An analytic time-domain expression for chromatographic peak shapes is derived from a stochastic-diffusive model with multiple independent slow retention mechanisms, together with efficient evaluation and parameter derivatives.
Chromatographic peak shape from a stochastic model: Analytictime-domain expression in terms ofphysicalparameters and conditions under which heterogeneity reduces tailing
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Chromatographic Peak Shape from a Stochastic-Diffusive Model with Multiple Retention Mechanisms: Analytic Time-Domain Expression and Derivatives
An analytic time-domain expression for chromatographic peak shapes is derived from a stochastic-diffusive model with multiple independent slow retention mechanisms, together with efficient evaluation and parameter derivatives.