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arxiv 1201.1182 v4 pith:U3IWHQ2W submitted 2012-01-05 cond-mat.mtrl-sci cond-mat.stat-mech

Cooperative mercury motion in the ionic conductor Cu2HgI4

classification cond-mat.mtrl-sci cond-mat.stat-mech
keywords ionicconductorcooperativecu2hgi4dynamicmercuryappearsarrested
verification ladder T0 review T1 audit T2 compute T3 formal T4 reserved
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We present the observation of glass-like dynamic correlations of mobile mercury ions in the ionic conductor Cu2HgI4, detected in both NMR and nonlinear conductivity experiments. The results show that dynamic cooperativity appears in systems seemingly unrelated to glassy and soft arrested materials. A simple kinetic two-component model is proposed, which seems to provide a good description of the cooperative ionic dynamics.

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