{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2014:YHXTUL6QRPEAKCJ6MNP4JTY4KY","short_pith_number":"pith:YHXTUL6Q","canonical_record":{"source":{"id":"1403.4266","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mes-hall","submitted_at":"2014-03-17T20:29:37Z","cross_cats_sorted":[],"title_canon_sha256":"24886381a799c5e3e8c921391d904737870e94a2ad3d8015ee14730ad06a6747","abstract_canon_sha256":"fb96f354ae3845c90a521098457bd9e97b9bab86dab3b5c10d3efb23e61f6da4"},"schema_version":"1.0"},"canonical_sha256":"c1ef3a2fd08bc805093e635fc4cf1c5633caaaa2b7ed8b3e4ed984ed657b23f7","source":{"kind":"arxiv","id":"1403.4266","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1403.4266","created_at":"2026-05-18T02:56:06Z"},{"alias_kind":"arxiv_version","alias_value":"1403.4266v1","created_at":"2026-05-18T02:56:06Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1403.4266","created_at":"2026-05-18T02:56:06Z"},{"alias_kind":"pith_short_12","alias_value":"YHXTUL6QRPEA","created_at":"2026-05-18T12:28:57Z"},{"alias_kind":"pith_short_16","alias_value":"YHXTUL6QRPEAKCJ6","created_at":"2026-05-18T12:28:57Z"},{"alias_kind":"pith_short_8","alias_value":"YHXTUL6Q","created_at":"2026-05-18T12:28:57Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2014:YHXTUL6QRPEAKCJ6MNP4JTY4KY","target":"record","payload":{"canonical_record":{"source":{"id":"1403.4266","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mes-hall","submitted_at":"2014-03-17T20:29:37Z","cross_cats_sorted":[],"title_canon_sha256":"24886381a799c5e3e8c921391d904737870e94a2ad3d8015ee14730ad06a6747","abstract_canon_sha256":"fb96f354ae3845c90a521098457bd9e97b9bab86dab3b5c10d3efb23e61f6da4"},"schema_version":"1.0"},"canonical_sha256":"c1ef3a2fd08bc805093e635fc4cf1c5633caaaa2b7ed8b3e4ed984ed657b23f7","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T02:56:06.099147Z","signature_b64":"B/d0cc8vqqQVw3/bmcj4NEXyebQdBzfizUvhv4EGf+UtM8Q4Sjo8T81A+mMGPqFKgfx2386StveNGqJzWDTRDw==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"c1ef3a2fd08bc805093e635fc4cf1c5633caaaa2b7ed8b3e4ed984ed657b23f7","last_reissued_at":"2026-05-18T02:56:06.098749Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T02:56:06.098749Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1403.4266","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T02:56:06Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"BbZhRdnWKROzMy4IsFI405JaNuWaea/DsvP+XEW0We+0BJKalHJBvszZhmu6H5qGRpyIMlc81gf9mJl7S77xDg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-23T20:24:55.704778Z"},"content_sha256":"181d3029ac77a5c0aad0409392016f1c0427edc7564f5789fa3da759b74392b2","schema_version":"1.0","event_id":"sha256:181d3029ac77a5c0aad0409392016f1c0427edc7564f5789fa3da759b74392b2"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2014:YHXTUL6QRPEAKCJ6MNP4JTY4KY","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Large tunable image-charge effects in single-molecule junctions","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mes-hall","authors_text":"A.J. Shaikh, C.A. Martin, C.J.O. Verzijl, D.Duli\\'c, H.S.J. van der Zant, J.H. van Esch, J.M. Thijssen, J.M. van Ruitenbeek, M.L. Perrin, R. Eelkema","submitted_at":"2014-03-17T20:29:37Z","abstract_excerpt":"The characteristics of molecular electronic devices are critically determined by metal-organic interfaces, which influence the arrangement of the orbital levels that participate in charge transport. Studies on self-assembled monolayers (SAMs) show (molecule-dependent) level shifts as well as transport-gap renormalization, suggesting that polarization effects in the metal substrate play a key role in the level alignment with respect to the metal's Fermi energy. Here, we provide direct evidence for an electrode-induced gap renormalization in single-molecule junctions. We study charge transport i"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1403.4266","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T02:56:06Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"aSdh417kAtzCOO/AkoINPuFhcOyv+uo9OKbEK3jfUYIYye2Bp8GgBf+2ngks84ptNMIQHNK1maMan8TKE5knDw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-23T20:24:55.705486Z"},"content_sha256":"d21236b3833f2b35c77004b82c6bfe23a5334a36a5f6baf9911549fa2228ede9","schema_version":"1.0","event_id":"sha256:d21236b3833f2b35c77004b82c6bfe23a5334a36a5f6baf9911549fa2228ede9"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/YHXTUL6QRPEAKCJ6MNP4JTY4KY/bundle.json","state_url":"https://pith.science/pith/YHXTUL6QRPEAKCJ6MNP4JTY4KY/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/YHXTUL6QRPEAKCJ6MNP4JTY4KY/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-05-23T20:24:55Z","links":{"resolver":"https://pith.science/pith/YHXTUL6QRPEAKCJ6MNP4JTY4KY","bundle":"https://pith.science/pith/YHXTUL6QRPEAKCJ6MNP4JTY4KY/bundle.json","state":"https://pith.science/pith/YHXTUL6QRPEAKCJ6MNP4JTY4KY/state.json","well_known_bundle":"https://pith.science/.well-known/pith/YHXTUL6QRPEAKCJ6MNP4JTY4KY/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2014:YHXTUL6QRPEAKCJ6MNP4JTY4KY","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"fb96f354ae3845c90a521098457bd9e97b9bab86dab3b5c10d3efb23e61f6da4","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mes-hall","submitted_at":"2014-03-17T20:29:37Z","title_canon_sha256":"24886381a799c5e3e8c921391d904737870e94a2ad3d8015ee14730ad06a6747"},"schema_version":"1.0","source":{"id":"1403.4266","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1403.4266","created_at":"2026-05-18T02:56:06Z"},{"alias_kind":"arxiv_version","alias_value":"1403.4266v1","created_at":"2026-05-18T02:56:06Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1403.4266","created_at":"2026-05-18T02:56:06Z"},{"alias_kind":"pith_short_12","alias_value":"YHXTUL6QRPEA","created_at":"2026-05-18T12:28:57Z"},{"alias_kind":"pith_short_16","alias_value":"YHXTUL6QRPEAKCJ6","created_at":"2026-05-18T12:28:57Z"},{"alias_kind":"pith_short_8","alias_value":"YHXTUL6Q","created_at":"2026-05-18T12:28:57Z"}],"graph_snapshots":[{"event_id":"sha256:d21236b3833f2b35c77004b82c6bfe23a5334a36a5f6baf9911549fa2228ede9","target":"graph","created_at":"2026-05-18T02:56:06Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"The characteristics of molecular electronic devices are critically determined by metal-organic interfaces, which influence the arrangement of the orbital levels that participate in charge transport. Studies on self-assembled monolayers (SAMs) show (molecule-dependent) level shifts as well as transport-gap renormalization, suggesting that polarization effects in the metal substrate play a key role in the level alignment with respect to the metal's Fermi energy. Here, we provide direct evidence for an electrode-induced gap renormalization in single-molecule junctions. We study charge transport i","authors_text":"A.J. Shaikh, C.A. Martin, C.J.O. Verzijl, D.Duli\\'c, H.S.J. van der Zant, J.H. van Esch, J.M. Thijssen, J.M. van Ruitenbeek, M.L. Perrin, R. Eelkema","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mes-hall","submitted_at":"2014-03-17T20:29:37Z","title":"Large tunable image-charge effects in single-molecule junctions"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1403.4266","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:181d3029ac77a5c0aad0409392016f1c0427edc7564f5789fa3da759b74392b2","target":"record","created_at":"2026-05-18T02:56:06Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"fb96f354ae3845c90a521098457bd9e97b9bab86dab3b5c10d3efb23e61f6da4","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mes-hall","submitted_at":"2014-03-17T20:29:37Z","title_canon_sha256":"24886381a799c5e3e8c921391d904737870e94a2ad3d8015ee14730ad06a6747"},"schema_version":"1.0","source":{"id":"1403.4266","kind":"arxiv","version":1}},"canonical_sha256":"c1ef3a2fd08bc805093e635fc4cf1c5633caaaa2b7ed8b3e4ed984ed657b23f7","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"c1ef3a2fd08bc805093e635fc4cf1c5633caaaa2b7ed8b3e4ed984ed657b23f7","first_computed_at":"2026-05-18T02:56:06.098749Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T02:56:06.098749Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"B/d0cc8vqqQVw3/bmcj4NEXyebQdBzfizUvhv4EGf+UtM8Q4Sjo8T81A+mMGPqFKgfx2386StveNGqJzWDTRDw==","signature_status":"signed_v1","signed_at":"2026-05-18T02:56:06.099147Z","signed_message":"canonical_sha256_bytes"},"source_id":"1403.4266","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:181d3029ac77a5c0aad0409392016f1c0427edc7564f5789fa3da759b74392b2","sha256:d21236b3833f2b35c77004b82c6bfe23a5334a36a5f6baf9911549fa2228ede9"],"state_sha256":"f0b596b5c46730191d77866e7fd133972eff23778189468170bde2432298543d"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"X9Bs3s/I9q+da6dVrNlcyeuVaku3dTkpt842jwbEvT5DFo1FqrBcexh6HVazhuMw9e2KbG4GUcfkCFzoiCEPBg==","signed_message":"bundle_sha256_bytes","signed_at":"2026-05-23T20:24:55.713392Z","bundle_sha256":"3be1522ad8bd45debeb78b58e8c45038b8bafdebbfcc9f15c0631b9457e129aa"}}