{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2017:Z6KHJ2SLTOPSPU5QVWAAFFW3NZ","short_pith_number":"pith:Z6KHJ2SL","canonical_record":{"source":{"id":"1709.03958","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2017-09-12T17:17:03Z","cross_cats_sorted":[],"title_canon_sha256":"4d40d7f2396b2c8b8214149cd49b842462f2e8829c13c0f9fe6fa1aed840de94","abstract_canon_sha256":"e3b2a7d6941368a8b6005a5482f83b983c21c47ec379e05f1a4d3ec5715b5c5b"},"schema_version":"1.0"},"canonical_sha256":"cf9474ea4b9b9f27d3b0ad800296db6e6a9c91b12bc4c7a6446b85be4a46e710","source":{"kind":"arxiv","id":"1709.03958","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1709.03958","created_at":"2026-05-18T00:30:57Z"},{"alias_kind":"arxiv_version","alias_value":"1709.03958v1","created_at":"2026-05-18T00:30:57Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1709.03958","created_at":"2026-05-18T00:30:57Z"},{"alias_kind":"pith_short_12","alias_value":"Z6KHJ2SLTOPS","created_at":"2026-05-18T12:31:59Z"},{"alias_kind":"pith_short_16","alias_value":"Z6KHJ2SLTOPSPU5Q","created_at":"2026-05-18T12:31:59Z"},{"alias_kind":"pith_short_8","alias_value":"Z6KHJ2SL","created_at":"2026-05-18T12:31:59Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2017:Z6KHJ2SLTOPSPU5QVWAAFFW3NZ","target":"record","payload":{"canonical_record":{"source":{"id":"1709.03958","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2017-09-12T17:17:03Z","cross_cats_sorted":[],"title_canon_sha256":"4d40d7f2396b2c8b8214149cd49b842462f2e8829c13c0f9fe6fa1aed840de94","abstract_canon_sha256":"e3b2a7d6941368a8b6005a5482f83b983c21c47ec379e05f1a4d3ec5715b5c5b"},"schema_version":"1.0"},"canonical_sha256":"cf9474ea4b9b9f27d3b0ad800296db6e6a9c91b12bc4c7a6446b85be4a46e710","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T00:30:57.391078Z","signature_b64":"ABNDONJgxb9Ipw1q3BBgv8Ci0p8S2dFK53PIUKX4x2GJpiT8OhLDtfHPtbIoG0zsCtHgbCHGyGH43l22xu+VCA==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"cf9474ea4b9b9f27d3b0ad800296db6e6a9c91b12bc4c7a6446b85be4a46e710","last_reissued_at":"2026-05-18T00:30:57.390597Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T00:30:57.390597Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"1709.03958","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:30:57Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"1ojTEc+HUQVNdkYYkLeyVZOkZEPZyUEGPUCxCrsCSLfvIki1jKzhDbn9YcCmOu5tUbtfgCAqNyZ3qKxIxJQwDQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-27T05:36:32.247231Z"},"content_sha256":"b913bd5eba4bae8657772436a27bc3c2ccc0e0d9fb2d7dc068d359c9ebecae9f","schema_version":"1.0","event_id":"sha256:b913bd5eba4bae8657772436a27bc3c2ccc0e0d9fb2d7dc068d359c9ebecae9f"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2017:Z6KHJ2SLTOPSPU5QVWAAFFW3NZ","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Full-dimensional treatment of short-time vibronic dynamics in molecular high-harmonics generation process in methane","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"physics.chem-ph","authors_text":"Michael S. Schuurman, Serguei Patchkovskii","submitted_at":"2017-09-12T17:17:03Z","abstract_excerpt":"We present derivation and implementation of the Multi-Configurational Strong-Field Approximation with Gaussian nuclear Wave Packets (MC-SFA-GWP) -- a version of the molecular strong-field approximation which treats all electronic and nuclear degrees of freedom, including their correlations, quantum-mechanically. The technique allows, for the first time, realistic simulation of high-harmonic emission in polyatomic molecules without invoking reduced-dimensionality models for the nuclear motion or the electronic structure. We use MC-SFA-GWP to model isotope effects in high-harmonics generation (H"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1709.03958","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T00:30:57Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"0VIQ3inOsm2mHzs5DwAa7sa4FCbRuyhGC5xTZ0CnPGBTt9zZpCyuTms0P+cEta6ohJJJL4r/VbgdNx+17Du6Bw==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-05-27T05:36:32.247608Z"},"content_sha256":"6ca5ed36e3e6baacb9a860dcb58c0f125dfb1336bf237422a79fd3c430ec3f08","schema_version":"1.0","event_id":"sha256:6ca5ed36e3e6baacb9a860dcb58c0f125dfb1336bf237422a79fd3c430ec3f08"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/Z6KHJ2SLTOPSPU5QVWAAFFW3NZ/bundle.json","state_url":"https://pith.science/pith/Z6KHJ2SLTOPSPU5QVWAAFFW3NZ/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/Z6KHJ2SLTOPSPU5QVWAAFFW3NZ/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-05-27T05:36:32Z","links":{"resolver":"https://pith.science/pith/Z6KHJ2SLTOPSPU5QVWAAFFW3NZ","bundle":"https://pith.science/pith/Z6KHJ2SLTOPSPU5QVWAAFFW3NZ/bundle.json","state":"https://pith.science/pith/Z6KHJ2SLTOPSPU5QVWAAFFW3NZ/state.json","well_known_bundle":"https://pith.science/.well-known/pith/Z6KHJ2SLTOPSPU5QVWAAFFW3NZ/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2017:Z6KHJ2SLTOPSPU5QVWAAFFW3NZ","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"e3b2a7d6941368a8b6005a5482f83b983c21c47ec379e05f1a4d3ec5715b5c5b","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2017-09-12T17:17:03Z","title_canon_sha256":"4d40d7f2396b2c8b8214149cd49b842462f2e8829c13c0f9fe6fa1aed840de94"},"schema_version":"1.0","source":{"id":"1709.03958","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"1709.03958","created_at":"2026-05-18T00:30:57Z"},{"alias_kind":"arxiv_version","alias_value":"1709.03958v1","created_at":"2026-05-18T00:30:57Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.1709.03958","created_at":"2026-05-18T00:30:57Z"},{"alias_kind":"pith_short_12","alias_value":"Z6KHJ2SLTOPS","created_at":"2026-05-18T12:31:59Z"},{"alias_kind":"pith_short_16","alias_value":"Z6KHJ2SLTOPSPU5Q","created_at":"2026-05-18T12:31:59Z"},{"alias_kind":"pith_short_8","alias_value":"Z6KHJ2SL","created_at":"2026-05-18T12:31:59Z"}],"graph_snapshots":[{"event_id":"sha256:6ca5ed36e3e6baacb9a860dcb58c0f125dfb1336bf237422a79fd3c430ec3f08","target":"graph","created_at":"2026-05-18T00:30:57Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"We present derivation and implementation of the Multi-Configurational Strong-Field Approximation with Gaussian nuclear Wave Packets (MC-SFA-GWP) -- a version of the molecular strong-field approximation which treats all electronic and nuclear degrees of freedom, including their correlations, quantum-mechanically. The technique allows, for the first time, realistic simulation of high-harmonic emission in polyatomic molecules without invoking reduced-dimensionality models for the nuclear motion or the electronic structure. We use MC-SFA-GWP to model isotope effects in high-harmonics generation (H","authors_text":"Michael S. Schuurman, Serguei Patchkovskii","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2017-09-12T17:17:03Z","title":"Full-dimensional treatment of short-time vibronic dynamics in molecular high-harmonics generation process in methane"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"1709.03958","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:b913bd5eba4bae8657772436a27bc3c2ccc0e0d9fb2d7dc068d359c9ebecae9f","target":"record","created_at":"2026-05-18T00:30:57Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"e3b2a7d6941368a8b6005a5482f83b983c21c47ec379e05f1a4d3ec5715b5c5b","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"physics.chem-ph","submitted_at":"2017-09-12T17:17:03Z","title_canon_sha256":"4d40d7f2396b2c8b8214149cd49b842462f2e8829c13c0f9fe6fa1aed840de94"},"schema_version":"1.0","source":{"id":"1709.03958","kind":"arxiv","version":1}},"canonical_sha256":"cf9474ea4b9b9f27d3b0ad800296db6e6a9c91b12bc4c7a6446b85be4a46e710","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"cf9474ea4b9b9f27d3b0ad800296db6e6a9c91b12bc4c7a6446b85be4a46e710","first_computed_at":"2026-05-18T00:30:57.390597Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T00:30:57.390597Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"ABNDONJgxb9Ipw1q3BBgv8Ci0p8S2dFK53PIUKX4x2GJpiT8OhLDtfHPtbIoG0zsCtHgbCHGyGH43l22xu+VCA==","signature_status":"signed_v1","signed_at":"2026-05-18T00:30:57.391078Z","signed_message":"canonical_sha256_bytes"},"source_id":"1709.03958","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:b913bd5eba4bae8657772436a27bc3c2ccc0e0d9fb2d7dc068d359c9ebecae9f","sha256:6ca5ed36e3e6baacb9a860dcb58c0f125dfb1336bf237422a79fd3c430ec3f08"],"state_sha256":"aa3dbe762ddfa2a16c48ffcd3225a7a2b7cc82e958068e9af0d3dea3615bdfea"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"0j0bm9BomF77gyuH+LegV0L9QQjPu0aZD8QZ/9delvRh1nzQVADM4lruBTL9V0QJMbp0bN6m4ZC/61ZLP+8tCQ==","signed_message":"bundle_sha256_bytes","signed_at":"2026-05-27T05:36:32.252388Z","bundle_sha256":"a6d416bb0e08f98dd108f050e158aea84b5fc53c727e795d7d512d1bd8fe2687"}}