{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2025:YI24XQ3ATX65JTJCRY4VJRFUS3","short_pith_number":"pith:YI24XQ3A","canonical_record":{"source":{"id":"2506.18984","kind":"arxiv","version":2},"metadata":{"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"cond-mat.str-el","submitted_at":"2025-06-23T18:00:03Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"01fba4d226ff4fb40739f386c368db93321dde473c3ad83ba3ad08ea6eb48951","abstract_canon_sha256":"e668ed584ff967c022bc0cc03820dde1b8c4b88ac91698f9da731fbea2675da6"},"schema_version":"1.0"},"canonical_sha256":"c235cbc3609dfdd4cd228e3954c4b496d39ce8a6a8907d0fc40b5184696a6509","source":{"kind":"arxiv","id":"2506.18984","version":2},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2506.18984","created_at":"2026-07-05T11:37:45Z"},{"alias_kind":"arxiv_version","alias_value":"2506.18984v2","created_at":"2026-07-05T11:37:45Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2506.18984","created_at":"2026-07-05T11:37:45Z"},{"alias_kind":"pith_short_12","alias_value":"YI24XQ3ATX65","created_at":"2026-07-05T11:37:45Z"},{"alias_kind":"pith_short_16","alias_value":"YI24XQ3ATX65JTJC","created_at":"2026-07-05T11:37:45Z"},{"alias_kind":"pith_short_8","alias_value":"YI24XQ3A","created_at":"2026-07-05T11:37:45Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2025:YI24XQ3ATX65JTJCRY4VJRFUS3","target":"record","payload":{"canonical_record":{"source":{"id":"2506.18984","kind":"arxiv","version":2},"metadata":{"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"cond-mat.str-el","submitted_at":"2025-06-23T18:00:03Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"01fba4d226ff4fb40739f386c368db93321dde473c3ad83ba3ad08ea6eb48951","abstract_canon_sha256":"e668ed584ff967c022bc0cc03820dde1b8c4b88ac91698f9da731fbea2675da6"},"schema_version":"1.0"},"canonical_sha256":"c235cbc3609dfdd4cd228e3954c4b496d39ce8a6a8907d0fc40b5184696a6509","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T11:37:45.114398Z","signature_b64":"zouHwqkNsLJmozYYlnTuQ38Sb7O6Ls9C5tcU03Y1NDsXrFEkfzgQ4ZGuTCaGVtAX+ftFTBeGp6pxnxH7hL+VDw==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"c235cbc3609dfdd4cd228e3954c4b496d39ce8a6a8907d0fc40b5184696a6509","last_reissued_at":"2026-07-05T11:37:45.113837Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T11:37:45.113837Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"2506.18984","source_version":2,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T11:37:45Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"Oq62fuay8VoBCt5IfRPz7Rssjl+NxRmtXW6xCQCMpg40xlWsl71sFxzAEeSwP3/aYSMTEaI5WfXa5Ik/lDIdCw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-16T20:30:33.554179Z"},"content_sha256":"46d84a8776bb9c0404079e860821c7dd846eda78cdccf23a723a527fb1992d69","schema_version":"1.0","event_id":"sha256:46d84a8776bb9c0404079e860821c7dd846eda78cdccf23a723a527fb1992d69"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2025:YI24XQ3ATX65JTJCRY4VJRFUS3","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Topological Transitions in Orbital-Symmetry-Controlled Chemical Reactions","license":"http://creativecommons.org/licenses/by/4.0/","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"cond-mat.str-el","authors_text":"Amir Mirzanejad, Lukas Muechler, Ziren Xie","submitted_at":"2025-06-23T18:00:03Z","abstract_excerpt":"Topological band theory has transformed our understanding of crystalline materials by classifying the connectivity and crossings of electronic energy levels. Extending these concepts to molecular systems has therefore attracted significant interest. Reactions governed by orbital symmetry conservation are ideal candidates, as they classify pathways as symmetry-allowed or symmetry-forbidden depending on whether molecular orbitals cross along the reaction coordinate. However, the presence of strong electronic correlations in these reactions invalidate the framework underlying topological band the"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2506.18984","kind":"arxiv","version":2},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2506.18984/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T11:37:45Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"zQgz/5o0W7P+fB6KbB2hrGj5rSZBQnnIDsAgBOUpq3v1n04aFHTEVtFfYQ7zmM2wgGj8dQBMvHFcajqSBRVDDg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-16T20:30:33.555694Z"},"content_sha256":"46abe3e3108898b2b783d4591df78964098b61fd5b34a238a143a81613e08835","schema_version":"1.0","event_id":"sha256:46abe3e3108898b2b783d4591df78964098b61fd5b34a238a143a81613e08835"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/YI24XQ3ATX65JTJCRY4VJRFUS3/bundle.json","state_url":"https://pith.science/pith/YI24XQ3ATX65JTJCRY4VJRFUS3/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/YI24XQ3ATX65JTJCRY4VJRFUS3/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-08-16T20:30:33Z","links":{"resolver":"https://pith.science/pith/YI24XQ3ATX65JTJCRY4VJRFUS3","bundle":"https://pith.science/pith/YI24XQ3ATX65JTJCRY4VJRFUS3/bundle.json","state":"https://pith.science/pith/YI24XQ3ATX65JTJCRY4VJRFUS3/state.json","well_known_bundle":"https://pith.science/.well-known/pith/YI24XQ3ATX65JTJCRY4VJRFUS3/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2025:YI24XQ3ATX65JTJCRY4VJRFUS3","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"e668ed584ff967c022bc0cc03820dde1b8c4b88ac91698f9da731fbea2675da6","cross_cats_sorted":["physics.chem-ph"],"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"cond-mat.str-el","submitted_at":"2025-06-23T18:00:03Z","title_canon_sha256":"01fba4d226ff4fb40739f386c368db93321dde473c3ad83ba3ad08ea6eb48951"},"schema_version":"1.0","source":{"id":"2506.18984","kind":"arxiv","version":2}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2506.18984","created_at":"2026-07-05T11:37:45Z"},{"alias_kind":"arxiv_version","alias_value":"2506.18984v2","created_at":"2026-07-05T11:37:45Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2506.18984","created_at":"2026-07-05T11:37:45Z"},{"alias_kind":"pith_short_12","alias_value":"YI24XQ3ATX65","created_at":"2026-07-05T11:37:45Z"},{"alias_kind":"pith_short_16","alias_value":"YI24XQ3ATX65JTJC","created_at":"2026-07-05T11:37:45Z"},{"alias_kind":"pith_short_8","alias_value":"YI24XQ3A","created_at":"2026-07-05T11:37:45Z"}],"graph_snapshots":[{"event_id":"sha256:46abe3e3108898b2b783d4591df78964098b61fd5b34a238a143a81613e08835","target":"graph","created_at":"2026-07-05T11:37:45Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2506.18984/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"Topological band theory has transformed our understanding of crystalline materials by classifying the connectivity and crossings of electronic energy levels. Extending these concepts to molecular systems has therefore attracted significant interest. Reactions governed by orbital symmetry conservation are ideal candidates, as they classify pathways as symmetry-allowed or symmetry-forbidden depending on whether molecular orbitals cross along the reaction coordinate. However, the presence of strong electronic correlations in these reactions invalidate the framework underlying topological band the","authors_text":"Amir Mirzanejad, Lukas Muechler, Ziren Xie","cross_cats":["physics.chem-ph"],"headline":"","license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"cond-mat.str-el","submitted_at":"2025-06-23T18:00:03Z","title":"Topological Transitions in Orbital-Symmetry-Controlled Chemical Reactions"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2506.18984","kind":"arxiv","version":2},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:46d84a8776bb9c0404079e860821c7dd846eda78cdccf23a723a527fb1992d69","target":"record","created_at":"2026-07-05T11:37:45Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"e668ed584ff967c022bc0cc03820dde1b8c4b88ac91698f9da731fbea2675da6","cross_cats_sorted":["physics.chem-ph"],"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"cond-mat.str-el","submitted_at":"2025-06-23T18:00:03Z","title_canon_sha256":"01fba4d226ff4fb40739f386c368db93321dde473c3ad83ba3ad08ea6eb48951"},"schema_version":"1.0","source":{"id":"2506.18984","kind":"arxiv","version":2}},"canonical_sha256":"c235cbc3609dfdd4cd228e3954c4b496d39ce8a6a8907d0fc40b5184696a6509","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"c235cbc3609dfdd4cd228e3954c4b496d39ce8a6a8907d0fc40b5184696a6509","first_computed_at":"2026-07-05T11:37:45.113837Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-05T11:37:45.113837Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"zouHwqkNsLJmozYYlnTuQ38Sb7O6Ls9C5tcU03Y1NDsXrFEkfzgQ4ZGuTCaGVtAX+ftFTBeGp6pxnxH7hL+VDw==","signature_status":"signed_v1","signed_at":"2026-07-05T11:37:45.114398Z","signed_message":"canonical_sha256_bytes"},"source_id":"2506.18984","source_kind":"arxiv","source_version":2}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:46d84a8776bb9c0404079e860821c7dd846eda78cdccf23a723a527fb1992d69","sha256:46abe3e3108898b2b783d4591df78964098b61fd5b34a238a143a81613e08835"],"state_sha256":"d3f8cc84c895af1309dd361f3cb2dc0bfeca45b0d99183d617d8f4f45a991ce7"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"amIeehevuLHOfxe/KqEiUze5McV7vVnHuP+rzEOaIhmj+A1ZdDEK3UsR5UHE3xanMYdtPQpMy1r/qIJBhVEDAw==","signed_message":"bundle_sha256_bytes","signed_at":"2026-08-16T20:30:33.564304Z","bundle_sha256":"1fe04daa7be37c8d1673492634217dfa1d7747e049d0dc4e054c0895fca184e1"}}