Barrierless termolecular reactions are governed by direct three-body dynamics, as shown by classical trajectory calculations in hyperspherical coordinates that reproduce ion-atom recombination kinetics across temperatures without intermediate complexes or steady-state assumptions.
Pérez-Ríos,The Journal of Chemical Physics, 2024,161, 144305
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Direct three body dynamics govern ion atom recombination and barrierless termolecular reactions
Barrierless termolecular reactions are governed by direct three-body dynamics, as shown by classical trajectory calculations in hyperspherical coordinates that reproduce ion-atom recombination kinetics across temperatures without intermediate complexes or steady-state assumptions.