Treating lattice site count as an extra thermodynamic variable yields a generalized Gibbs-Duhem equation and new response functions for vacancy formation in compressible crystals.
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Thermodynamics of a compressible lattice gas crystal: Generalized Gibbs-Duhem equation and adsorption
Treating lattice site count as an extra thermodynamic variable yields a generalized Gibbs-Duhem equation and new response functions for vacancy formation in compressible crystals.