Surface polarons on TiO2(110) are stabilized by water dissociation near oxygen vacancies through proton-coupled electron polaron transfer, enabling N2 activation and photocatalytic reduction.
Fundamentals and Recent Progress of Photocatalytic Nitrogen-Fixation Reaction over Semiconductors
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Synergistic Interplay between Surface Polarons and Adsorbates for Photocatalytic Nitrogen Reduction on TiO$_2$(110)
Surface polarons on TiO2(110) are stabilized by water dissociation near oxygen vacancies through proton-coupled electron polaron transfer, enabling N2 activation and photocatalytic reduction.