","canonical_record":{"source":{"id":"1403.5495","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2014-03-21T15:23:58Z","cross_cats_sorted":[],"title_canon_sha256":"e7a0110a1189241664d48b94560b93f5c63cd54fcb6e4906c22ec82d3bfe37eb","abstract_canon_sha256":"589f0a216f5d166aedb13fc3af59b408d9dd12900ab7688c70f2b332adfe81da"},"schema_version":"1.0"},"canonical_sha256":"ae07b84abcb4c034a5d36b188b444ee85c3a7645bbc0851fe08c05f89de7919f","source":{"kind":"arxiv","id":"1403.5495","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1403.5495","created_at":"2026-05-18T02:51:49Z"},{"alias_kind":"arxiv_version","alias_value":"1403.5495v1","created_at":"2026-05-18T02:51:49Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1403.5495","created_at":"2026-05-18T02:51:49Z"},{"alias_kind":"pith_short_12","alias_value":"VYD3QSV4WTAD","created_at":"2026-05-18T12:28:54Z"},{"alias_kind":"pith_short_16","alias_value":"VYD3QSV4WTADJJOT","created_at":"2026-05-18T12:28:54Z"},{"alias_kind":"pith_short_8","alias_value":"VYD3QSV4","created_at":"2026-05-18T12:28:54Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2014:VYD3QSV4WTADJJOTNMMIWRCO5B","target":"record","payload":{"canonical_record":{"source":{"id":"1403.5495","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2014-03-21T15:23:58Z","cross_cats_sorted":[],"title_canon_sha256":"e7a0110a1189241664d48b94560b93f5c63cd54fcb6e4906c22ec82d3bfe37eb","abstract_canon_sha256":"589f0a216f5d166aedb13fc3af59b408d9dd12900ab7688c70f2b332adfe81da"},"schema_version":"1.0"},"canonical_sha256":"ae07b84abcb4c034a5d36b188b444ee85c3a7645bbc0851fe08c05f89de7919f","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T02:51:49.433006Z","signature_b64":"eyudbx4pj61DcH17IYw9Bdt9l7tpCurAUOtHA0ohul+7U+DGL1fYS5+YTN1AnH5bA9NRwRFjMxPTd906iiVnBg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"ae07b84abcb4c034a5d36b188b444ee85c3a7645bbc0851fe08c05f89de7919f","last_reissued_at":"2026-05-18T02:51:49.432554Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T02:51:49.432554Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1403.5495","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T02:51:49Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"ObDpf4zpqnvQOk4Mhm67p5NxPN+KQSQD1KK2p1+OMvyTytoA3Wyl1CjAeZ2uPpOO6CA62GtAT7sc9mcHenJADA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-07T14:45:30.086277Z"},"content_sha256":"c766b2edfe47d216c7f79803fb1c5df3a7b3344677c0cc35f783f4d59fc7fe8a","schema_version":"1.0","event_id":"sha256:c766b2edfe47d216c7f79803fb1c5df3a7b3344677c0cc35f783f4d59fc7fe8a"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2014:VYD3QSV4WTADJJOTNMMIWRCO5B","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Non-adiabatic and time-resolved photoelectron spectroscopy for molecular systems","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"Angel Rubio, Heiko Appel, Johannes Flick","submitted_at":"2014-03-21T15:23:58Z","abstract_excerpt":"We quantify the non-adiabatic contributions to the vibronic sidebands of equilibrium and explicitly time-resolved non-equilibrium photoelectron spectra for a vibronic model system of Trans-Polyacetylene. Using exact diagonalization, we directly evaluate the sum-over-states expressions for the linear-response photocurrent. We show that spurious peaks appear in the Born-Oppenheimer approximation for the vibronic spectral function, which are not present in the exact spectral function of the system. The effect can be traced back to the factorized nature of the Born-Oppenheimer initial and final ph"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1403.5495","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T02:51:49Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"bJV4KVRR7FqO8caKe4lIh3GG+THPN4YOiZcM4bhRwlk7Kytj1LD53vjNFqOnego5+GcqUnVRLcm5cLr+pFY5Cg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-07T14:45:30.086640Z"},"content_sha256":"89484bbe7a527448fef575309c18835b140e90cf5853c4129f72b6fbdc900d1b","schema_version":"1.0","event_id":"sha256:89484bbe7a527448fef575309c18835b140e90cf5853c4129f72b6fbdc900d1b"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/VYD3QSV4WTADJJOTNMMIWRCO5B/bundle.json","state_url":"https://pith.science/pith/VYD3QSV4WTADJJOTNMMIWRCO5B/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/VYD3QSV4WTADJJOTNMMIWRCO5B/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-07T14:45:30Z","links":{"resolver":"https://pith.science/pith/VYD3QSV4WTADJJOTNMMIWRCO5B","bundle":"https://pith.science/pith/VYD3QSV4WTADJJOTNMMIWRCO5B/bundle.json","state":"https://pith.science/pith/VYD3QSV4WTADJJOTNMMIWRCO5B/state.json","well_known_bundle":"https://pith.science/.well-known/pith/VYD3QSV4WTADJJOTNMMIWRCO5B/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2014:VYD3QSV4WTADJJOTNMMIWRCO5B","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"589f0a216f5d166aedb13fc3af59b408d9dd12900ab7688c70f2b332adfe81da","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2014-03-21T15:23:58Z","title_canon_sha256":"e7a0110a1189241664d48b94560b93f5c63cd54fcb6e4906c22ec82d3bfe37eb"},"schema_version":"1.0","source":{"id":"1403.5495","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1403.5495","created_at":"2026-05-18T02:51:49Z"},{"alias_kind":"arxiv_version","alias_value":"1403.5495v1","created_at":"2026-05-18T02:51:49Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1403.5495","created_at":"2026-05-18T02:51:49Z"},{"alias_kind":"pith_short_12","alias_value":"VYD3QSV4WTAD","created_at":"2026-05-18T12:28:54Z"},{"alias_kind":"pith_short_16","alias_value":"VYD3QSV4WTADJJOT","created_at":"2026-05-18T12:28:54Z"},{"alias_kind":"pith_short_8","alias_value":"VYD3QSV4","created_at":"2026-05-18T12:28:54Z"}],"graph_snapshots":[{"event_id":"sha256:89484bbe7a527448fef575309c18835b140e90cf5853c4129f72b6fbdc900d1b","target":"graph","created_at":"2026-05-18T02:51:49Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"We quantify the non-adiabatic contributions to the vibronic sidebands of equilibrium and explicitly time-resolved non-equilibrium photoelectron spectra for a vibronic model system of Trans-Polyacetylene. Using exact diagonalization, we directly evaluate the sum-over-states expressions for the linear-response photocurrent. We show that spurious peaks appear in the Born-Oppenheimer approximation for the vibronic spectral function, which are not present in the exact spectral function of the system. The effect can be traced back to the factorized nature of the Born-Oppenheimer initial and final ph","authors_text":"Angel Rubio, Heiko Appel, Johannes Flick","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2014-03-21T15:23:58Z","title":"Non-adiabatic and time-resolved photoelectron spectroscopy for molecular systems"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1403.5495","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:c766b2edfe47d216c7f79803fb1c5df3a7b3344677c0cc35f783f4d59fc7fe8a","target":"record","created_at":"2026-05-18T02:51:49Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"589f0a216f5d166aedb13fc3af59b408d9dd12900ab7688c70f2b332adfe81da","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2014-03-21T15:23:58Z","title_canon_sha256":"e7a0110a1189241664d48b94560b93f5c63cd54fcb6e4906c22ec82d3bfe37eb"},"schema_version":"1.0","source":{"id":"1403.5495","kind":"arxiv","version":1}},"canonical_sha256":"ae07b84abcb4c034a5d36b188b444ee85c3a7645bbc0851fe08c05f89de7919f","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"ae07b84abcb4c034a5d36b188b444ee85c3a7645bbc0851fe08c05f89de7919f","first_computed_at":"2026-05-18T02:51:49.432554Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T02:51:49.432554Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"eyudbx4pj61DcH17IYw9Bdt9l7tpCurAUOtHA0ohul+7U+DGL1fYS5+YTN1AnH5bA9NRwRFjMxPTd906iiVnBg==","signature_status":"signed_v1","signed_at":"2026-05-18T02:51:49.433006Z","signed_message":"canonical_sha256_bytes"},"source_id":"1403.5495","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:c766b2edfe47d216c7f79803fb1c5df3a7b3344677c0cc35f783f4d59fc7fe8a","sha256:89484bbe7a527448fef575309c18835b140e90cf5853c4129f72b6fbdc900d1b"],"state_sha256":"d5e1d099083c47a1743bf05ff115cdd50bb62baa5f494a35fc527e44079b8006"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"XODN/r529OAI8qa5oWyNar9L3q70Es843y+hd7sIPOZKWBKfXMJyjAChFQG43QE8fc9s1gQ5D0O7jR8VCJ/vCg==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-07T14:45:30.088561Z","bundle_sha256":"a5719c5f69983df5b3d939451cf542f6bb63fb4e58d3c26ea7811a451cc58587"}}