Topochemical lithium-to-cobalt exchange yields metastable Co2Ti3O8, a strongly frustrated S = 3/2 diamond-lattice antiferromagnet whose molecular-field analysis suggests a spiral ground state.
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Frustrated $J_1-J_2$ Diamond Lattice Antiferromagnet Co$_2$Ti$_3$O$_8$ with a Vacancy-ordered Spinel Structure Synthesized via a Topochemical Reaction
Topochemical lithium-to-cobalt exchange yields metastable Co2Ti3O8, a strongly frustrated S = 3/2 diamond-lattice antiferromagnet whose molecular-field analysis suggests a spiral ground state.