pith:WRDJJCEB
Effects of Divalent Cations on Diffusion Dynamics of Biological Water Confined between Lipid Membranes
Calcium ions steadily increase the diffusion rate of water confined between lipid membranes, while magnesium ions produce a non-monotonic effect.
arxiv:2603.19719 v3 · 2026-03-20 · cond-mat.soft
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Claims
We find that the diffusion coefficient of biological water monotonically increases with Ca2+ ion concentration but exhibits a largely opposite, non-monotonic dependence on Mg2+ concentration. These contrasting behaviors originate from the different hydration radii of these divalent ions and their distinct effects on the interfacial structure and dynamics of biological water.
The molecular dynamics force fields and the generalized transport equation faithfully reproduce the real interfacial structure, ion hydration, and diffusion fluctuations without significant artifacts from finite system size or parameter choices.
Simulations find calcium ions monotonically raise the diffusion coefficient of nanoconfined biological water while magnesium ions yield non-monotonic dependence due to differing hydration radii and interfacial effects.
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Receipt and verification
| First computed | 2026-05-26T01:03:28.477463Z |
|---|---|
| Builder | pith-number-builder-2026-05-17-v1 |
| Signature | Pith Ed25519
(pith-v1-2026-05) · public key |
| Schema | pith-number/v1.0 |
Canonical hash
b44694888111be1fd865e866cb14d2057f2a9f7b6a41c58ce193427361a98e22
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curl -sH 'Accept: application/ld+json' https://pith.science/pith/WRDJJCEBCG7B7WDF5BTMWFGSAV \
| jq -c '.canonical_record' \
| python3 -c "import sys,json,hashlib; b=json.dumps(json.loads(sys.stdin.read()), sort_keys=True, separators=(',',':'), ensure_ascii=False).encode(); print(hashlib.sha256(b).hexdigest())"
# expect: b44694888111be1fd865e866cb14d2057f2a9f7b6a41c58ce193427361a98e22
Canonical record JSON
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