Peropyrene's molecular plasmon is barely changed by nitrogen substitution, but oxygen substitution disrupts the pi-electron network, red-shifting and weakening the resonance, while charge doping tunes it.
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Influence of conjugated structure for tunable molecular plasmons in peropyrene and its derivatives
Peropyrene's molecular plasmon is barely changed by nitrogen substitution, but oxygen substitution disrupts the pi-electron network, red-shifting and weakening the resonance, while charge doping tunes it.