CaCl2 conduction in negatively charged silica nanopores becomes bulk-like or anion-favored due to Ca2+ immobilization near the wall and Cl- flow in the interior after charge inversion, unlike conventional cation selectivity in NaCl.
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Interplay of ion availability and mobility in the loss of cation selectivity for CaCl\textsubscript{2} in negatively charged nanopores: molecular dynamics using scaled-charge models
CaCl2 conduction in negatively charged silica nanopores becomes bulk-like or anion-favored due to Ca2+ immobilization near the wall and Cl- flow in the interior after charge inversion, unlike conventional cation selectivity in NaCl.