{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2021:ZKKRMJJUL7VUIKAHTZXCBPA6IG","short_pith_number":"pith:ZKKRMJJU","canonical_record":{"source":{"id":"2102.04637","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"physics.chem-ph","submitted_at":"2021-02-09T04:09:59Z","cross_cats_sorted":["cond-mat.mes-hall"],"title_canon_sha256":"2e774265d8932418b12350952b0fcdaf5f9829edc35d7dd932e333f18cac53b1","abstract_canon_sha256":"90f308923e2427ef052325c884d390fe412d0f6106ac40fe5f94fa379c9ea836"},"schema_version":"1.0"},"canonical_sha256":"ca951625345feb4428079e6e20bc1e41b2292eaad8597de6901fda00c7b75fbb","source":{"kind":"arxiv","id":"2102.04637","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2102.04637","created_at":"2026-07-05T02:14:03Z"},{"alias_kind":"arxiv_version","alias_value":"2102.04637v1","created_at":"2026-07-05T02:14:03Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2102.04637","created_at":"2026-07-05T02:14:03Z"},{"alias_kind":"pith_short_12","alias_value":"ZKKRMJJUL7VU","created_at":"2026-07-05T02:14:03Z"},{"alias_kind":"pith_short_16","alias_value":"ZKKRMJJUL7VUIKAH","created_at":"2026-07-05T02:14:03Z"},{"alias_kind":"pith_short_8","alias_value":"ZKKRMJJU","created_at":"2026-07-05T02:14:03Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2021:ZKKRMJJUL7VUIKAHTZXCBPA6IG","target":"record","payload":{"canonical_record":{"source":{"id":"2102.04637","kind":"arxiv","version":1},"metadata":{"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"physics.chem-ph","submitted_at":"2021-02-09T04:09:59Z","cross_cats_sorted":["cond-mat.mes-hall"],"title_canon_sha256":"2e774265d8932418b12350952b0fcdaf5f9829edc35d7dd932e333f18cac53b1","abstract_canon_sha256":"90f308923e2427ef052325c884d390fe412d0f6106ac40fe5f94fa379c9ea836"},"schema_version":"1.0"},"canonical_sha256":"ca951625345feb4428079e6e20bc1e41b2292eaad8597de6901fda00c7b75fbb","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-05T02:14:03.140642Z","signature_b64":"Nop3NAQeRqVcwiPQowf7ammZAb9D8Uelt8wnepe63+HPngEuMXoTjVEn52bSwIwg4rnSbBKFtmctRj5RYSPWDg==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"ca951625345feb4428079e6e20bc1e41b2292eaad8597de6901fda00c7b75fbb","last_reissued_at":"2026-07-05T02:14:03.140214Z","signature_status":"signed_v1","first_computed_at":"2026-07-05T02:14:03.140214Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"2102.04637","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T02:14:03Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"23vLFyugCYVF6CAnzosPQ2du0iIddhOA57a/ZUG3zKbMNWatksdgXyA+1+DCHb7NgsUMJcRRY1ikpj7ZnnWPAQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-12T15:06:35.998566Z"},"content_sha256":"22447277139e4af208cbcdb4aa72079fe4dbb67731fd2015e15a593134c5f0a8","schema_version":"1.0","event_id":"sha256:22447277139e4af208cbcdb4aa72079fe4dbb67731fd2015e15a593134c5f0a8"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2021:ZKKRMJJUL7VUIKAHTZXCBPA6IG","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"On the theory of charge transport and entropic effects in solvated molecular junctions","license":"http://creativecommons.org/licenses/by/4.0/","headline":"","cross_cats":["cond-mat.mes-hall"],"primary_cat":"physics.chem-ph","authors_text":"Jakub K. Sowa, Rudolph A. Marcus","submitted_at":"2021-02-09T04:09:59Z","abstract_excerpt":"Experimental studies on single-molecule junctions are typically in need of a simple theoretical approach that can reproduce or be fitted to experimentally measured transport data. In this context, the single-level variant of the Landauer approach is most commonly used but methods based on Marcus theory are also gaining in popularity. Recently, a generalized theory unifying these two approaches has also been developed. In the present work, we extend this theory so that it includes entropic effects (which can be important when polar solvents are involved, but are likely minor for solid-state sys"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2102.04637","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/2102.04637/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-05T02:14:03Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"IjafqQ/In3KKa1/SZdLuiL7jjcz2gq+0KML4UTH001YKIh1flm2EmyZqoYb8nQIx4kSYL6yRsNbPDhRnULGGDA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-12T15:06:35.999129Z"},"content_sha256":"55f36784d4ced376ab16abf970c7c4404f86e2f28250c96c07e0c90392404dda","schema_version":"1.0","event_id":"sha256:55f36784d4ced376ab16abf970c7c4404f86e2f28250c96c07e0c90392404dda"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/ZKKRMJJUL7VUIKAHTZXCBPA6IG/bundle.json","state_url":"https://pith.science/pith/ZKKRMJJUL7VUIKAHTZXCBPA6IG/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/ZKKRMJJUL7VUIKAHTZXCBPA6IG/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-08-12T15:06:36Z","links":{"resolver":"https://pith.science/pith/ZKKRMJJUL7VUIKAHTZXCBPA6IG","bundle":"https://pith.science/pith/ZKKRMJJUL7VUIKAHTZXCBPA6IG/bundle.json","state":"https://pith.science/pith/ZKKRMJJUL7VUIKAHTZXCBPA6IG/state.json","well_known_bundle":"https://pith.science/.well-known/pith/ZKKRMJJUL7VUIKAHTZXCBPA6IG/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2021:ZKKRMJJUL7VUIKAHTZXCBPA6IG","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"90f308923e2427ef052325c884d390fe412d0f6106ac40fe5f94fa379c9ea836","cross_cats_sorted":["cond-mat.mes-hall"],"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"physics.chem-ph","submitted_at":"2021-02-09T04:09:59Z","title_canon_sha256":"2e774265d8932418b12350952b0fcdaf5f9829edc35d7dd932e333f18cac53b1"},"schema_version":"1.0","source":{"id":"2102.04637","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"2102.04637","created_at":"2026-07-05T02:14:03Z"},{"alias_kind":"arxiv_version","alias_value":"2102.04637v1","created_at":"2026-07-05T02:14:03Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.2102.04637","created_at":"2026-07-05T02:14:03Z"},{"alias_kind":"pith_short_12","alias_value":"ZKKRMJJUL7VU","created_at":"2026-07-05T02:14:03Z"},{"alias_kind":"pith_short_16","alias_value":"ZKKRMJJUL7VUIKAH","created_at":"2026-07-05T02:14:03Z"},{"alias_kind":"pith_short_8","alias_value":"ZKKRMJJU","created_at":"2026-07-05T02:14:03Z"}],"graph_snapshots":[{"event_id":"sha256:55f36784d4ced376ab16abf970c7c4404f86e2f28250c96c07e0c90392404dda","target":"graph","created_at":"2026-07-05T02:14:03Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/2102.04637/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"Experimental studies on single-molecule junctions are typically in need of a simple theoretical approach that can reproduce or be fitted to experimentally measured transport data. In this context, the single-level variant of the Landauer approach is most commonly used but methods based on Marcus theory are also gaining in popularity. Recently, a generalized theory unifying these two approaches has also been developed. In the present work, we extend this theory so that it includes entropic effects (which can be important when polar solvents are involved, but are likely minor for solid-state sys","authors_text":"Jakub K. Sowa, Rudolph A. Marcus","cross_cats":["cond-mat.mes-hall"],"headline":"","license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"physics.chem-ph","submitted_at":"2021-02-09T04:09:59Z","title":"On the theory of charge transport and entropic effects in solvated molecular junctions"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"2102.04637","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:22447277139e4af208cbcdb4aa72079fe4dbb67731fd2015e15a593134c5f0a8","target":"record","created_at":"2026-07-05T02:14:03Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"90f308923e2427ef052325c884d390fe412d0f6106ac40fe5f94fa379c9ea836","cross_cats_sorted":["cond-mat.mes-hall"],"license":"http://creativecommons.org/licenses/by/4.0/","primary_cat":"physics.chem-ph","submitted_at":"2021-02-09T04:09:59Z","title_canon_sha256":"2e774265d8932418b12350952b0fcdaf5f9829edc35d7dd932e333f18cac53b1"},"schema_version":"1.0","source":{"id":"2102.04637","kind":"arxiv","version":1}},"canonical_sha256":"ca951625345feb4428079e6e20bc1e41b2292eaad8597de6901fda00c7b75fbb","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"ca951625345feb4428079e6e20bc1e41b2292eaad8597de6901fda00c7b75fbb","first_computed_at":"2026-07-05T02:14:03.140214Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-05T02:14:03.140214Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"Nop3NAQeRqVcwiPQowf7ammZAb9D8Uelt8wnepe63+HPngEuMXoTjVEn52bSwIwg4rnSbBKFtmctRj5RYSPWDg==","signature_status":"signed_v1","signed_at":"2026-07-05T02:14:03.140642Z","signed_message":"canonical_sha256_bytes"},"source_id":"2102.04637","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:22447277139e4af208cbcdb4aa72079fe4dbb67731fd2015e15a593134c5f0a8","sha256:55f36784d4ced376ab16abf970c7c4404f86e2f28250c96c07e0c90392404dda"],"state_sha256":"fb9704a42a835a38254db5ce1f4c649b4e6e18fa142bd6be94849cf794272b60"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"2hBviw7teV2dzvRa9Jl2uSocTMvbktA2pH71cX1n6Zm9+wJdGK90qEADxVE3PDUibRAFR3BoZiLZ+dxXVR0DCQ==","signed_message":"bundle_sha256_bytes","signed_at":"2026-08-12T15:06:36.004388Z","bundle_sha256":"801c71a94a494e71c1d6599bfbd7bec9ef0a22824bd092b3114637c626f4901c"}}