High pressure converts IO3 units to hypercoordinated IO6 in K2Zn(IO3)4.2H2O forming 2D iodate networks, promotes multicenter O-H-O bonds, yields bulk modulus 22(3) GPa, and closes the band gap from 4.2 eV to 3.4 eV at 20 GPa.
DIOPTAS: A Program for Reduction of Two-Dimensional X-Ray Diffraction Data and Data Exploration
5 Pith papers cite this work. Polarity classification is still indexing.
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A Zr-BMG clamp cell delivers higher neutron transmission and clean background for high-pressure INS compared to conventional CuBe cells.
DFT predicts phase transitions in BaSnF4 at 10 GPa and 32 GPa; the first is confirmed experimentally while the second is supported by indirect signatures.
New Gibbs energy representations for ices III, V, and VI, built from volume measurements and vibrational calculations, enable thermodynamic and seismic properties across solar-system hydrosphere conditions.
Both (CePr)O2-δ and (CePrLa)O2-δ retain cubic fluorite structure to 30 GPa with a 9-16 GPa anomaly from local distortions and bond bending, while the La-containing compound amorphizes above 22 GPa.
citing papers explorer
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Effects of Compression on the Local Iodine Environment in Dipotassium Zinc Tetraiodate(V) Dihydrate K2Zn(IO3)4.2H2O
High pressure converts IO3 units to hypercoordinated IO6 in K2Zn(IO3)4.2H2O forming 2D iodate networks, promotes multicenter O-H-O bonds, yields bulk modulus 22(3) GPa, and closes the band gap from 4.2 eV to 3.4 eV at 20 GPa.
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Zr-based bulk metallic glass clamp cell for high-pressure inelastic neutron scattering
A Zr-BMG clamp cell delivers higher neutron transmission and clean background for high-pressure INS compared to conventional CuBe cells.
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Theory-Guided Discovery of Pressure-Induced Transitions in Fast-Ion Conductor BaSnF4
DFT predicts phase transitions in BaSnF4 at 10 GPa and 32 GPa; the first is confirmed experimentally while the second is supported by indirect signatures.
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Gibbs energy of ices III, V and VI: wholistic thermodynamics and elasticity of the water phase diagram to 2300 MPa
New Gibbs energy representations for ices III, V, and VI, built from volume measurements and vibrational calculations, enable thermodynamic and seismic properties across solar-system hydrosphere conditions.
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Comparative high-pressure study on rare-earth entropy fluorite-type oxides
Both (CePr)O2-δ and (CePrLa)O2-δ retain cubic fluorite structure to 30 GPa with a 9-16 GPa anomaly from local distortions and bond bending, while the La-containing compound amorphizes above 22 GPa.