{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2024:YHSBV6JJN32MNZWS5LL2O5CXA5","short_pith_number":"pith:YHSBV6JJ","canonical_record":{"source":{"id":"2406.13313","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2024-06-19T08:02:14Z","cross_cats_sorted":[],"title_canon_sha256":"b511661e19849593dc66213295b3d668c67ddb47f1e096bca7042f106e2c7a16","abstract_canon_sha256":"7982f07b574b6dbb58ae9d99fe1df790d915ee45a37b881c8356caf6daeeaa17"},"schema_version":"1.0"},"canonical_sha256":"c1e41af9296ef4c6e6d2ead7a77457077a2a7de0550eb1ab3b139aba577c7dab","source":{"kind":"arxiv","id":"2406.13313","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2406.13313","created_at":"2026-07-05T08:34:28Z"},{"alias_kind":"arxiv_version","alias_value":"2406.13313v1","created_at":"2026-07-05T08:34:28Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2406.13313","created_at":"2026-07-05T08:34:28Z"},{"alias_kind":"pith_short_12","alias_value":"YHSBV6JJN32M","created_at":"2026-07-05T08:34:28Z"},{"alias_kind":"pith_short_16","alias_value":"YHSBV6JJN32MNZWS","created_at":"2026-07-05T08:34:28Z"},{"alias_kind":"pith_short_8","alias_value":"YHSBV6JJ","created_at":"2026-07-05T08:34:28Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2024:YHSBV6JJN32MNZWS5LL2O5CXA5","target":"record","payload":{"canonical_record":{"source":{"id":"2406.13313","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2024-06-19T08:02:14Z","cross_cats_sorted":[],"title_canon_sha256":"b511661e19849593dc66213295b3d668c67ddb47f1e096bca7042f106e2c7a16","abstract_canon_sha256":"7982f07b574b6dbb58ae9d99fe1df790d915ee45a37b881c8356caf6daeeaa17"},"schema_version":"1.0"},"canonical_sha256":"c1e41af9296ef4c6e6d2ead7a77457077a2a7de0550eb1ab3b139aba577c7dab","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T08:34:28.280629Z","signature_b64":"bPt3seZ+0Xvt4mUdGULx5IIZ1P67kh3oQyKVnpJpGWxQ8kxS1z+p0lp6jrs/aV3+Fk8D9UoJj2ttbLu//1J2CQ==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"c1e41af9296ef4c6e6d2ead7a77457077a2a7de0550eb1ab3b139aba577c7dab","last_reissued_at":"2026-07-05T08:34:28.280209Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T08:34:28.280209Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"2406.13313","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T08:34:28Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"69h7iYTl8js/YymRzJqDMsx7bQyniXpiO5Iy/uY1fJPid2sKu7lAPCKrSyazU/41CuhtjzM43kMHR16X8TjYCg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-21T17:50:13.547846Z"},"content_sha256":"ad601076abd350125584c4850fa7531551e03827fbbf9e74ac0b2eb2b2704204","schema_version":"1.0","event_id":"sha256:ad601076abd350125584c4850fa7531551e03827fbbf9e74ac0b2eb2b2704204"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2024:YHSBV6JJN32MNZWS5LL2O5CXA5","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Solution-dependent electrostatic spray deposition (ESD) ZnO thin film growth processes","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mtrl-sci","authors_text":"Fysol Ibna Abbas, Mutsumi Sugiyama","submitted_at":"2024-06-19T08:02:14Z","abstract_excerpt":"The present study describes a facile route of zinc oxide (ZnO) grows using the solution-dependent electrostatic spray deposition (ESD) method at temperatures ranging from 300 {\\deg}C - 500 {\\deg}C. In this work, zinc chloride (ZnCl2) was dissolved in ethanol (CH3CH2OH) to prepare the 0.1 M concentration of 20 ml for spray solution by ESD. Adding different deionized water (H2O) ratio, three different solutions were prepared. The results reveal that adding H2O ration, suppressing the c-axis crystal growth of ZnO thin films. The adhesion of anions was believed to be responsible for this suppressi"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2406.13313","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2406.13313/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T08:34:28Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"7dK4NxOIMTx6+sP8VCrhT9vuIjZDe4jA2lAWiA/EPvjE5e8XsR9QERQm8BSq+BabF9jokUuz7MXCVwq24m7aDQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-21T17:50:13.548431Z"},"content_sha256":"4db4c8495712a9ae063f75904d33ae0199affa3c880eaf060db98aeb7fa68737","schema_version":"1.0","event_id":"sha256:4db4c8495712a9ae063f75904d33ae0199affa3c880eaf060db98aeb7fa68737"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/YHSBV6JJN32MNZWS5LL2O5CXA5/bundle.json","state_url":"https://pith.science/pith/YHSBV6JJN32MNZWS5LL2O5CXA5/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/YHSBV6JJN32MNZWS5LL2O5CXA5/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-08-21T17:50:13Z","links":{"resolver":"https://pith.science/pith/YHSBV6JJN32MNZWS5LL2O5CXA5","bundle":"https://pith.science/pith/YHSBV6JJN32MNZWS5LL2O5CXA5/bundle.json","state":"https://pith.science/pith/YHSBV6JJN32MNZWS5LL2O5CXA5/state.json","well_known_bundle":"https://pith.science/.well-known/pith/YHSBV6JJN32MNZWS5LL2O5CXA5/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2024:YHSBV6JJN32MNZWS5LL2O5CXA5","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"7982f07b574b6dbb58ae9d99fe1df790d915ee45a37b881c8356caf6daeeaa17","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2024-06-19T08:02:14Z","title_canon_sha256":"b511661e19849593dc66213295b3d668c67ddb47f1e096bca7042f106e2c7a16"},"schema_version":"1.0","source":{"id":"2406.13313","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2406.13313","created_at":"2026-07-05T08:34:28Z"},{"alias_kind":"arxiv_version","alias_value":"2406.13313v1","created_at":"2026-07-05T08:34:28Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2406.13313","created_at":"2026-07-05T08:34:28Z"},{"alias_kind":"pith_short_12","alias_value":"YHSBV6JJN32M","created_at":"2026-07-05T08:34:28Z"},{"alias_kind":"pith_short_16","alias_value":"YHSBV6JJN32MNZWS","created_at":"2026-07-05T08:34:28Z"},{"alias_kind":"pith_short_8","alias_value":"YHSBV6JJ","created_at":"2026-07-05T08:34:28Z"}],"graph_snapshots":[{"event_id":"sha256:4db4c8495712a9ae063f75904d33ae0199affa3c880eaf060db98aeb7fa68737","target":"graph","created_at":"2026-07-05T08:34:28Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2406.13313/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"The present study describes a facile route of zinc oxide (ZnO) grows using the solution-dependent electrostatic spray deposition (ESD) method at temperatures ranging from 300 {\\deg}C - 500 {\\deg}C. In this work, zinc chloride (ZnCl2) was dissolved in ethanol (CH3CH2OH) to prepare the 0.1 M concentration of 20 ml for spray solution by ESD. Adding different deionized water (H2O) ratio, three different solutions were prepared. The results reveal that adding H2O ration, suppressing the c-axis crystal growth of ZnO thin films. The adhesion of anions was believed to be responsible for this suppressi","authors_text":"Fysol Ibna Abbas, Mutsumi Sugiyama","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2024-06-19T08:02:14Z","title":"Solution-dependent electrostatic spray deposition (ESD) ZnO thin film growth processes"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2406.13313","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:ad601076abd350125584c4850fa7531551e03827fbbf9e74ac0b2eb2b2704204","target":"record","created_at":"2026-07-05T08:34:28Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"7982f07b574b6dbb58ae9d99fe1df790d915ee45a37b881c8356caf6daeeaa17","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mtrl-sci","submitted_at":"2024-06-19T08:02:14Z","title_canon_sha256":"b511661e19849593dc66213295b3d668c67ddb47f1e096bca7042f106e2c7a16"},"schema_version":"1.0","source":{"id":"2406.13313","kind":"arxiv","version":1}},"canonical_sha256":"c1e41af9296ef4c6e6d2ead7a77457077a2a7de0550eb1ab3b139aba577c7dab","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"c1e41af9296ef4c6e6d2ead7a77457077a2a7de0550eb1ab3b139aba577c7dab","first_computed_at":"2026-07-05T08:34:28.280209Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-05T08:34:28.280209Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"bPt3seZ+0Xvt4mUdGULx5IIZ1P67kh3oQyKVnpJpGWxQ8kxS1z+p0lp6jrs/aV3+Fk8D9UoJj2ttbLu//1J2CQ==","signature_status":"signed_v1","signed_at":"2026-07-05T08:34:28.280629Z","signed_message":"canonical_sha256_bytes"},"source_id":"2406.13313","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:ad601076abd350125584c4850fa7531551e03827fbbf9e74ac0b2eb2b2704204","sha256:4db4c8495712a9ae063f75904d33ae0199affa3c880eaf060db98aeb7fa68737"],"state_sha256":"6d7fcb3be13ef7d767c07ba4fd5b27bca728cf7478e5aedfacadfab6f9aa797c"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"ZOrLt2fpXUQ3ONO14Z2A9klaJKsJ+Ng37MRUtZ6e5JYBb6iKBBLSfDiAsD94agdgIPul5pYIYzrgPzGKGu9pDA==","signed_message":"bundle_sha256_bytes","signed_at":"2026-08-21T17:50:13.554473Z","bundle_sha256":"2096703dee3f1b8e9d8d8da302baa2ae17b549f01a7a077019c2dc379b587ec7"}}