{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2018:YIGZJ7JDA34HB7SQGPZN2WB7N2","short_pith_number":"pith:YIGZJ7JD","canonical_record":{"source":{"id":"1802.09782","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.ao-ph","submitted_at":"2018-02-27T09:07:55Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"5e77855afbc158588c18e073a29da62ec7631a8fd4685beb122a267b280c6542","abstract_canon_sha256":"e1743a0b036089d216ba938114a05750f710cedc9971469a3c21fe9cbe3b27bb"},"schema_version":"1.0"},"canonical_sha256":"c20d94fd2306f870fe5033f2dd583f6e80977966270257b251214b95d4ba29b9","source":{"kind":"arxiv","id":"1802.09782","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1802.09782","created_at":"2026-05-18T00:18:00Z"},{"alias_kind":"arxiv_version","alias_value":"1802.09782v1","created_at":"2026-05-18T00:18:00Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1802.09782","created_at":"2026-05-18T00:18:00Z"},{"alias_kind":"pith_short_12","alias_value":"YIGZJ7JDA34H","created_at":"2026-05-18T12:33:04Z"},{"alias_kind":"pith_short_16","alias_value":"YIGZJ7JDA34HB7SQ","created_at":"2026-05-18T12:33:04Z"},{"alias_kind":"pith_short_8","alias_value":"YIGZJ7JD","created_at":"2026-05-18T12:33:04Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2018:YIGZJ7JDA34HB7SQGPZN2WB7N2","target":"record","payload":{"canonical_record":{"source":{"id":"1802.09782","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.ao-ph","submitted_at":"2018-02-27T09:07:55Z","cross_cats_sorted":["physics.chem-ph"],"title_canon_sha256":"5e77855afbc158588c18e073a29da62ec7631a8fd4685beb122a267b280c6542","abstract_canon_sha256":"e1743a0b036089d216ba938114a05750f710cedc9971469a3c21fe9cbe3b27bb"},"schema_version":"1.0"},"canonical_sha256":"c20d94fd2306f870fe5033f2dd583f6e80977966270257b251214b95d4ba29b9","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T00:18:00.738993Z","signature_b64":"w1BcSHmbHgL36Gj7gnBvM1H6CUVA2+CAnegzH7CvmccTBOxLhErZvlSbMABQ7hURO4PUBd3q5+ZROqh5Fig2Bg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"c20d94fd2306f870fe5033f2dd583f6e80977966270257b251214b95d4ba29b9","last_reissued_at":"2026-05-18T00:18:00.738217Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T00:18:00.738217Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1802.09782","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:18:00Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"bsllURQgis/T7VbNYmRXIuJzx4t4xK/WgrabMRuAoGek55THH3tLzZI4To6M4LWYLr9jlxyr4bfxypX5vK5oAg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-22T11:11:22.943142Z"},"content_sha256":"6f8b5f1fe9e176a983651fef8a660aa423856742a4101d4d1e4a628f041652f4","schema_version":"1.0","event_id":"sha256:6f8b5f1fe9e176a983651fef8a660aa423856742a4101d4d1e4a628f041652f4"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2018:YIGZJ7JDA34HB7SQGPZN2WB7N2","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Potential energy surface, dipole moment surface and the intensity calculations for the 10 micron, 5 micron, and 3 micron bands of ozone","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":["physics.chem-ph"],"primary_cat":"physics.ao-ph","authors_text":"Aleksandra A. Kyuberis, Irina I. Mizus, Jonathan Tennyson, Lorenzo Lodi, Nikolai F. Zobov, Oleg L. Polyansky","submitted_at":"2018-02-27T09:07:55Z","abstract_excerpt":"Monitoring ozone concentrations in the Earth's atmosphere using spectroscopic methods is a major activity which undertaken both from the ground and from space. However there are long-running issues of consistency between measurements made at infrared (IR) and ultraviolet (UV) wavelengths. In addition, key O$_3$ IR bands at 10 \\muu, 5 \\muu\\ and 3 \\muu\\ also yield results which differ by a few percent when used for retrievals. These problems stem from the underlying laboratory measurements of the line intensities. Here we use quantum chemical techniques, first principles electronic structure and"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1802.09782","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:18:00Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"wqBKEHUG8eQFZZGf5YWdARb5GdSsAgeVEteSsBIVlZPNmSSVZJKXGWQ98rIwdWEskFz1P1x4oi/ZXwPUOufHCw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-22T11:11:22.943502Z"},"content_sha256":"6fd07be24698de32305ad5c27e86e6f533059451a26a54c836a40aa9f2ebfcfb","schema_version":"1.0","event_id":"sha256:6fd07be24698de32305ad5c27e86e6f533059451a26a54c836a40aa9f2ebfcfb"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/YIGZJ7JDA34HB7SQGPZN2WB7N2/bundle.json","state_url":"https://pith.science/pith/YIGZJ7JDA34HB7SQGPZN2WB7N2/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/YIGZJ7JDA34HB7SQGPZN2WB7N2/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-22T11:11:22Z","links":{"resolver":"https://pith.science/pith/YIGZJ7JDA34HB7SQGPZN2WB7N2","bundle":"https://pith.science/pith/YIGZJ7JDA34HB7SQGPZN2WB7N2/bundle.json","state":"https://pith.science/pith/YIGZJ7JDA34HB7SQGPZN2WB7N2/state.json","well_known_bundle":"https://pith.science/.well-known/pith/YIGZJ7JDA34HB7SQGPZN2WB7N2/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2018:YIGZJ7JDA34HB7SQGPZN2WB7N2","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"e1743a0b036089d216ba938114a05750f710cedc9971469a3c21fe9cbe3b27bb","cross_cats_sorted":["physics.chem-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.ao-ph","submitted_at":"2018-02-27T09:07:55Z","title_canon_sha256":"5e77855afbc158588c18e073a29da62ec7631a8fd4685beb122a267b280c6542"},"schema_version":"1.0","source":{"id":"1802.09782","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1802.09782","created_at":"2026-05-18T00:18:00Z"},{"alias_kind":"arxiv_version","alias_value":"1802.09782v1","created_at":"2026-05-18T00:18:00Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1802.09782","created_at":"2026-05-18T00:18:00Z"},{"alias_kind":"pith_short_12","alias_value":"YIGZJ7JDA34H","created_at":"2026-05-18T12:33:04Z"},{"alias_kind":"pith_short_16","alias_value":"YIGZJ7JDA34HB7SQ","created_at":"2026-05-18T12:33:04Z"},{"alias_kind":"pith_short_8","alias_value":"YIGZJ7JD","created_at":"2026-05-18T12:33:04Z"}],"graph_snapshots":[{"event_id":"sha256:6fd07be24698de32305ad5c27e86e6f533059451a26a54c836a40aa9f2ebfcfb","target":"graph","created_at":"2026-05-18T00:18:00Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"Monitoring ozone concentrations in the Earth's atmosphere using spectroscopic methods is a major activity which undertaken both from the ground and from space. However there are long-running issues of consistency between measurements made at infrared (IR) and ultraviolet (UV) wavelengths. In addition, key O$_3$ IR bands at 10 \\muu, 5 \\muu\\ and 3 \\muu\\ also yield results which differ by a few percent when used for retrievals. These problems stem from the underlying laboratory measurements of the line intensities. Here we use quantum chemical techniques, first principles electronic structure and","authors_text":"Aleksandra A. Kyuberis, Irina I. Mizus, Jonathan Tennyson, Lorenzo Lodi, Nikolai F. Zobov, Oleg L. Polyansky","cross_cats":["physics.chem-ph"],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.ao-ph","submitted_at":"2018-02-27T09:07:55Z","title":"Potential energy surface, dipole moment surface and the intensity calculations for the 10 micron, 5 micron, and 3 micron bands of ozone"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1802.09782","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:6f8b5f1fe9e176a983651fef8a660aa423856742a4101d4d1e4a628f041652f4","target":"record","created_at":"2026-05-18T00:18:00Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"e1743a0b036089d216ba938114a05750f710cedc9971469a3c21fe9cbe3b27bb","cross_cats_sorted":["physics.chem-ph"],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.ao-ph","submitted_at":"2018-02-27T09:07:55Z","title_canon_sha256":"5e77855afbc158588c18e073a29da62ec7631a8fd4685beb122a267b280c6542"},"schema_version":"1.0","source":{"id":"1802.09782","kind":"arxiv","version":1}},"canonical_sha256":"c20d94fd2306f870fe5033f2dd583f6e80977966270257b251214b95d4ba29b9","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"c20d94fd2306f870fe5033f2dd583f6e80977966270257b251214b95d4ba29b9","first_computed_at":"2026-05-18T00:18:00.738217Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T00:18:00.738217Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"w1BcSHmbHgL36Gj7gnBvM1H6CUVA2+CAnegzH7CvmccTBOxLhErZvlSbMABQ7hURO4PUBd3q5+ZROqh5Fig2Bg==","signature_status":"signed_v1","signed_at":"2026-05-18T00:18:00.738993Z","signed_message":"canonical_sha256_bytes"},"source_id":"1802.09782","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:6f8b5f1fe9e176a983651fef8a660aa423856742a4101d4d1e4a628f041652f4","sha256:6fd07be24698de32305ad5c27e86e6f533059451a26a54c836a40aa9f2ebfcfb"],"state_sha256":"05bcf6887de442f4303fe2644ecbaa882d41faaefdb941605d6a27957bf61bc3"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"Fd16F9lUsUu9VrreBmtQvDnmNSu5VHf7jAgRFR6HjYwLTWLNIEqoC4tm6O3GAeP87AoFFdJ1uwcedH9PwRzGAA==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-22T11:11:22.945391Z","bundle_sha256":"1ed66bcf9f938901e83b28981c6aed23fc67c08b61b8861dd54a346541ace4dd"}}