{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2024:WF7R3PDA7YWES2Y66AM4B3TMJ6","short_pith_number":"pith:WF7R3PDA","canonical_record":{"source":{"id":"2411.09392","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/by-nc-nd/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2024-11-14T12:10:04Z","cross_cats_sorted":["cond-mat.mes-hall"],"title_canon_sha256":"0d19d1b217c11456d17ea0e37f38835888eebfd3a69b6e4e1cdbe79d33df32c2","abstract_canon_sha256":"b3c59c066fd8c47534fa537a3d7822079cd67faa2d4f09adac9bc189d1cd5087"},"schema_version":"1.0"},"canonical_sha256":"b17f1dbc60fe2c496b1ef019c0ee6c4f8a1ddd205bd30ef89af91578b29beb1a","source":{"kind":"arxiv","id":"2411.09392","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2411.09392","created_at":"2026-07-05T10:30:25Z"},{"alias_kind":"arxiv_version","alias_value":"2411.09392v1","created_at":"2026-07-05T10:30:25Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2411.09392","created_at":"2026-07-05T10:30:25Z"},{"alias_kind":"pith_short_12","alias_value":"WF7R3PDA7YWE","created_at":"2026-07-05T10:30:25Z"},{"alias_kind":"pith_short_16","alias_value":"WF7R3PDA7YWES2Y6","created_at":"2026-07-05T10:30:25Z"},{"alias_kind":"pith_short_8","alias_value":"WF7R3PDA","created_at":"2026-07-05T10:30:25Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2024:WF7R3PDA7YWES2Y66AM4B3TMJ6","target":"record","payload":{"canonical_record":{"source":{"id":"2411.09392","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/by-nc-nd/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2024-11-14T12:10:04Z","cross_cats_sorted":["cond-mat.mes-hall"],"title_canon_sha256":"0d19d1b217c11456d17ea0e37f38835888eebfd3a69b6e4e1cdbe79d33df32c2","abstract_canon_sha256":"b3c59c066fd8c47534fa537a3d7822079cd67faa2d4f09adac9bc189d1cd5087"},"schema_version":"1.0"},"canonical_sha256":"b17f1dbc60fe2c496b1ef019c0ee6c4f8a1ddd205bd30ef89af91578b29beb1a","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T10:30:25.885972Z","signature_b64":"3sj85QBHuwIM5/SZrXwRa2xrn/9UFTfcqXMX4RRpqgsyO2vWwHBTK5TGqAVc3eefUt0cL5WYch3+SbbCIxdrAw==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"b17f1dbc60fe2c496b1ef019c0ee6c4f8a1ddd205bd30ef89af91578b29beb1a","last_reissued_at":"2026-07-05T10:30:25.885452Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T10:30:25.885452Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"2411.09392","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T10:30:25Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"F7jB6MRisHS8r72hFP4DEAjcBn/3Uxrb2XkpEG5e30f9ZIL7wt9prsmrfUADH9JNx+2kXjC6klb4eEHvAzMpAA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-07-05T14:30:03.569535Z"},"content_sha256":"52c96642b4afefaf5e88492be98714f3291cee94e05954c7f7ce7c892d273e8a","schema_version":"1.0","event_id":"sha256:52c96642b4afefaf5e88492be98714f3291cee94e05954c7f7ce7c892d273e8a"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2024:WF7R3PDA7YWES2Y66AM4B3TMJ6","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"How orbitals and oxidation states determine apparent topographies in scanning tunneling microscopy: the case of fluorine on silver surfaces","license":"http://creativecommons.org/licenses/by-nc-nd/4.0/","headline":"","cross_cats":["cond-mat.mes-hall"],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Adri\\'an G\\'omez Pueyo, Antonio Caporale, Conor Hogan, Daniel Jezierski, Ilya Degtev, Jazm\\'in Arag\\'on S\\'anchez, Jos\\'e Lorenzana, Luca Camilli, Luca Persichetti, Luciana Di Gaspare, Maria Eleonora Temperini, Monica De Seta, Paolo Barone, Wojciech Grochala","submitted_at":"2024-11-14T12:10:04Z","abstract_excerpt":"We use density functional theory calculations to characterize the early stages of fluorination of silver's (100) and (110) surfaces. In the Ag(100) surface, the hollow site is the most favorable for F adatoms. In the Ag(110) surface, three adsorption sites, namely hollow, long bridge, and short bridge, exhibit similar energies. These locations are also more favorable than an F adatom occupying a vacancy site irrespectively of whether the vacancy was present or not in the pristine surface. The computed energy as a function of surface coverage is used to compute the equilibrium thermodynamics ph"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2411.09392","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2411.09392/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T10:30:25Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"Bk8enLBaLYvKpO4a6XliEAgtzWY+mTlPr/VDb8AOsu0Bh4BSRmXiT6NzbAtyLhFe3kBCh2mD7mcFcmxjoqCQBA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-07-05T14:30:03.569918Z"},"content_sha256":"3ea857f44fc881cb1eed76a11456dc49234039db1409c80cea7d012328d8c312","schema_version":"1.0","event_id":"sha256:3ea857f44fc881cb1eed76a11456dc49234039db1409c80cea7d012328d8c312"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/WF7R3PDA7YWES2Y66AM4B3TMJ6/bundle.json","state_url":"https://pith.science/pith/WF7R3PDA7YWES2Y66AM4B3TMJ6/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/WF7R3PDA7YWES2Y66AM4B3TMJ6/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-07-05T14:30:03Z","links":{"resolver":"https://pith.science/pith/WF7R3PDA7YWES2Y66AM4B3TMJ6","bundle":"https://pith.science/pith/WF7R3PDA7YWES2Y66AM4B3TMJ6/bundle.json","state":"https://pith.science/pith/WF7R3PDA7YWES2Y66AM4B3TMJ6/state.json","well_known_bundle":"https://pith.science/.well-known/pith/WF7R3PDA7YWES2Y66AM4B3TMJ6/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2024:WF7R3PDA7YWES2Y66AM4B3TMJ6","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"b3c59c066fd8c47534fa537a3d7822079cd67faa2d4f09adac9bc189d1cd5087","cross_cats_sorted":["cond-mat.mes-hall"],"license":"http://creativecommons.org/licenses/by-nc-nd/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2024-11-14T12:10:04Z","title_canon_sha256":"0d19d1b217c11456d17ea0e37f38835888eebfd3a69b6e4e1cdbe79d33df32c2"},"schema_version":"1.0","source":{"id":"2411.09392","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2411.09392","created_at":"2026-07-05T10:30:25Z"},{"alias_kind":"arxiv_version","alias_value":"2411.09392v1","created_at":"2026-07-05T10:30:25Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2411.09392","created_at":"2026-07-05T10:30:25Z"},{"alias_kind":"pith_short_12","alias_value":"WF7R3PDA7YWE","created_at":"2026-07-05T10:30:25Z"},{"alias_kind":"pith_short_16","alias_value":"WF7R3PDA7YWES2Y6","created_at":"2026-07-05T10:30:25Z"},{"alias_kind":"pith_short_8","alias_value":"WF7R3PDA","created_at":"2026-07-05T10:30:25Z"}],"graph_snapshots":[{"event_id":"sha256:3ea857f44fc881cb1eed76a11456dc49234039db1409c80cea7d012328d8c312","target":"graph","created_at":"2026-07-05T10:30:25Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2411.09392/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"We use density functional theory calculations to characterize the early stages of fluorination of silver's (100) and (110) surfaces. In the Ag(100) surface, the hollow site is the most favorable for F adatoms. In the Ag(110) surface, three adsorption sites, namely hollow, long bridge, and short bridge, exhibit similar energies. These locations are also more favorable than an F adatom occupying a vacancy site irrespectively of whether the vacancy was present or not in the pristine surface. The computed energy as a function of surface coverage is used to compute the equilibrium thermodynamics ph","authors_text":"Adri\\'an G\\'omez Pueyo, Antonio Caporale, Conor Hogan, Daniel Jezierski, Ilya Degtev, Jazm\\'in Arag\\'on S\\'anchez, Jos\\'e Lorenzana, Luca Camilli, Luca Persichetti, Luciana Di Gaspare, Maria Eleonora Temperini, Monica De Seta, Paolo Barone, Wojciech Grochala","cross_cats":["cond-mat.mes-hall"],"headline":"","license":"http://creativecommons.org/licenses/by-nc-nd/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2024-11-14T12:10:04Z","title":"How orbitals and oxidation states determine apparent topographies in scanning tunneling microscopy: the case of fluorine on silver surfaces"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2411.09392","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:52c96642b4afefaf5e88492be98714f3291cee94e05954c7f7ce7c892d273e8a","target":"record","created_at":"2026-07-05T10:30:25Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"b3c59c066fd8c47534fa537a3d7822079cd67faa2d4f09adac9bc189d1cd5087","cross_cats_sorted":["cond-mat.mes-hall"],"license":"http://creativecommons.org/licenses/by-nc-nd/4.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2024-11-14T12:10:04Z","title_canon_sha256":"0d19d1b217c11456d17ea0e37f38835888eebfd3a69b6e4e1cdbe79d33df32c2"},"schema_version":"1.0","source":{"id":"2411.09392","kind":"arxiv","version":1}},"canonical_sha256":"b17f1dbc60fe2c496b1ef019c0ee6c4f8a1ddd205bd30ef89af91578b29beb1a","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"b17f1dbc60fe2c496b1ef019c0ee6c4f8a1ddd205bd30ef89af91578b29beb1a","first_computed_at":"2026-07-05T10:30:25.885452Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-05T10:30:25.885452Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"3sj85QBHuwIM5/SZrXwRa2xrn/9UFTfcqXMX4RRpqgsyO2vWwHBTK5TGqAVc3eefUt0cL5WYch3+SbbCIxdrAw==","signature_status":"signed_v1","signed_at":"2026-07-05T10:30:25.885972Z","signed_message":"canonical_sha256_bytes"},"source_id":"2411.09392","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:52c96642b4afefaf5e88492be98714f3291cee94e05954c7f7ce7c892d273e8a","sha256:3ea857f44fc881cb1eed76a11456dc49234039db1409c80cea7d012328d8c312"],"state_sha256":"21378bab478bc6eea844c0fcb575066050c3d1f68b0443ddaeb60c1d1b645c0d"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"Nd2AjjAsGmE7MPZWwKz7aYdYbN2j/2j8YlJc1SwhQTR8MiV6F4tL7pHU8Xpz2k2r2oyKHuwCbH638byp+W3iCA==","signed_message":"bundle_sha256_bytes","signed_at":"2026-07-05T14:30:03.573735Z","bundle_sha256":"d74aa60d270ae4d58012518ea2d872bd35c3ed38617176fc4687b1892024e012"}}