The authors derive the large-deviation rate function for ionic current in a symmetric dilute electrolyte and show it is non-Gaussian away from equilibrium, with a boundary-layer mechanism at large voltage.
Camalet , author J
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Large deviations of ionic currents in dilute electrolytes
The authors derive the large-deviation rate function for ionic current in a symmetric dilute electrolyte and show it is non-Gaussian away from equilibrium, with a boundary-layer mechanism at large voltage.