{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2017:XQELMPIYAAH63Z3ZQUGSMXK4GG","short_pith_number":"pith:XQELMPIY","canonical_record":{"source":{"id":"1706.09054","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2017-06-27T21:23:46Z","cross_cats_sorted":[],"title_canon_sha256":"96f113a34b9d10165f11c1bd2ae25299da7cf99a50efcea498473abc43d4c94c","abstract_canon_sha256":"65ec20c0405d097ae32e65594024dfd0f573be800269dce652f4bfa57c546697"},"schema_version":"1.0"},"canonical_sha256":"bc08b63d18000fede779850d265d5c318afcdd1dc2e729e538290c6c5b526e82","source":{"kind":"arxiv","id":"1706.09054","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1706.09054","created_at":"2026-05-18T00:34:17Z"},{"alias_kind":"arxiv_version","alias_value":"1706.09054v1","created_at":"2026-05-18T00:34:17Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1706.09054","created_at":"2026-05-18T00:34:17Z"},{"alias_kind":"pith_short_12","alias_value":"XQELMPIYAAH6","created_at":"2026-05-18T12:31:56Z"},{"alias_kind":"pith_short_16","alias_value":"XQELMPIYAAH63Z3Z","created_at":"2026-05-18T12:31:56Z"},{"alias_kind":"pith_short_8","alias_value":"XQELMPIY","created_at":"2026-05-18T12:31:56Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2017:XQELMPIYAAH63Z3ZQUGSMXK4GG","target":"record","payload":{"canonical_record":{"source":{"id":"1706.09054","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2017-06-27T21:23:46Z","cross_cats_sorted":[],"title_canon_sha256":"96f113a34b9d10165f11c1bd2ae25299da7cf99a50efcea498473abc43d4c94c","abstract_canon_sha256":"65ec20c0405d097ae32e65594024dfd0f573be800269dce652f4bfa57c546697"},"schema_version":"1.0"},"canonical_sha256":"bc08b63d18000fede779850d265d5c318afcdd1dc2e729e538290c6c5b526e82","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T00:34:17.824216Z","signature_b64":"GYJdUPpcpfYRwCUH6VQuUlC3ZNpkvsOaYLl2xDcwjh/VlsOgcdAhvuWGgQSvSUoJpwMD28khafxjn+rVvvlpDg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"bc08b63d18000fede779850d265d5c318afcdd1dc2e729e538290c6c5b526e82","last_reissued_at":"2026-05-18T00:34:17.823557Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T00:34:17.823557Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1706.09054","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:34:17Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"V/uD3cMqJXDUz9PO0J7upAXIegUp21aN55PIzT8GzeaC4nAIU1bcQnNJVSuUDnZ4U3gjiugY2IaX5YUnWk2aBg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-25T20:19:59.052022Z"},"content_sha256":"35e5cfaac592a8e5579e20dfd7e718f0d35996a1e752a7ac8c692d917e3c54c2","schema_version":"1.0","event_id":"sha256:35e5cfaac592a8e5579e20dfd7e718f0d35996a1e752a7ac8c692d917e3c54c2"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2017:XQELMPIYAAH63Z3ZQUGSMXK4GG","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Benchmark Results and Theoretical Treatments for Valence-to-Core X-ray Emission Spectroscopy in Transition Metal Compounds","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"C.P. Schwartz, D.G. Prendergrast, D.R. Mortensen, G.T. Seidler, J.J. Kas, Niranjin Govind, Sri Pemmaraju","submitted_at":"2017-06-27T21:23:46Z","abstract_excerpt":"We report measurement of the valence-to-core (VTC) region of the K-shell x-ray emission spectra from several Zn and Fe inorganic compounds, and their critical comparison with several existing theoretical treatments. We find generally good agreement between the respective theories and experiment, and in particular find an important admixture of dipole and quadrupole character for Zn materials that is much weaker in Fe-based systems. These results on materials whose simple crystal structures should not, a prior, pose deep challenges to theory, will prove useful in guiding the further development"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1706.09054","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:34:17Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"zWpoJqRfXcJ/erR7OJ++8Fa02ij4YHBSiUu9qfgr8puOLoEpZ5Rexz7mSxB1hQVoL6ytAsx6k1ymrjC/c+g5AA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-25T20:19:59.052689Z"},"content_sha256":"5a1cf82411f47c8d4da663c81806eb70725ece2b362152435e9b5f848a7a9d8a","schema_version":"1.0","event_id":"sha256:5a1cf82411f47c8d4da663c81806eb70725ece2b362152435e9b5f848a7a9d8a"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/XQELMPIYAAH63Z3ZQUGSMXK4GG/bundle.json","state_url":"https://pith.science/pith/XQELMPIYAAH63Z3ZQUGSMXK4GG/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/XQELMPIYAAH63Z3ZQUGSMXK4GG/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-05-25T20:19:59Z","links":{"resolver":"https://pith.science/pith/XQELMPIYAAH63Z3ZQUGSMXK4GG","bundle":"https://pith.science/pith/XQELMPIYAAH63Z3ZQUGSMXK4GG/bundle.json","state":"https://pith.science/pith/XQELMPIYAAH63Z3ZQUGSMXK4GG/state.json","well_known_bundle":"https://pith.science/.well-known/pith/XQELMPIYAAH63Z3ZQUGSMXK4GG/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2017:XQELMPIYAAH63Z3ZQUGSMXK4GG","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"65ec20c0405d097ae32e65594024dfd0f573be800269dce652f4bfa57c546697","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2017-06-27T21:23:46Z","title_canon_sha256":"96f113a34b9d10165f11c1bd2ae25299da7cf99a50efcea498473abc43d4c94c"},"schema_version":"1.0","source":{"id":"1706.09054","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1706.09054","created_at":"2026-05-18T00:34:17Z"},{"alias_kind":"arxiv_version","alias_value":"1706.09054v1","created_at":"2026-05-18T00:34:17Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1706.09054","created_at":"2026-05-18T00:34:17Z"},{"alias_kind":"pith_short_12","alias_value":"XQELMPIYAAH6","created_at":"2026-05-18T12:31:56Z"},{"alias_kind":"pith_short_16","alias_value":"XQELMPIYAAH63Z3Z","created_at":"2026-05-18T12:31:56Z"},{"alias_kind":"pith_short_8","alias_value":"XQELMPIY","created_at":"2026-05-18T12:31:56Z"}],"graph_snapshots":[{"event_id":"sha256:5a1cf82411f47c8d4da663c81806eb70725ece2b362152435e9b5f848a7a9d8a","target":"graph","created_at":"2026-05-18T00:34:17Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"We report measurement of the valence-to-core (VTC) region of the K-shell x-ray emission spectra from several Zn and Fe inorganic compounds, and their critical comparison with several existing theoretical treatments. We find generally good agreement between the respective theories and experiment, and in particular find an important admixture of dipole and quadrupole character for Zn materials that is much weaker in Fe-based systems. These results on materials whose simple crystal structures should not, a prior, pose deep challenges to theory, will prove useful in guiding the further development","authors_text":"C.P. Schwartz, D.G. Prendergrast, D.R. Mortensen, G.T. Seidler, J.J. Kas, Niranjin Govind, Sri Pemmaraju","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2017-06-27T21:23:46Z","title":"Benchmark Results and Theoretical Treatments for Valence-to-Core X-ray Emission Spectroscopy in Transition Metal Compounds"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1706.09054","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:35e5cfaac592a8e5579e20dfd7e718f0d35996a1e752a7ac8c692d917e3c54c2","target":"record","created_at":"2026-05-18T00:34:17Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"65ec20c0405d097ae32e65594024dfd0f573be800269dce652f4bfa57c546697","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2017-06-27T21:23:46Z","title_canon_sha256":"96f113a34b9d10165f11c1bd2ae25299da7cf99a50efcea498473abc43d4c94c"},"schema_version":"1.0","source":{"id":"1706.09054","kind":"arxiv","version":1}},"canonical_sha256":"bc08b63d18000fede779850d265d5c318afcdd1dc2e729e538290c6c5b526e82","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"bc08b63d18000fede779850d265d5c318afcdd1dc2e729e538290c6c5b526e82","first_computed_at":"2026-05-18T00:34:17.823557Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T00:34:17.823557Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"GYJdUPpcpfYRwCUH6VQuUlC3ZNpkvsOaYLl2xDcwjh/VlsOgcdAhvuWGgQSvSUoJpwMD28khafxjn+rVvvlpDg==","signature_status":"signed_v1","signed_at":"2026-05-18T00:34:17.824216Z","signed_message":"canonical_sha256_bytes"},"source_id":"1706.09054","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:35e5cfaac592a8e5579e20dfd7e718f0d35996a1e752a7ac8c692d917e3c54c2","sha256:5a1cf82411f47c8d4da663c81806eb70725ece2b362152435e9b5f848a7a9d8a"],"state_sha256":"ce6b8ce031682dc1174b02e7879e5c3f1bc59714dd33d8b55f0d983ef7815734"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"DrYuLWyLyL+4DBfG5TvCNbn07PP8ktBOz26PpaCw/P5qgARZ5zl6FM9TteApyZ9WK3neez965EPOkLYZyJrxBQ==","signed_message":"bundle_sha256_bytes","signed_at":"2026-05-25T20:19:59.056410Z","bundle_sha256":"dcde6c3165bb1de4f224f8e74caf3d5a8063f0bc15f5d1fc693af93f696e96df"}}