{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2023:YJT22M5TA3D4S7XDUQCZOXTV3E","short_pith_number":"pith:YJT22M5T","canonical_record":{"source":{"id":"2302.03880","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2023-02-08T04:57:55Z","cross_cats_sorted":[],"title_canon_sha256":"8611a85eb99cf374e9dc2a29765b7a9ce6b426431291a65ab22975c9cb747a2f","abstract_canon_sha256":"068704112723ba2a02b03393346ce7c82204940cdbb9468e23728cdb4f43be7b"},"schema_version":"1.0"},"canonical_sha256":"c267ad33b306c7c97ee3a405975e75d91287e4de1ae7404ed57772e456bb137c","source":{"kind":"arxiv","id":"2302.03880","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2302.03880","created_at":"2026-07-05T05:39:58Z"},{"alias_kind":"arxiv_version","alias_value":"2302.03880v1","created_at":"2026-07-05T05:39:58Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2302.03880","created_at":"2026-07-05T05:39:58Z"},{"alias_kind":"pith_short_12","alias_value":"YJT22M5TA3D4","created_at":"2026-07-05T05:39:58Z"},{"alias_kind":"pith_short_16","alias_value":"YJT22M5TA3D4S7XD","created_at":"2026-07-05T05:39:58Z"},{"alias_kind":"pith_short_8","alias_value":"YJT22M5T","created_at":"2026-07-05T05:39:58Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2023:YJT22M5TA3D4S7XDUQCZOXTV3E","target":"record","payload":{"canonical_record":{"source":{"id":"2302.03880","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2023-02-08T04:57:55Z","cross_cats_sorted":[],"title_canon_sha256":"8611a85eb99cf374e9dc2a29765b7a9ce6b426431291a65ab22975c9cb747a2f","abstract_canon_sha256":"068704112723ba2a02b03393346ce7c82204940cdbb9468e23728cdb4f43be7b"},"schema_version":"1.0"},"canonical_sha256":"c267ad33b306c7c97ee3a405975e75d91287e4de1ae7404ed57772e456bb137c","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T05:39:58.766593Z","signature_b64":"lfwuWr4tnhGvXbpNKt0Uu6GLuN9bljAm/haHL7Du6uTgrsEYSd6anLk5KC7VqesPx8q0QYYPboaKP0O+OuWbCQ==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"c267ad33b306c7c97ee3a405975e75d91287e4de1ae7404ed57772e456bb137c","last_reissued_at":"2026-07-05T05:39:58.766173Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T05:39:58.766173Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"2302.03880","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T05:39:58Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"3FCVHGICXXxUHHPtCshLRzx69xn2laiTUPIRrylbzKeQp1IcPIIl2ghArOdKiz6GOfOOQO2yMOMZFlAF0IkXAA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-15T22:15:10.840501Z"},"content_sha256":"11990a6a562021537cef0857598e3fdfd420e97c222ad982e668e708d08cfb10","schema_version":"1.0","event_id":"sha256:11990a6a562021537cef0857598e3fdfd420e97c222ad982e668e708d08cfb10"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2023:YJT22M5TA3D4S7XDUQCZOXTV3E","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Thermodynamic coupling of reactions via few-molecule vibrational polaritons","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"Arghadip Koner, Joel Yuen-Zhou, Matthew Du, Randall H. Goldsmith, Sindhana Pannir-Sivajothi","submitted_at":"2023-02-08T04:57:55Z","abstract_excerpt":"Interaction between light and molecular vibrations leads to hybrid light-matter states called vibrational polaritons. Even though many intriguing phenomena have been predicted for single-molecule vibrational strong coupling (VSC), several studies suggest that these effects tend to be diminished in the many-molecule regime due to the presence of dark states. Achieving single or few-molecule vibrational polaritons has been constrained by the need for fabricating extremely small mode volume infrared cavities. In this work, we propose an alternative strategy to achieve single-molecule VSC in a cav"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2302.03880","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2302.03880/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T05:39:58Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"aQQHde2udlLCbZx/xcc2wrqsgjLaOfpQAI56rpADaAcOKc2jaBpYk0I6otKVpyMePuPkK51lfXjaLUtn9GMSDg==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-15T22:15:10.841445Z"},"content_sha256":"b0135d2e70002434ecc3b0b3229db0d07c3ce4c84c505ecac30e5a23ea337332","schema_version":"1.0","event_id":"sha256:b0135d2e70002434ecc3b0b3229db0d07c3ce4c84c505ecac30e5a23ea337332"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/YJT22M5TA3D4S7XDUQCZOXTV3E/bundle.json","state_url":"https://pith.science/pith/YJT22M5TA3D4S7XDUQCZOXTV3E/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/YJT22M5TA3D4S7XDUQCZOXTV3E/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-08-15T22:15:10Z","links":{"resolver":"https://pith.science/pith/YJT22M5TA3D4S7XDUQCZOXTV3E","bundle":"https://pith.science/pith/YJT22M5TA3D4S7XDUQCZOXTV3E/bundle.json","state":"https://pith.science/pith/YJT22M5TA3D4S7XDUQCZOXTV3E/state.json","well_known_bundle":"https://pith.science/.well-known/pith/YJT22M5TA3D4S7XDUQCZOXTV3E/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2023:YJT22M5TA3D4S7XDUQCZOXTV3E","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"068704112723ba2a02b03393346ce7c82204940cdbb9468e23728cdb4f43be7b","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2023-02-08T04:57:55Z","title_canon_sha256":"8611a85eb99cf374e9dc2a29765b7a9ce6b426431291a65ab22975c9cb747a2f"},"schema_version":"1.0","source":{"id":"2302.03880","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2302.03880","created_at":"2026-07-05T05:39:58Z"},{"alias_kind":"arxiv_version","alias_value":"2302.03880v1","created_at":"2026-07-05T05:39:58Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2302.03880","created_at":"2026-07-05T05:39:58Z"},{"alias_kind":"pith_short_12","alias_value":"YJT22M5TA3D4","created_at":"2026-07-05T05:39:58Z"},{"alias_kind":"pith_short_16","alias_value":"YJT22M5TA3D4S7XD","created_at":"2026-07-05T05:39:58Z"},{"alias_kind":"pith_short_8","alias_value":"YJT22M5T","created_at":"2026-07-05T05:39:58Z"}],"graph_snapshots":[{"event_id":"sha256:b0135d2e70002434ecc3b0b3229db0d07c3ce4c84c505ecac30e5a23ea337332","target":"graph","created_at":"2026-07-05T05:39:58Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2302.03880/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"Interaction between light and molecular vibrations leads to hybrid light-matter states called vibrational polaritons. Even though many intriguing phenomena have been predicted for single-molecule vibrational strong coupling (VSC), several studies suggest that these effects tend to be diminished in the many-molecule regime due to the presence of dark states. Achieving single or few-molecule vibrational polaritons has been constrained by the need for fabricating extremely small mode volume infrared cavities. In this work, we propose an alternative strategy to achieve single-molecule VSC in a cav","authors_text":"Arghadip Koner, Joel Yuen-Zhou, Matthew Du, Randall H. Goldsmith, Sindhana Pannir-Sivajothi","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2023-02-08T04:57:55Z","title":"Thermodynamic coupling of reactions via few-molecule vibrational polaritons"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2302.03880","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:11990a6a562021537cef0857598e3fdfd420e97c222ad982e668e708d08cfb10","target":"record","created_at":"2026-07-05T05:39:58Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"068704112723ba2a02b03393346ce7c82204940cdbb9468e23728cdb4f43be7b","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2023-02-08T04:57:55Z","title_canon_sha256":"8611a85eb99cf374e9dc2a29765b7a9ce6b426431291a65ab22975c9cb747a2f"},"schema_version":"1.0","source":{"id":"2302.03880","kind":"arxiv","version":1}},"canonical_sha256":"c267ad33b306c7c97ee3a405975e75d91287e4de1ae7404ed57772e456bb137c","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"c267ad33b306c7c97ee3a405975e75d91287e4de1ae7404ed57772e456bb137c","first_computed_at":"2026-07-05T05:39:58.766173Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-05T05:39:58.766173Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"lfwuWr4tnhGvXbpNKt0Uu6GLuN9bljAm/haHL7Du6uTgrsEYSd6anLk5KC7VqesPx8q0QYYPboaKP0O+OuWbCQ==","signature_status":"signed_v1","signed_at":"2026-07-05T05:39:58.766593Z","signed_message":"canonical_sha256_bytes"},"source_id":"2302.03880","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:11990a6a562021537cef0857598e3fdfd420e97c222ad982e668e708d08cfb10","sha256:b0135d2e70002434ecc3b0b3229db0d07c3ce4c84c505ecac30e5a23ea337332"],"state_sha256":"8b7ee495b4fcb654151a5e4fbced07b74c783fde71043adb1cbd5de519081bfe"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"1JVRxxVUGVyWsNpRi3W2hb2ps3zRdsc4xaVxKDrAeFLZ5b9xQuAIfN5ScEXp2LPTMTG+T/uWHmsTFwbJcaeRDQ==","signed_message":"bundle_sha256_bytes","signed_at":"2026-08-15T22:15:10.897794Z","bundle_sha256":"bcc41e6537b38f5580e7a5fe4fa4f336be9697f4a755e0d3374129589201b10f"}}