{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2012:X6T2IQX23BKGZKFI2N6V22XLPZ","short_pith_number":"pith:X6T2IQX2","canonical_record":{"source":{"id":"1202.4046","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2012-02-18T01:38:41Z","cross_cats_sorted":[],"title_canon_sha256":"313f2046c59144a95733c5c9fa11d95bedf8803098944ae98d38032a7ddb21a1","abstract_canon_sha256":"0aaeccf78242887ced2fe712d04d4857aac96273bc6b392881568dee7a6b4e28"},"schema_version":"1.0"},"canonical_sha256":"bfa7a442fad8546ca8a8d37d5d6aeb7e74d780d9cc8ff659423e79fd8d27d2fa","source":{"kind":"arxiv","id":"1202.4046","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1202.4046","created_at":"2026-05-18T01:58:23Z"},{"alias_kind":"arxiv_version","alias_value":"1202.4046v1","created_at":"2026-05-18T01:58:23Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1202.4046","created_at":"2026-05-18T01:58:23Z"},{"alias_kind":"pith_short_12","alias_value":"X6T2IQX23BKG","created_at":"2026-05-18T12:27:27Z"},{"alias_kind":"pith_short_16","alias_value":"X6T2IQX23BKGZKFI","created_at":"2026-05-18T12:27:27Z"},{"alias_kind":"pith_short_8","alias_value":"X6T2IQX2","created_at":"2026-05-18T12:27:27Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2012:X6T2IQX23BKGZKFI2N6V22XLPZ","target":"record","payload":{"canonical_record":{"source":{"id":"1202.4046","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2012-02-18T01:38:41Z","cross_cats_sorted":[],"title_canon_sha256":"313f2046c59144a95733c5c9fa11d95bedf8803098944ae98d38032a7ddb21a1","abstract_canon_sha256":"0aaeccf78242887ced2fe712d04d4857aac96273bc6b392881568dee7a6b4e28"},"schema_version":"1.0"},"canonical_sha256":"bfa7a442fad8546ca8a8d37d5d6aeb7e74d780d9cc8ff659423e79fd8d27d2fa","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T01:58:23.943473Z","signature_b64":"kWLJKopybr4w0hXFGgh75ry2fAM+Nee+WZ10ua+7Ww909yQrZRpqiVDkdABAs/Kqd1GwGZfiiRl4qPYUeoXGDg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"bfa7a442fad8546ca8a8d37d5d6aeb7e74d780d9cc8ff659423e79fd8d27d2fa","last_reissued_at":"2026-05-18T01:58:23.942962Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T01:58:23.942962Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1202.4046","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T01:58:23Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"QbMtNx9Sucx8WZ9LO5OfTr0pTB4khNMQTWKGFpfIXwZUB7Y4T788K9FVZmjnvSDvQLB04uzY4AOhlFlMP68NBw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-03T13:57:57.636962Z"},"content_sha256":"c7f7a4f45e5cc850ccab373e79a55a261492c9d8677a9d27e00d9b7c4b753d75","schema_version":"1.0","event_id":"sha256:c7f7a4f45e5cc850ccab373e79a55a261492c9d8677a9d27e00d9b7c4b753d75"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2012:X6T2IQX23BKGZKFI2N6V22XLPZ","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Coherent Ro-vibrational Revivals in a Thermal Molecular Ensemble","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"quant-ph","authors_text":"Evgeny A. Shapiro, Martin Bitter, Valery Milner","submitted_at":"2012-02-18T01:38:41Z","abstract_excerpt":"We report an experimental and theoretical study of the evolution of vibrational coherence in a thermal ensemble of nitrogen molecules. Rotational dephasing and rephasing of the vibrational coherence is detected by coherent anti-Stokes Raman scattering. The existence of ro-vibrational coupling and the discrete energy spectrum of the rotational bath lead to a whole new class of full and fractional ro-vibrational revivals. Following the rich ro-vibrational dynamics on a nanosecond time scale with sub-picosecond time resolution enables us to determine the second-order ro-vibrational constant $gamm"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1202.4046","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T01:58:23Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"6l013DhgN6d43kR2M6B1lRXON8yeypSOzC5zRRbIcyJ0C44EpZg7hIx0S4YCXOZtlS4nWSktoarT1X5KMCttBg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-03T13:57:57.637324Z"},"content_sha256":"697bdb7092b3da02b630c3315efbaf0f3494c1a5bafa61f6c35664d313ab2653","schema_version":"1.0","event_id":"sha256:697bdb7092b3da02b630c3315efbaf0f3494c1a5bafa61f6c35664d313ab2653"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/X6T2IQX23BKGZKFI2N6V22XLPZ/bundle.json","state_url":"https://pith.science/pith/X6T2IQX23BKGZKFI2N6V22XLPZ/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/X6T2IQX23BKGZKFI2N6V22XLPZ/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-03T13:57:57Z","links":{"resolver":"https://pith.science/pith/X6T2IQX23BKGZKFI2N6V22XLPZ","bundle":"https://pith.science/pith/X6T2IQX23BKGZKFI2N6V22XLPZ/bundle.json","state":"https://pith.science/pith/X6T2IQX23BKGZKFI2N6V22XLPZ/state.json","well_known_bundle":"https://pith.science/.well-known/pith/X6T2IQX23BKGZKFI2N6V22XLPZ/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2012:X6T2IQX23BKGZKFI2N6V22XLPZ","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"0aaeccf78242887ced2fe712d04d4857aac96273bc6b392881568dee7a6b4e28","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2012-02-18T01:38:41Z","title_canon_sha256":"313f2046c59144a95733c5c9fa11d95bedf8803098944ae98d38032a7ddb21a1"},"schema_version":"1.0","source":{"id":"1202.4046","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1202.4046","created_at":"2026-05-18T01:58:23Z"},{"alias_kind":"arxiv_version","alias_value":"1202.4046v1","created_at":"2026-05-18T01:58:23Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1202.4046","created_at":"2026-05-18T01:58:23Z"},{"alias_kind":"pith_short_12","alias_value":"X6T2IQX23BKG","created_at":"2026-05-18T12:27:27Z"},{"alias_kind":"pith_short_16","alias_value":"X6T2IQX23BKGZKFI","created_at":"2026-05-18T12:27:27Z"},{"alias_kind":"pith_short_8","alias_value":"X6T2IQX2","created_at":"2026-05-18T12:27:27Z"}],"graph_snapshots":[{"event_id":"sha256:697bdb7092b3da02b630c3315efbaf0f3494c1a5bafa61f6c35664d313ab2653","target":"graph","created_at":"2026-05-18T01:58:23Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"We report an experimental and theoretical study of the evolution of vibrational coherence in a thermal ensemble of nitrogen molecules. Rotational dephasing and rephasing of the vibrational coherence is detected by coherent anti-Stokes Raman scattering. The existence of ro-vibrational coupling and the discrete energy spectrum of the rotational bath lead to a whole new class of full and fractional ro-vibrational revivals. Following the rich ro-vibrational dynamics on a nanosecond time scale with sub-picosecond time resolution enables us to determine the second-order ro-vibrational constant $gamm","authors_text":"Evgeny A. Shapiro, Martin Bitter, Valery Milner","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2012-02-18T01:38:41Z","title":"Coherent Ro-vibrational Revivals in a Thermal Molecular Ensemble"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1202.4046","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:c7f7a4f45e5cc850ccab373e79a55a261492c9d8677a9d27e00d9b7c4b753d75","target":"record","created_at":"2026-05-18T01:58:23Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"0aaeccf78242887ced2fe712d04d4857aac96273bc6b392881568dee7a6b4e28","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"quant-ph","submitted_at":"2012-02-18T01:38:41Z","title_canon_sha256":"313f2046c59144a95733c5c9fa11d95bedf8803098944ae98d38032a7ddb21a1"},"schema_version":"1.0","source":{"id":"1202.4046","kind":"arxiv","version":1}},"canonical_sha256":"bfa7a442fad8546ca8a8d37d5d6aeb7e74d780d9cc8ff659423e79fd8d27d2fa","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"bfa7a442fad8546ca8a8d37d5d6aeb7e74d780d9cc8ff659423e79fd8d27d2fa","first_computed_at":"2026-05-18T01:58:23.942962Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T01:58:23.942962Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"kWLJKopybr4w0hXFGgh75ry2fAM+Nee+WZ10ua+7Ww909yQrZRpqiVDkdABAs/Kqd1GwGZfiiRl4qPYUeoXGDg==","signature_status":"signed_v1","signed_at":"2026-05-18T01:58:23.943473Z","signed_message":"canonical_sha256_bytes"},"source_id":"1202.4046","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:c7f7a4f45e5cc850ccab373e79a55a261492c9d8677a9d27e00d9b7c4b753d75","sha256:697bdb7092b3da02b630c3315efbaf0f3494c1a5bafa61f6c35664d313ab2653"],"state_sha256":"6b8dde82a5aad46185da5d3135831486d19c7af2a1f53f06d296873d576de548"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"1/0lCRyYcfWteXj5b7o79JTfOmzoEdfdI2nl4wLgv0+7fkRvRKhWzYM1d4pg9hzJsb/rXVeCwpal/NlSzfz3Bg==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-03T13:57:57.639369Z","bundle_sha256":"e8e29408005f659b58f0501dee93929a8842f71d1821a8c094d5afce5def952b"}}