Combined Thermal Expansion and Hydrolytic Stability Study of Lanthanide Vanadates LnVO4 and CaLnZr(VO4)3 (Ln = La, Nd, Sm, Eu, Gd, Dy, Yb) with Zircon and Monazite Structures

(2) Joint Institute for Nuclear Research; (3) ((1) Lobachevsky State University of Nizhny Novgorod; (3) National University of Science; (4) A.M. Prokhorov General Physics Institute of the Russian Academy of Science); A. A. Atopshev (1); A. A. Murashov (1); A. I. Beskrovnyi (2); A. I. Orlova (1); A. K. Koryttseva (1); A. V. Nokhrin (1)

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arxiv 2312.08738 v1 pith:GFHWZOGF submitted 2023-12-14 cond-mat.mtrl-sci

Combined Thermal Expansion and Hydrolytic Stability Study of Lanthanide Vanadates LnVO4 and CaLnZr(VO4)3 (Ln = La, Nd, Sm, Eu, Gd, Dy, Yb) with Zircon and Monazite Structures

A. K. Koryttseva (1) , A. I. Orlova (1) , N. S. Litonova (1) , A. V. Nokhrin (1) , M. S. Boldin (1) , A. A. Murashov (1) , D. G. Fukina (1) , A. A. Atopshev (1)

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K. E. Smetanina (1) A. I. Beskrovnyi (2) V. A. Turchenko (2) N. Y. Tabachkova (2) (3) ((1) Lobachevsky State University of Nizhny Novgorod (2) Joint Institute for Nuclear Research (3) National University of Science Technology "MISIS" (4) A.M. Prokhorov General Physics Institute of the Russian Academy of Science)

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keywords werevanadatespowderscalnzrceramicexpansionhydrolyticlnvo4

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The paper presents the investigation of ordinary and ternary vanadates with zircon and monazite structures. Vanadates LnVO4 and CaLnZr(VO4)3 , where (Ln = La, Nd, Sm, Eu, Gd, Dy, Yb) and solid solution La0.3Nd0.5Sm0.1Eu0.1VO4, were prepared by precipitation reaction. Bulk ceramic samples were obtained from powders by Spark Plasma Sintering (SPS). The powders and ceramics were examined with several physicochemical methods. The coefficients of thermal expansion at 900{\deg}C were determined. The hydrolytic stability of ceramic materials was studied. The peculiarities of high-rate SPS of powders of ordinary and ternary vanadates were analyzed.

Combined Thermal Expansion and Hydrolytic Stability Study of Lanthanide Vanadates LnVO4 and CaLnZr(VO4)3 (Ln = La, Nd, Sm, Eu, Gd, Dy, Yb) with Zircon and Monazite Structures

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