Increasing the lattice constant shifts TCNQ adsorbate-adsorbate interactions from repulsive to attractive, favoring tight-packing polymorphs and inducing a lattice-constant-driven phase transition.
Direct Experimental Determination of Ag Adatom Locations in TCNQ-Ag 2D Metal–Organic Framework on Ag(111)
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Impact of the Lattice Constant on the Polymorphism of Organic/Inorganic Interfaces
Increasing the lattice constant shifts TCNQ adsorbate-adsorbate interactions from repulsive to attractive, favoring tight-packing polymorphs and inducing a lattice-constant-driven phase transition.