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Theoretical results showed the possibility that neutron capture elements were produced in the early Universe by two different sources: a frequent s-process source hosted by rotating massive stars, and a rare r-process source hosted most likely by neutron star mergers. The two sources produce barium with different isotopic compositions. Aims. We aim to investigate the lines of barium in two halo stars, HD 6268 and HD 4306. The spectra present an exquisite quality, both in terms of resolution (R > 100'000) and signal-to-noise (400). 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