{"bundle_type":"pith_open_graph_bundle","bundle_version":"1.0","pith_number":"pith:2001:ZPRMK27ELNEPY66S73UPDZIOQB","short_pith_number":"pith:ZPRMK27E","canonical_record":{"source":{"id":"cond-mat/0109509","kind":"arxiv","version":1},"metadata":{"license":"","primary_cat":"cond-mat.str-el","submitted_at":"2001-09-27T04:47:49Z","cross_cats_sorted":[],"title_canon_sha256":"cf8244b0a81b47e35aedb40fb6109dc5e5baab0d97393b8f4866026b9cc7fead","abstract_canon_sha256":"b0d074431db51f0b0eb0c73cd0763f6d7cae3787760bdbe5d29c58a67f297433"},"schema_version":"1.0"},"canonical_sha256":"cbe2c56be45b48fc7bd2fee8f1e50e806b780f5c9dc89ab7372c7dd4fcb392b6","source":{"kind":"arxiv","id":"cond-mat/0109509","version":1},"source_aliases":[{"alias_kind":"arxiv","alias_value":"cond-mat/0109509","created_at":"2026-07-04T14:18:39Z"},{"alias_kind":"arxiv_version","alias_value":"cond-mat/0109509v1","created_at":"2026-07-04T14:18:39Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.cond-mat/0109509","created_at":"2026-07-04T14:18:39Z"},{"alias_kind":"pith_short_12","alias_value":"ZPRMK27ELNEP","created_at":"2026-07-04T14:18:39Z"},{"alias_kind":"pith_short_16","alias_value":"ZPRMK27ELNEPY66S","created_at":"2026-07-04T14:18:39Z"},{"alias_kind":"pith_short_8","alias_value":"ZPRMK27E","created_at":"2026-07-04T14:18:39Z"}],"events":[{"event_type":"record_created","subject_pith_number":"pith:2001:ZPRMK27ELNEPY66S73UPDZIOQB","target":"record","payload":{"canonical_record":{"source":{"id":"cond-mat/0109509","kind":"arxiv","version":1},"metadata":{"license":"","primary_cat":"cond-mat.str-el","submitted_at":"2001-09-27T04:47:49Z","cross_cats_sorted":[],"title_canon_sha256":"cf8244b0a81b47e35aedb40fb6109dc5e5baab0d97393b8f4866026b9cc7fead","abstract_canon_sha256":"b0d074431db51f0b0eb0c73cd0763f6d7cae3787760bdbe5d29c58a67f297433"},"schema_version":"1.0"},"canonical_sha256":"cbe2c56be45b48fc7bd2fee8f1e50e806b780f5c9dc89ab7372c7dd4fcb392b6","receipt":{"kind":"pith_receipt","key_id":"pith-v1-2026-05","algorithm":"ed25519","signed_at":"2026-07-04T14:18:39.115173Z","signature_b64":"KYvG9hUo6+m+Gpi6l++9FdonbI3nnfQ2XOyVMdS7uqTIu+Pk3yd7gfKGAb/GXn2yIZ0PkH5iNLYL2QsHo3wLDA==","signed_message":"canonical_sha256_bytes","builder_version":"pith-number-builder-2026-05-17-v1","receipt_version":"0.3","canonical_sha256":"cbe2c56be45b48fc7bd2fee8f1e50e806b780f5c9dc89ab7372c7dd4fcb392b6","last_reissued_at":"2026-07-04T14:18:39.114754Z","signature_status":"signed_v1","first_computed_at":"2026-07-04T14:18:39.114754Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"source_kind":"arxiv","source_id":"cond-mat/0109509","source_version":1,"attestation_state":"computed"},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-04T14:18:39Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"Pzrf6b3qdAIOJRGd+ljYcbRp8wP2V+ZbbzqGK42IB2+UFi2VUR3G9cc1DXH4xJKOLXZRjN1GLLR3Hk9FXgUvDQ==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-07T14:08:31.583286Z"},"content_sha256":"da874b5f38103fa718ff94c9955ac497742f0395619a8e6407c7093320e67f2b","schema_version":"1.0","event_id":"sha256:da874b5f38103fa718ff94c9955ac497742f0395619a8e6407c7093320e67f2b"},{"event_type":"graph_snapshot","subject_pith_number":"pith:2001:ZPRMK27ELNEPY66S73UPDZIOQB","target":"graph","payload":{"graph_snapshot":{"paper":{"title":"Orbital excitations in CMR progenitor of LaMnO3 studied by resonant inelastic x-ray scattering","license":"","headline":"","cross_cats":[],"primary_cat":"cond-mat.str-el","authors_text":"H. Kondo, H. Nakao, J. Mizuki, K. Hirota, S. Ishihara, S. Maekawa, T. Fukuda, T. Inami, T. Matsumura, Y. Endoh, Y. Murakami","submitted_at":"2001-09-27T04:47:49Z","abstract_excerpt":"We report resonant inelastic x-ray scattering experiments of the orbital ordered manganite LaMnO3. When the incident photon energy is tuned near the Mn K absorption edge, the spectra reveal three features at 2.5 eV, 8 eV and 11 eV. The 8 eV and 11 eV peaks are considered charge-transfer type excitations. On the other hand, theoretical calculations identify the 2.5 eV peak as an orbital excitation across the Mott gap, i.e. an electron excitation from the lower Hubbard band with the d3x2-r2 and d3y2-r2 orbital characters to the upper Hubbard band with the dy2-z2 and dz2-x2 ones. The observed wea"},"claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"cond-mat/0109509","kind":"arxiv","version":1},"verdict":{"id":null,"model_set":{},"created_at":null,"strongest_claim":"","one_line_summary":"","pipeline_version":null,"weakest_assumption":"","pith_extraction_headline":""},"integrity":{"clean":true,"summary":{"advisory":0,"critical":0,"by_detector":{},"informational":0},"endpoint":"/pith/cond-mat/0109509/integrity.json","findings":[],"available":true,"detectors_run":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938"},"references":{"count":0,"sample":[],"resolved_work":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","internal_anchors":0},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"author_claims":{"count":0,"strong_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"builder_version":"pith-number-builder-2026-05-17-v1"},"verdict_id":null},"signer":{"signer_id":"pith.science","signer_type":"pith_registry","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54"},"created_at":"2026-07-04T14:18:39Z","supersedes":[],"prev_event":null,"signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"1Otpwc8gU+GIRv/9b8Nv5nz5M+MZDzYXHKgcniaYhP32zzb7Snq4nvBfDmDdGcyMU1SOhzyRPhllMydRMkMEBA==","signed_message":"open_graph_event_sha256_bytes","signed_at":"2026-08-07T14:08:31.583936Z"},"content_sha256":"ed058738b9779e4205d01fbef432d24058f2682ff09355d3daf2472ca111ee21","schema_version":"1.0","event_id":"sha256:ed058738b9779e4205d01fbef432d24058f2682ff09355d3daf2472ca111ee21"}],"timestamp_proofs":[],"mirror_hints":[{"mirror_type":"https","name":"Pith Resolver","base_url":"https://pith.science","bundle_url":"https://pith.science/pith/ZPRMK27ELNEPY66S73UPDZIOQB/bundle.json","state_url":"https://pith.science/pith/ZPRMK27ELNEPY66S73UPDZIOQB/state.json","well_known_bundle_url":"https://pith.science/.well-known/pith/ZPRMK27ELNEPY66S73UPDZIOQB/bundle.json","status":"primary"}],"public_keys":[{"key_id":"pith-v1-2026-05","algorithm":"ed25519","format":"raw","public_key_b64":"stVStoiQhXFxp4s2pdzPNoqVNBMojDU/fJ2db5S3CbM=","public_key_hex":"b2d552b68890857171a78b36a5dccf368a953413288c353f7c9d9d6f94b709b3","fingerprint_sha256_b32_first128bits":"RVFV5Z2OI2J3ZUO7ERDEBCYNKS","fingerprint_sha256_hex":"8d4b5ee74e4693bcd1df2446408b0d54","rotates_at":null,"url":"https://pith.science/pith-signing-key.json","notes":"Pith uses this Ed25519 key to sign canonical record SHA-256 digests. Verify with: ed25519_verify(public_key, message=canonical_sha256_bytes, signature=base64decode(signature_b64))."}],"merge_version":"pith-open-graph-merge-v1","built_at":"2026-08-07T14:08:31Z","links":{"resolver":"https://pith.science/pith/ZPRMK27ELNEPY66S73UPDZIOQB","bundle":"https://pith.science/pith/ZPRMK27ELNEPY66S73UPDZIOQB/bundle.json","state":"https://pith.science/pith/ZPRMK27ELNEPY66S73UPDZIOQB/state.json","well_known_bundle":"https://pith.science/.well-known/pith/ZPRMK27ELNEPY66S73UPDZIOQB/bundle.json"},"state":{"state_type":"pith_open_graph_state","state_version":"1.0","pith_number":"pith:2001:ZPRMK27ELNEPY66S73UPDZIOQB","merge_version":"pith-open-graph-merge-v1","event_count":2,"valid_event_count":2,"invalid_event_count":0,"equivocation_count":0,"current":{"canonical_record":{"metadata":{"abstract_canon_sha256":"b0d074431db51f0b0eb0c73cd0763f6d7cae3787760bdbe5d29c58a67f297433","cross_cats_sorted":[],"license":"","primary_cat":"cond-mat.str-el","submitted_at":"2001-09-27T04:47:49Z","title_canon_sha256":"cf8244b0a81b47e35aedb40fb6109dc5e5baab0d97393b8f4866026b9cc7fead"},"schema_version":"1.0","source":{"id":"cond-mat/0109509","kind":"arxiv","version":1}},"source_aliases":[{"alias_kind":"arxiv","alias_value":"cond-mat/0109509","created_at":"2026-07-04T14:18:39Z"},{"alias_kind":"arxiv_version","alias_value":"cond-mat/0109509v1","created_at":"2026-07-04T14:18:39Z"},{"alias_kind":"doi","alias_value":"10.48550/arxiv.cond-mat/0109509","created_at":"2026-07-04T14:18:39Z"},{"alias_kind":"pith_short_12","alias_value":"ZPRMK27ELNEP","created_at":"2026-07-04T14:18:39Z"},{"alias_kind":"pith_short_16","alias_value":"ZPRMK27ELNEPY66S","created_at":"2026-07-04T14:18:39Z"},{"alias_kind":"pith_short_8","alias_value":"ZPRMK27E","created_at":"2026-07-04T14:18:39Z"}],"graph_snapshots":[{"event_id":"sha256:ed058738b9779e4205d01fbef432d24058f2682ff09355d3daf2472ca111ee21","target":"graph","created_at":"2026-07-04T14:18:39Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"graph_snapshot":{"author_claims":{"count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57","strong_count":0},"builder_version":"pith-number-builder-2026-05-17-v1","claims":{"count":0,"items":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"formal_canon":{"evidence_count":0,"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"integrity":{"available":true,"clean":true,"detectors_run":[],"endpoint":"/pith/cond-mat/0109509/integrity.json","findings":[],"snapshot_sha256":"c28c3603d3b5d939e8dc4c7e95fa8dfce3d595e45f758748cecf8e644a296938","summary":{"advisory":0,"by_detector":{},"critical":0,"informational":0}},"paper":{"abstract_excerpt":"We report resonant inelastic x-ray scattering experiments of the orbital ordered manganite LaMnO3. When the incident photon energy is tuned near the Mn K absorption edge, the spectra reveal three features at 2.5 eV, 8 eV and 11 eV. The 8 eV and 11 eV peaks are considered charge-transfer type excitations. On the other hand, theoretical calculations identify the 2.5 eV peak as an orbital excitation across the Mott gap, i.e. an electron excitation from the lower Hubbard band with the d3x2-r2 and d3y2-r2 orbital characters to the upper Hubbard band with the dy2-z2 and dz2-x2 ones. The observed wea","authors_text":"H. Kondo, H. Nakao, J. Mizuki, K. Hirota, S. Ishihara, S. Maekawa, T. Fukuda, T. Inami, T. Matsumura, Y. Endoh, Y. Murakami","cross_cats":[],"headline":"","license":"","primary_cat":"cond-mat.str-el","submitted_at":"2001-09-27T04:47:49Z","title":"Orbital excitations in CMR progenitor of LaMnO3 studied by resonant inelastic x-ray scattering"},"references":{"count":0,"internal_anchors":0,"resolved_work":0,"sample":[],"snapshot_sha256":"258153158e38e3291e3d48162225fcdb2d5a3ed65a07baac614ab91432fd4f57"},"source":{"id":"cond-mat/0109509","kind":"arxiv","version":1},"verdict":{"created_at":null,"id":null,"model_set":{},"one_line_summary":"","pipeline_version":null,"pith_extraction_headline":"","strongest_claim":"","weakest_assumption":""}},"verdict_id":null}}],"author_attestations":[],"timestamp_anchors":[],"storage_attestations":[],"citation_signatures":[],"replication_records":[],"corrections":[],"mirror_hints":[],"record_created":{"event_id":"sha256:da874b5f38103fa718ff94c9955ac497742f0395619a8e6407c7093320e67f2b","target":"record","created_at":"2026-07-04T14:18:39Z","signer":{"key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signer_id":"pith.science","signer_type":"pith_registry"},"payload":{"attestation_state":"computed","canonical_record":{"metadata":{"abstract_canon_sha256":"b0d074431db51f0b0eb0c73cd0763f6d7cae3787760bdbe5d29c58a67f297433","cross_cats_sorted":[],"license":"","primary_cat":"cond-mat.str-el","submitted_at":"2001-09-27T04:47:49Z","title_canon_sha256":"cf8244b0a81b47e35aedb40fb6109dc5e5baab0d97393b8f4866026b9cc7fead"},"schema_version":"1.0","source":{"id":"cond-mat/0109509","kind":"arxiv","version":1}},"canonical_sha256":"cbe2c56be45b48fc7bd2fee8f1e50e806b780f5c9dc89ab7372c7dd4fcb392b6","receipt":{"algorithm":"ed25519","builder_version":"pith-number-builder-2026-05-17-v1","canonical_sha256":"cbe2c56be45b48fc7bd2fee8f1e50e806b780f5c9dc89ab7372c7dd4fcb392b6","first_computed_at":"2026-07-04T14:18:39.114754Z","key_id":"pith-v1-2026-05","kind":"pith_receipt","last_reissued_at":"2026-07-04T14:18:39.114754Z","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","receipt_version":"0.3","signature_b64":"KYvG9hUo6+m+Gpi6l++9FdonbI3nnfQ2XOyVMdS7uqTIu+Pk3yd7gfKGAb/GXn2yIZ0PkH5iNLYL2QsHo3wLDA==","signature_status":"signed_v1","signed_at":"2026-07-04T14:18:39.115173Z","signed_message":"canonical_sha256_bytes"},"source_id":"cond-mat/0109509","source_kind":"arxiv","source_version":1}}},"equivocations":[],"invalid_events":[],"applied_event_ids":["sha256:da874b5f38103fa718ff94c9955ac497742f0395619a8e6407c7093320e67f2b","sha256:ed058738b9779e4205d01fbef432d24058f2682ff09355d3daf2472ca111ee21"],"state_sha256":"aef13b00cb63c8537148026cec7355fda9d96335ca2dfaeeff1f075b9f38bf62"},"bundle_signature":{"signature_status":"signed_v1","algorithm":"ed25519","key_id":"pith-v1-2026-05","public_key_fingerprint":"8d4b5ee74e4693bcd1df2446408b0d54","signature_b64":"Fk5bQkl4SNOVRhku1FOZiub7BeoYQrKEDbAIoXGnsWQlbCurJhGc5Lc8ot7vILAzV4zINQaFr5+yhf+1WuTiBQ==","signed_message":"bundle_sha256_bytes","signed_at":"2026-08-07T14:08:31.588734Z","bundle_sha256":"3812adf2d9c912b6505189a776ce6729e58c0ced186e9bac93f138b813956834"}}