{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2008:ZC4LP2EAEM33BFM6GUKJIXF5JF","short_pith_number":"pith:ZC4LP2EA","canonical_record":{"source":{"id":"0812.0309","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mes-hall","submitted_at":"2008-12-01T14:53:47Z","cross_cats_sorted":[],"title_canon_sha256":"bd066a72cedef17f925327be2764582e02e70b4a78a94dbb9dfa8d2dd8cd7985","abstract_canon_sha256":"f9955431bcd15de5ac7cc697f2a26603579e31667cbfe6539492f009fab748a9"},"schema_version":"1.0"},"canonical_sha256":"c8b8b7e8802337b0959e3514945cbd49431dbe1ca28fae745963c2fbb5f81361","source":{"kind":"arxiv","id":"0812.0309","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"0812.0309","created_at":"2026-05-18T04:26:55Z"},{"alias_kind":"arxiv_version","alias_value":"0812.0309v1","created_at":"2026-05-18T04:26:55Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.0812.0309","created_at":"2026-05-18T04:26:55Z"},{"alias_kind":"pith_short_12","alias_value":"ZC4LP2EAEM33","created_at":"2026-05-18T12:25:58Z"},{"alias_kind":"pith_short_16","alias_value":"ZC4LP2EAEM33BFM6","created_at":"2026-05-18T12:25:58Z"},{"alias_kind":"pith_short_8","alias_value":"ZC4LP2EA","created_at":"2026-05-18T12:25:58Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2008:ZC4LP2EAEM33BFM6GUKJIXF5JF","target":"record","payload":{"canonical_record":{"source":{"id":"0812.0309","kind":"arxiv","version":1},"metadata":{"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mes-hall","submitted_at":"2008-12-01T14:53:47Z","cross_cats_sorted":[],"title_canon_sha256":"bd066a72cedef17f925327be2764582e02e70b4a78a94dbb9dfa8d2dd8cd7985","abstract_canon_sha256":"f9955431bcd15de5ac7cc697f2a26603579e31667cbfe6539492f009fab748a9"},"schema_version":"1.0"},"canonical_sha256":"c8b8b7e8802337b0959e3514945cbd49431dbe1ca28fae745963c2fbb5f81361","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-05-18T04:26:55.685743Z","signature_b64":"TwzK3LYSDrc5mi4kRq2lAKL4W5/dcIZD29csWiiHgm5OgZCV5Xn+cbABds2TM7CpdkT7GalPxP8JCL6gL1/SDA==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"c8b8b7e8802337b0959e3514945cbd49431dbe1ca28fae745963c2fbb5f81361","last_reissued_at":"2026-05-18T04:26:55.685351Z","signature_status":"signed_v1","first_computed_at":"2026-05-18T04:26:55.685351Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"0812.0309","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T04:26:55Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"7OFO4LwLCng81Y0rLAKB5egpThl4P0xzczAcDa5kYRY+R0MrQMwSW1bX3kgvXDeRso9dawGCjk5VB/U7wYuLCQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-07T02:50:35.823157Z"},"content_sha256":"207ca0b755b8f9b238f87f775715275f9701a7a85284e013b8a0b0809da57933","schema_version":"1.0","event_id":"sha256:207ca0b755b8f9b238f87f775715275f9701a7a85284e013b8a0b0809da57933"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2008:ZC4LP2EAEM33BFM6GUKJIXF5JF","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Vibrational nonequilibrium effects in the conductance of single-molecules with multiple electronic states","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","headline":"","cross_cats":[],"primary_cat":"cond-mat.mes-hall","authors_text":"C. Benesch, M. Thoss, R. H\\\"artle","submitted_at":"2008-12-01T14:53:47Z","abstract_excerpt":"Vibrational nonequilibrium effects in charge transport through single-molecule junctions are investigated. Focusing on molecular bridges with multiple electronic states, it is shown that electronic-vibrational coupling triggers a variety of vibronic emission and absorption processes, which influence the conductance properties and mechanical stability of single-molecule junctions profoundly. Employing a master equation and a nonequilibrium Green's function approach, these processes are analyzed in detail for a generic model of a molecular junction and for benzenedibutanethiolate bound to gold e"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"0812.0309","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-05-18T04:26:55Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"BenkTg1U3z6CFo7tWQjHe/csZGBHJVFgyYTIOqfi3ssx7Y8k6uYEtIFU4QE7gNG+C/IMJ1Sv/e0ubDtwsrIrAQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-06-07T02:50:35.823539Z"},"content_sha256":"883ffc616ae4fdd48c1cabe1c3458944dc001cbcaf8357c904c6526b6ef97d77","schema_version":"1.0","event_id":"sha256:883ffc616ae4fdd48c1cabe1c3458944dc001cbcaf8357c904c6526b6ef97d77"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/ZC4LP2EAEM33BFM6GUKJIXF5JF/bundle.json","state_url":"https://pith.science/pith/ZC4LP2EAEM33BFM6GUKJIXF5JF/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/ZC4LP2EAEM33BFM6GUKJIXF5JF/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-06-07T02:50:35Z","links":{"resolver":"https://pith.science/pith/ZC4LP2EAEM33BFM6GUKJIXF5JF","bundle":"https://pith.science/pith/ZC4LP2EAEM33BFM6GUKJIXF5JF/bundle.json","state":"https://pith.science/pith/ZC4LP2EAEM33BFM6GUKJIXF5JF/state.json","well_known_bundle":"https://pith.science/.well-known/pith/ZC4LP2EAEM33BFM6GUKJIXF5JF/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2008:ZC4LP2EAEM33BFM6GUKJIXF5JF","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"f9955431bcd15de5ac7cc697f2a26603579e31667cbfe6539492f009fab748a9","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mes-hall","submitted_at":"2008-12-01T14:53:47Z","title_canon_sha256":"bd066a72cedef17f925327be2764582e02e70b4a78a94dbb9dfa8d2dd8cd7985"},"schema_version":"1.0","source":{"id":"0812.0309","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"0812.0309","created_at":"2026-05-18T04:26:55Z"},{"alias_kind":"arxiv_version","alias_value":"0812.0309v1","created_at":"2026-05-18T04:26:55Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.0812.0309","created_at":"2026-05-18T04:26:55Z"},{"alias_kind":"pith_short_12","alias_value":"ZC4LP2EAEM33","created_at":"2026-05-18T12:25:58Z"},{"alias_kind":"pith_short_16","alias_value":"ZC4LP2EAEM33BFM6","created_at":"2026-05-18T12:25:58Z"},{"alias_kind":"pith_short_8","alias_value":"ZC4LP2EA","created_at":"2026-05-18T12:25:58Z"}],"graph_snapshots":[{"event_id":"sha256:883ffc616ae4fdd48c1cabe1c3458944dc001cbcaf8357c904c6526b6ef97d77","target":"graph","created_at":"2026-05-18T04:26:55Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"paper":{"abstract_excerpt":"Vibrational nonequilibrium effects in charge transport through single-molecule junctions are investigated. Focusing on molecular bridges with multiple electronic states, it is shown that electronic-vibrational coupling triggers a variety of vibronic emission and absorption processes, which influence the conductance properties and mechanical stability of single-molecule junctions profoundly. Employing a master equation and a nonequilibrium Green's function approach, these processes are analyzed in detail for a generic model of a molecular junction and for benzenedibutanethiolate bound to gold e","authors_text":"C. Benesch, M. Thoss, R. H\\\"artle","cross_cats":[],"headline":"","license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mes-hall","submitted_at":"2008-12-01T14:53:47Z","title":"Vibrational nonequilibrium effects in the conductance of single-molecules with multiple electronic states"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"0812.0309","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:207ca0b755b8f9b238f87f775715275f9701a7a85284e013b8a0b0809da57933","target":"record","created_at":"2026-05-18T04:26:55Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"f9955431bcd15de5ac7cc697f2a26603579e31667cbfe6539492f009fab748a9","cross_cats_sorted":[],"license":"http://arxiv.org/licenses/nonexclusive-distrib/1.0/","primary_cat":"cond-mat.mes-hall","submitted_at":"2008-12-01T14:53:47Z","title_canon_sha256":"bd066a72cedef17f925327be2764582e02e70b4a78a94dbb9dfa8d2dd8cd7985"},"schema_version":"1.0","source":{"id":"0812.0309","kind":"arxiv","version":1}},"canonical_sha256":"c8b8b7e8802337b0959e3514945cbd49431dbe1ca28fae745963c2fbb5f81361","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"c8b8b7e8802337b0959e3514945cbd49431dbe1ca28fae745963c2fbb5f81361","first_computed_at":"2026-05-18T04:26:55.685351Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-05-18T04:26:55.685351Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"TwzK3LYSDrc5mi4kRq2lAKL4W5/dcIZD29csWiiHgm5OgZCV5Xn+cbABds2TM7CpdkT7GalPxP8JCL6gL1/SDA==","signature_status":"signed_v1","signed_at":"2026-05-18T04:26:55.685743Z","signed_message":"canonical_sha256_bytes"},"source_id":"0812.0309","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:207ca0b755b8f9b238f87f775715275f9701a7a85284e013b8a0b0809da57933","sha256:883ffc616ae4fdd48c1cabe1c3458944dc001cbcaf8357c904c6526b6ef97d77"],"state_sha256":"74bacc5aa37b7913d5febd92b421682c16cb0c269e5a4110d85182f4b6c9a9d1"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"xOivHTBJx2jms+E8OViDPgR5W1Ulsab3B/moMWZjYfzuHinDBCbh5ZUuA6N2ImAtM/4p4xOkHfsHmuwMH2AUDg==","signed_message":"bundle_sha256_bytes","signed_at":"2026-06-07T02:50:35.825597Z","bundle_sha256":"d0e9383c9d6db8df9ff7a537743b2b5d1089b900161f38cce5f38d5c63a393c0"}}