Korteweg fluid constitutive equations are derived via Liu's multipliers with capillary effects in entropy, allowing temperature-dependent material parameters in stresses and producing a generalized Gibbs relation consistent with kinetic theory.
Proceedings of the Royal Society of London A 454, 2617–2654
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Constitutive Modelling of Korteweg Fluids Using Liu's Method
Korteweg fluid constitutive equations are derived via Liu's multipliers with capillary effects in entropy, allowing temperature-dependent material parameters in stresses and producing a generalized Gibbs relation consistent with kinetic theory.