Free-energy model predicts bubble nucleation activation energy scales as supersaturation to the -2 power and critical radius to the -1, with quantitative experimental agreement for hydrogen, oxygen, and nitrogen bubbles plus a coupling to current density.
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Free-Energy Analysis of Bubble Nucleation on Electrocatalytic Surfaces
Free-energy model predicts bubble nucleation activation energy scales as supersaturation to the -2 power and critical radius to the -1, with quantitative experimental agreement for hydrogen, oxygen, and nitrogen bubbles plus a coupling to current density.