{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2017:WX3GTH3STKAR2HDZCBHNJ77YE3","short_pith_number":"pith:WX3GTH3S","canonical_record":{"source":{"id":"1707.06174","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2017-07-19T16:02:54Z","cross_cats_sorted":["cond-mat.soft"],"title_canon_sha256":"67eef860d9161f9593eeea56fa90f90175c8aba38bb01c19058ee2efe2946319","abstract_canon_sha256":"43842ff4ec109a1c5d8a90c6abddff10f26cf543972153ec704a15c4731ab285"},"schema_version":"1.0"},"canonical_sha256":"b5f6699f729a811d1c79104ed4fff826ea6363c816c8356b069c95283f03a95d","source":{"kind":"arxiv","id":"1707.06174","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1707.06174","created_at":"2026-05-18T00:25:04Z"},{"alias_kind":"arxiv_version","alias_value":"1707.06174v1","created_at":"2026-05-18T00:25:04Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1707.06174","created_at":"2026-05-18T00:25:04Z"},{"alias_kind":"pith_short_12","alias_value":"WX3GTH3STKAR","created_at":"2026-05-18T12:31:53Z"},{"alias_kind":"pith_short_16","alias_value":"WX3GTH3STKAR2HDZ","created_at":"2026-05-18T12:31:53Z"},{"alias_kind":"pith_short_8","alias_value":"WX3GTH3S","created_at":"2026-05-18T12:31:53Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2017:WX3GTH3STKAR2HDZCBHNJ77YE3","target":"record","payload":{"canonical_record":{"source":{"id":"1707.06174","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2017-07-19T16:02:54Z","cross_cats_sorted":["cond-mat.soft"],"title_canon_sha256":"67eef860d9161f9593eeea56fa90f90175c8aba38bb01c19058ee2efe2946319","abstract_canon_sha256":"43842ff4ec109a1c5d8a90c6abddff10f26cf543972153ec704a15c4731ab285"},"schema_version":"1.0"},"canonical_sha256":"b5f6699f729a811d1c79104ed4fff826ea6363c816c8356b069c95283f03a95d","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T00:25:04.077803Z","signature_b64":"cVRRQvkKTEJvsVwlAncs6vNBE2zX2lh8Dve2yX5nD+v7sbGkQXPFK/bAdYQuAWfDVbUesCGdpt9oi8ePlVeIDg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"b5f6699f729a811d1c79104ed4fff826ea6363c816c8356b069c95283f03a95d","last_reissued_at":"2026-05-18T00:25:04.077383Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T00:25:04.077383Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1707.06174","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:25:04Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"SqDeqjChSAaeC3+lULsgaa52IYwRXdjwigwNrXd0Ao0NgsLcC7m+R4c3Sgz5Nw05l/87WoWQKKR5CsSo3CpUAA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-19T11:59:08.076499Z"},"content_sha256":"f2341d985c2566e6407fb63ae7c7f594a6238e10505f6d721676cd65b554eea4","schema_version":"1.0","event_id":"sha256:f2341d985c2566e6407fb63ae7c7f594a6238e10505f6d721676cd65b554eea4"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2017:WX3GTH3STKAR2HDZCBHNJ77YE3","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Catalyzed bimolecular reactions in responsive nanoreactors","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["cond-mat.soft"],"primary_cat":"physics.chem-ph","authors_text":"Joachim Dzubiella, Matej Kanduc, Rafael Roa, Stefano Angioletti-Uberti, Won Kyu Kim","submitted_at":"2017-07-19T16:02:54Z","abstract_excerpt":"We describe a general theory for surface-catalyzed bimolecular reactions in responsive nanoreactors, catalytically active nanoparticles coated by a stimuli-responsive 'gating' shell, whose permeability controls the activity of the process. We address two archetypal scenarios encountered in this system: The first, where two species diffusing from a bulk solution react at the catalyst's surface; the second where only one of the reactants diffuses from the bulk while the other one is produced at the nanoparticle surface, e.g., by light conversion. We find that in both scenarios the total catalyti"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1707.06174","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:25:04Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"D4aNL4wyv8rnLy1CagxaLJPATD8GefLnFPRROjN3a/9WzHdxbqoQFZ7KxnC31+2AvYfagrrA+gbpmZHt2ykiDA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-19T11:59:08.076889Z"},"content_sha256":"73b26cb73540c08cda893deeee9e798f23b30f0b2f31158e0162039ef7c41170","schema_version":"1.0","event_id":"sha256:73b26cb73540c08cda893deeee9e798f23b30f0b2f31158e0162039ef7c41170"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/WX3GTH3STKAR2HDZCBHNJ77YE3/bundle.json","state_url":"https://pith.science/pith/WX3GTH3STKAR2HDZCBHNJ77YE3/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/WX3GTH3STKAR2HDZCBHNJ77YE3/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-05-19T11:59:08Z","links":{"resolver":"https://pith.science/pith/WX3GTH3STKAR2HDZCBHNJ77YE3","bundle":"https://pith.science/pith/WX3GTH3STKAR2HDZCBHNJ77YE3/bundle.json","state":"https://pith.science/pith/WX3GTH3STKAR2HDZCBHNJ77YE3/state.json","well_known_bundle":"https://pith.science/.well-known/pith/WX3GTH3STKAR2HDZCBHNJ77YE3/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2017:WX3GTH3STKAR2HDZCBHNJ77YE3","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"43842ff4ec109a1c5d8a90c6abddff10f26cf543972153ec704a15c4731ab285","cross_cats_sorted":["cond-mat.soft"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2017-07-19T16:02:54Z","title_canon_sha256":"67eef860d9161f9593eeea56fa90f90175c8aba38bb01c19058ee2efe2946319"},"schema_version":"1.0","source":{"id":"1707.06174","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1707.06174","created_at":"2026-05-18T00:25:04Z"},{"alias_kind":"arxiv_version","alias_value":"1707.06174v1","created_at":"2026-05-18T00:25:04Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1707.06174","created_at":"2026-05-18T00:25:04Z"},{"alias_kind":"pith_short_12","alias_value":"WX3GTH3STKAR","created_at":"2026-05-18T12:31:53Z"},{"alias_kind":"pith_short_16","alias_value":"WX3GTH3STKAR2HDZ","created_at":"2026-05-18T12:31:53Z"},{"alias_kind":"pith_short_8","alias_value":"WX3GTH3S","created_at":"2026-05-18T12:31:53Z"}],"graph_snapshots":[{"event_id":"sha256:73b26cb73540c08cda893deeee9e798f23b30f0b2f31158e0162039ef7c41170","target":"graph","created_at":"2026-05-18T00:25:04Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"We describe a general theory for surface-catalyzed bimolecular reactions in responsive nanoreactors, catalytically active nanoparticles coated by a stimuli-responsive 'gating' shell, whose permeability controls the activity of the process. We address two archetypal scenarios encountered in this system: The first, where two species diffusing from a bulk solution react at the catalyst's surface; the second where only one of the reactants diffuses from the bulk while the other one is produced at the nanoparticle surface, e.g., by light conversion. We find that in both scenarios the total catalyti","authors_text":"Joachim Dzubiella, Matej Kanduc, Rafael Roa, Stefano Angioletti-Uberti, Won Kyu Kim","cross_cats":["cond-mat.soft"],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2017-07-19T16:02:54Z","title":"Catalyzed bimolecular reactions in responsive nanoreactors"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1707.06174","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:f2341d985c2566e6407fb63ae7c7f594a6238e10505f6d721676cd65b554eea4","target":"record","created_at":"2026-05-18T00:25:04Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"43842ff4ec109a1c5d8a90c6abddff10f26cf543972153ec704a15c4731ab285","cross_cats_sorted":["cond-mat.soft"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2017-07-19T16:02:54Z","title_canon_sha256":"67eef860d9161f9593eeea56fa90f90175c8aba38bb01c19058ee2efe2946319"},"schema_version":"1.0","source":{"id":"1707.06174","kind":"arxiv","version":1}},"canonical_sha256":"b5f6699f729a811d1c79104ed4fff826ea6363c816c8356b069c95283f03a95d","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"b5f6699f729a811d1c79104ed4fff826ea6363c816c8356b069c95283f03a95d","first_computed_at":"2026-05-18T00:25:04.077383Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T00:25:04.077383Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"cVRRQvkKTEJvsVwlAncs6vNBE2zX2lh8Dve2yX5nD+v7sbGkQXPFK/bAdYQuAWfDVbUesCGdpt9oi8ePlVeIDg==","signature_status":"signed_v1","signed_at":"2026-05-18T00:25:04.077803Z","signed_message":"canonical_sha256_bytes"},"source_id":"1707.06174","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:f2341d985c2566e6407fb63ae7c7f594a6238e10505f6d721676cd65b554eea4","sha256:73b26cb73540c08cda893deeee9e798f23b30f0b2f31158e0162039ef7c41170"],"state_sha256":"058f18380477b114343657d91b5d57ab838777b9c67f878bf608f4645e9c1467"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"u5HntJT1AqDh76I4s6Z1pUuVLUw8FNL64rqf3zcOGFw+qH3xOF2Q6ikZ4IKJgHBLCaTySsWtWQ1uboq7q5eVCA==","signed_message":"bundle_sha256_bytes","signed_at":"2026-05-19T11:59:08.078547Z","bundle_sha256":"3cb67df441c4be7b75f48c111ad536fc27aff4f1b1b55cfd60f663140f08d8ba"}}