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Semiclassical analysis of the quantum instanton approximation

physics.chem-ph · 2019-08-09 · accept · novelty 8.0

The quantum instanton rate reduces to semiclassical instanton theory only for symmetric barriers; for asymmetric barriers a spurious low-energy path ruins the approximation, and a projection operator fixes it.

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  • Semiclassical analysis of the quantum instanton approximation physics.chem-ph · 2019-08-09 · accept · none · ref 4

    The quantum instanton rate reduces to semiclassical instanton theory only for symmetric barriers; for asymmetric barriers a spurious low-energy path ruins the approximation, and a projection operator fixes it.