Spin-orbit coupling and sloped crossing geometry make the triplet metal-centered state a trap rather than a fast funnel back to the ground state in Ir(III) complexes.
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The role of spin-orbit coupling and state-crossing topography in the non-radiative decay of Ir(III) complexes
Spin-orbit coupling and sloped crossing geometry make the triplet metal-centered state a trap rather than a fast funnel back to the ground state in Ir(III) complexes.