The PFO model coupled with the Sips isotherm predicts finite-time abrupt breakthrough and yields a concentration-dependent effective rate constant, indicating it is unfit for column adsorption dynamics.
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On the use of equilibrium models to describe dynamic adsorption regimes
The PFO model coupled with the Sips isotherm predicts finite-time abrupt breakthrough and yields a concentration-dependent effective rate constant, indicating it is unfit for column adsorption dynamics.