Analytic solutions to the linear modified Poisson-Boltzmann equation predict a transition to damped oscillatory screening in electrolytes above a critical concentration.
Comments on the linear modified Poisson-Boltzmann equation in electrolyte solution theory
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abstract
Three analytic results are proposed for a linear form of the modified Poisson-Boltzmann equation in the theory of bulk electrolytes. Comparison is also made with the mean spherical approximation results. The linear theories predict a transition of the mean electrostatic potential from a Debye-H\"{u}ckel type damped exponential to a damped oscillatory behaviour as the electrolyte concentration increases beyond a critical value. The screening length decreases with increasing concentration when the mean electrostatic potential is damped oscillatory. A comparison is made with one set of recent experimental screening results for aqueous NaCl electrolytes.
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cond-mat.stat-mech 1years
2019 1verdicts
UNVERDICTED 1representative citing papers
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Comments on the linear modified Poisson-Boltzmann equation in electrolyte solution theory
Analytic solutions to the linear modified Poisson-Boltzmann equation predict a transition to damped oscillatory screening in electrolytes above a critical concentration.